Mechanistic Insights on the Functionalization of CO2 with Amines and Hydrosilanes Catalyzed by a Zwitterionic Iridium Carboxylate‐Functionalized Bis‐NHC Catalyst

The zwitterionic complex [Cp*IrCl{(MeIm)2CHCOO}] (1) efficiently catalyzes the selective hydrosilylation of CO2 to afford the corresponding silylformate. The best reaction performance has been achieved in acetonitrile at 348 K using HSiMe2Ph. The 1‐catalyzed reaction of pyrrolidine with CO2 and HSiM...

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Veröffentlicht in:	ChemCatChem 2019-11, Vol.11 (22), p.5524-5535
Hauptverfasser:	Ojeda‐Amador, Ana I., Munarriz, Julen, Alamán‐Valtierra, Pablo, Polo, Víctor, Puerta‐Oteo, Raquel, Jiménez, M. Victoria, Fernández‐Alvarez, Francisco J., Pérez‐Torrente, Jesús J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetonitrile Amines Carbon dioxide CO2 formylation Hydrosilylation Iridium NHC Reaction products Zwitterions
Online-Zugang:	Volltext
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