Evaluation of thermal hazards based on thermokinetic parameters of 2-(1-cyano-1-methylethyl)azocarboxamide by ARC and DSC

Azo compounds (azos) are widely used as radical initiators in the polymerization industry. Nonetheless, due to the azo group molecular structure, azos gravitate toward thermal decomposition and lead to thermal runaway accidents. In this paper, the thermal decomposition behaviors of 2-(1-cyano-1-meth...

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Veröffentlicht in:	Journal of thermal analysis and calorimetry 2019-11, Vol.138 (4), p.2873-2881
Hauptverfasser:	Lu, Yi-Ming, Liu, Shang-Hao, Shu, Chi-Min
Format:	Artikel
Sprache:	eng
Schlagworte:	Accidents Adiabatic conditions Analysis Analytical Chemistry Azo compounds Calorimetry Chemistry Chemistry and Materials Science Confined spaces Curve fitting Decomposition Deflagration Emergency procedures Emergency response Evaluation Explosions Hazards Industrial applications Initiators Inorganic Chemistry Low temperature Measurement Science and Instrumentation Molecular structure Parameters Physical Chemistry Polymer Sciences Polymerization Safety and security measures Thermal decomposition Thermal runaway
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