Performance evaluation of Ce3+ doped flexible PVDF fibers for efficient optical pressure sensors

[Display omitted] •Centrifugally spun cerium doped nonwoven fibrous mat are explored as a non-contact optical pressure sensor.•The developed sensor depicted wide linear dynamic range and good pressure sensitivity.•The sensor properties are based on the spectral shift, broadening and intensity enhanc...

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Veröffentlicht in:Sensors and actuators. A. Physical. 2019-10, Vol.298, p.111595, Article 111595
Hauptverfasser: Hernandez, C., Gupta, Santosh K., Zuniga, Jose P., Vidal, Jorge, Galvan, Rene, Martinez, Misael, Guzman, Hector, Chavez, Lilian, Mao, Yuanbing, Lozano, Karen
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container_start_page 111595
container_title Sensors and actuators. A. Physical.
container_volume 298
creator Hernandez, C.
Gupta, Santosh K.
Zuniga, Jose P.
Vidal, Jorge
Galvan, Rene
Martinez, Misael
Guzman, Hector
Chavez, Lilian
Mao, Yuanbing
Lozano, Karen
description [Display omitted] •Centrifugally spun cerium doped nonwoven fibrous mat are explored as a non-contact optical pressure sensor.•The developed sensor depicted wide linear dynamic range and good pressure sensitivity.•The sensor properties are based on the spectral shift, broadening and intensity enhancement.•β-phase in doped fibers increases when compared to undoped PVDF.•Cerium nitrate doped fiber exhibits a high-pressure sensitivity (dλ/dP ≈ 0.28 nm/GPa) with no luminescence quenching. This work proposes a highly novel centrifugally spun lanthanide doped nonwoven fibrous mat as a non-contact optical pressure sensor with a wide linear dynamic range and good pressure sensitivity. The sensor properties are based on the spectral shift, broadening and intensity enhancement of Ce3+ ion in Ce doped PVDF fiber upto significantly high pressure. Two different systems: Ce(NO3)3·6H2O and (NH4)4Ce(SO4)4·2H2O doped PVDF flexible fibers (CeN-PF and CeS-PF) were produced using the Forcespinning® technique. Both CeN-PF and CeS-PF fibers displayed violet-blue emission under UV irradiation due to a 5d-4f transition of Ce3+ ions. Our emission results show that both CeN-PF and CeS-PF spectral characteristics are influenced by high pressures, inducing significant spectral ref shift in 5d-4f. The pressure-induced monotonous changes in bandwidth and emission intensity enhancement along with red shift suggesting the potential application of these fibers for pressure sensing applications. The CeN-PF fiber exhibits a high-pressure sensitivity (dλ/dP ≈ 0.28 nm/GPa) under a comprehensive linear dynamic range (0–64 GPa) with no pressure-induced luminescence quenching. The changes in CeS-PF is less pronounced with a lower pressure sensitivity of 0.10 nm/GPa compared to CeN-PF due to large crystal field splitting energy of nitrate ion compared to sulphate ion. This work presents a highly efficient, cost effective, scalable lanthanide doped flexible fibrous based system with negligible high pressure quenching and a wider linear dynamic range for optical pressure sensing applications.
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This work proposes a highly novel centrifugally spun lanthanide doped nonwoven fibrous mat as a non-contact optical pressure sensor with a wide linear dynamic range and good pressure sensitivity. The sensor properties are based on the spectral shift, broadening and intensity enhancement of Ce3+ ion in Ce doped PVDF fiber upto significantly high pressure. Two different systems: Ce(NO3)3·6H2O and (NH4)4Ce(SO4)4·2H2O doped PVDF flexible fibers (CeN-PF and CeS-PF) were produced using the Forcespinning® technique. Both CeN-PF and CeS-PF fibers displayed violet-blue emission under UV irradiation due to a 5d-4f transition of Ce3+ ions. Our emission results show that both CeN-PF and CeS-PF spectral characteristics are influenced by high pressures, inducing significant spectral ref shift in 5d-4f. The pressure-induced monotonous changes in bandwidth and emission intensity enhancement along with red shift suggesting the potential application of these fibers for pressure sensing applications. The CeN-PF fiber exhibits a high-pressure sensitivity (dλ/dP ≈ 0.28 nm/GPa) under a comprehensive linear dynamic range (0–64 GPa) with no pressure-induced luminescence quenching. The changes in CeS-PF is less pronounced with a lower pressure sensitivity of 0.10 nm/GPa compared to CeN-PF due to large crystal field splitting energy of nitrate ion compared to sulphate ion. 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A. Physical.</title><description>[Display omitted] •Centrifugally spun cerium doped nonwoven fibrous mat are explored as a non-contact optical pressure sensor.•The developed sensor depicted wide linear dynamic range and good pressure sensitivity.•The sensor properties are based on the spectral shift, broadening and intensity enhancement.•β-phase in doped fibers increases when compared to undoped PVDF.•Cerium nitrate doped fiber exhibits a high-pressure sensitivity (dλ/dP ≈ 0.28 nm/GPa) with no luminescence quenching. This work proposes a highly novel centrifugally spun lanthanide doped nonwoven fibrous mat as a non-contact optical pressure sensor with a wide linear dynamic range and good pressure sensitivity. The sensor properties are based on the spectral shift, broadening and intensity enhancement of Ce3+ ion in Ce doped PVDF fiber upto significantly high pressure. Two different systems: Ce(NO3)3·6H2O and (NH4)4Ce(SO4)4·2H2O doped PVDF flexible fibers (CeN-PF and CeS-PF) were produced using the Forcespinning® technique. Both CeN-PF and CeS-PF fibers displayed violet-blue emission under UV irradiation due to a 5d-4f transition of Ce3+ ions. Our emission results show that both CeN-PF and CeS-PF spectral characteristics are influenced by high pressures, inducing significant spectral ref shift in 5d-4f. The pressure-induced monotonous changes in bandwidth and emission intensity enhancement along with red shift suggesting the potential application of these fibers for pressure sensing applications. The CeN-PF fiber exhibits a high-pressure sensitivity (dλ/dP ≈ 0.28 nm/GPa) under a comprehensive linear dynamic range (0–64 GPa) with no pressure-induced luminescence quenching. The changes in CeS-PF is less pronounced with a lower pressure sensitivity of 0.10 nm/GPa compared to CeN-PF due to large crystal field splitting energy of nitrate ion compared to sulphate ion. This work presents a highly efficient, cost effective, scalable lanthanide doped flexible fibrous based system with negligible high pressure quenching and a wider linear dynamic range for optical pressure sensing applications.</description><subject>Cerium</subject><subject>Cerium nitrate</subject><subject>Contact pressure</subject><subject>Doppler effect</subject><subject>Dynamic range</subject><subject>Emission</subject><subject>Fiber</subject><subject>Forcespinning</subject><subject>High pressure</subject><subject>Luminescence</subject><subject>Optical fibers</subject><subject>Performance evaluation</subject><subject>Photoluminescence</subject><subject>Pressure</subject><subject>Pressure sensors</subject><subject>Quenching</subject><subject>Red shift</subject><subject>Sensitivity</subject><subject>Sensor</subject><subject>Sensors</subject><subject>Spectra</subject><subject>Ultraviolet radiation</subject><issn>0924-4247</issn><issn>1873-3069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwzAQRS0EEqXwAewssUQJfuVhsUKlBaRKdAFsjeOMJUdpHOykgr8nVVizms09d2YOQteUpJTQ_K5JY6dTRqhMKaWZzE7QgpYFTzjJ5SlaEMlEIpgoztFFjA0hhPOiWKDPHQTrw153BjAcdDvqwfkOe4tXwG9x7XuosW3h21Ut4N3H4wZbV0GIeMIwWOuMg27Avh-c0S3uA8Q4BsARuuhDvERnVrcRrv7mEr1v1m-r52T7-vSyetgmhslySFhhdKmLikENAljFeMXKrLRUSyK1NVUlMpKbkjDJC81rIcHYjBmgjAhNgS_RzdzbB_81QhxU48fQTSsV45MQkXNaTik6p0zwMQawqg9ur8OPokQdRapGTSLVUaSaRU7M_czAdP7BQVDx-LKB2gUwg6q9-4f-BeHbe78</recordid><startdate>20191015</startdate><enddate>20191015</enddate><creator>Hernandez, C.</creator><creator>Gupta, Santosh K.</creator><creator>Zuniga, Jose P.</creator><creator>Vidal, Jorge</creator><creator>Galvan, Rene</creator><creator>Martinez, Misael</creator><creator>Guzman, Hector</creator><creator>Chavez, Lilian</creator><creator>Mao, Yuanbing</creator><creator>Lozano, Karen</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7TB</scope><scope>7U5</scope><scope>8FD</scope><scope>FR3</scope><scope>L7M</scope></search><sort><creationdate>20191015</creationdate><title>Performance evaluation of Ce3+ doped flexible PVDF fibers for efficient optical pressure sensors</title><author>Hernandez, C. ; Gupta, Santosh K. ; Zuniga, Jose P. ; Vidal, Jorge ; Galvan, Rene ; Martinez, Misael ; Guzman, Hector ; Chavez, Lilian ; Mao, Yuanbing ; Lozano, Karen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c298t-27ca8a7b2ede4e2b23b2858f1a909afcbb4506c802937a3d49ecf52ce1204a1e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Cerium</topic><topic>Cerium nitrate</topic><topic>Contact pressure</topic><topic>Doppler effect</topic><topic>Dynamic range</topic><topic>Emission</topic><topic>Fiber</topic><topic>Forcespinning</topic><topic>High pressure</topic><topic>Luminescence</topic><topic>Optical fibers</topic><topic>Performance evaluation</topic><topic>Photoluminescence</topic><topic>Pressure</topic><topic>Pressure sensors</topic><topic>Quenching</topic><topic>Red shift</topic><topic>Sensitivity</topic><topic>Sensor</topic><topic>Sensors</topic><topic>Spectra</topic><topic>Ultraviolet radiation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hernandez, C.</creatorcontrib><creatorcontrib>Gupta, Santosh K.</creatorcontrib><creatorcontrib>Zuniga, Jose P.</creatorcontrib><creatorcontrib>Vidal, Jorge</creatorcontrib><creatorcontrib>Galvan, Rene</creatorcontrib><creatorcontrib>Martinez, Misael</creatorcontrib><creatorcontrib>Guzman, Hector</creatorcontrib><creatorcontrib>Chavez, Lilian</creatorcontrib><creatorcontrib>Mao, Yuanbing</creatorcontrib><creatorcontrib>Lozano, Karen</creatorcontrib><collection>CrossRef</collection><collection>Mechanical &amp; Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Sensors and actuators. 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Physical.</jtitle><date>2019-10-15</date><risdate>2019</risdate><volume>298</volume><spage>111595</spage><pages>111595-</pages><artnum>111595</artnum><issn>0924-4247</issn><eissn>1873-3069</eissn><abstract>[Display omitted] •Centrifugally spun cerium doped nonwoven fibrous mat are explored as a non-contact optical pressure sensor.•The developed sensor depicted wide linear dynamic range and good pressure sensitivity.•The sensor properties are based on the spectral shift, broadening and intensity enhancement.•β-phase in doped fibers increases when compared to undoped PVDF.•Cerium nitrate doped fiber exhibits a high-pressure sensitivity (dλ/dP ≈ 0.28 nm/GPa) with no luminescence quenching. This work proposes a highly novel centrifugally spun lanthanide doped nonwoven fibrous mat as a non-contact optical pressure sensor with a wide linear dynamic range and good pressure sensitivity. The sensor properties are based on the spectral shift, broadening and intensity enhancement of Ce3+ ion in Ce doped PVDF fiber upto significantly high pressure. Two different systems: Ce(NO3)3·6H2O and (NH4)4Ce(SO4)4·2H2O doped PVDF flexible fibers (CeN-PF and CeS-PF) were produced using the Forcespinning® technique. Both CeN-PF and CeS-PF fibers displayed violet-blue emission under UV irradiation due to a 5d-4f transition of Ce3+ ions. Our emission results show that both CeN-PF and CeS-PF spectral characteristics are influenced by high pressures, inducing significant spectral ref shift in 5d-4f. The pressure-induced monotonous changes in bandwidth and emission intensity enhancement along with red shift suggesting the potential application of these fibers for pressure sensing applications. The CeN-PF fiber exhibits a high-pressure sensitivity (dλ/dP ≈ 0.28 nm/GPa) under a comprehensive linear dynamic range (0–64 GPa) with no pressure-induced luminescence quenching. The changes in CeS-PF is less pronounced with a lower pressure sensitivity of 0.10 nm/GPa compared to CeN-PF due to large crystal field splitting energy of nitrate ion compared to sulphate ion. This work presents a highly efficient, cost effective, scalable lanthanide doped flexible fibrous based system with negligible high pressure quenching and a wider linear dynamic range for optical pressure sensing applications.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.sna.2019.111595</doi><oa>free_for_read</oa></addata></record>
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subjects Cerium
Cerium nitrate
Contact pressure
Doppler effect
Dynamic range
Emission
Fiber
Forcespinning
High pressure
Luminescence
Optical fibers
Performance evaluation
Photoluminescence
Pressure
Pressure sensors
Quenching
Red shift
Sensitivity
Sensor
Sensors
Spectra
Ultraviolet radiation
title Performance evaluation of Ce3+ doped flexible PVDF fibers for efficient optical pressure sensors
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