Photocatalyst‐Free Visible Light‐Induced Synthesis of β‐Oxo Sulfones via Oxysulfonylation of Alkenes with Arylazo Sulfones and Dioxygen in Air

A catalyst‐free strategy has been established for the synthesis of β‐oxo sulfones via visible light‐induced oxysulfonylation of alkenes with arylazo sulfones with dioxygen in air. The present photoinduced transformation proceeds smoothly at room temperature in the absence of an external photosensiti...

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Veröffentlicht in:	Advanced synthesis & catalysis 2019-11, Vol.361 (22), p.5277-5282
Hauptverfasser:	Liu, Qishun, Liu, Fei, Yue, Huilan, Zhao, Xiaohui, Li, Jiangsheng, Wei, Wei
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes arylazo sulfones oxysulfonylation photocatalyst-free Photochemical reactions Room temperature Sulfones visible light β-oxo sulfones
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container_title	Advanced synthesis & catalysis
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creator	Liu, Qishun Liu, Fei Yue, Huilan Zhao, Xiaohui Li, Jiangsheng Wei, Wei
description	A catalyst‐free strategy has been established for the synthesis of β‐oxo sulfones via visible light‐induced oxysulfonylation of alkenes with arylazo sulfones with dioxygen in air. The present photoinduced transformation proceeds smoothly at room temperature in the absence of an external photosensitizer, which not only provides a mild and efficient approach to various β‐oxo sulfones, but also opens a different reaction mode for the photochemical reaction of arylazo sulfones.
doi_str_mv	10.1002/adsc.201900984
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subjects	Alkenes arylazo sulfones oxysulfonylation photocatalyst-free Photochemical reactions Room temperature Sulfones visible light β-oxo sulfones
title	Photocatalyst‐Free Visible Light‐Induced Synthesis of β‐Oxo Sulfones via Oxysulfonylation of Alkenes with Arylazo Sulfones and Dioxygen in Air
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