Effects of Al dopant on XRD, FT-IR and UV–vis properties of MgO films
Undoped and Al doped MgO films have been prepared by a sol–gel spin coating method. The crystalline structural, optical, vibrational and morphological properties of the Al doped MgO films were characterized by different techniques including scanning electron microscopy (SEM), X-ray diffraction (XRD)...
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description | Undoped and Al doped MgO films have been prepared by a sol–gel spin coating method. The crystalline structural, optical, vibrational and morphological properties of the Al doped MgO films were characterized by different techniques including scanning electron microscopy (SEM), X-ray diffraction (XRD), UV–vis absorption spectra, and Fourier transform infrared (FT-IR) measurements. XRD patterns confirm that the films were polycrystalline cubic nature. The crystallite size of the films slightly changed with increasing the Al dopant content. The optical band gap of the films was found to decrease from 3.92 to 3.84 eV by Al incorporation. The FT-IR spectroscopy confirms the presence of MgO. The observed vibrational bands at 679 and 862 cm−1 revealed the existence of the cubic MgO bonds. Surface morphology of the films was significantly affected by Al doping.
•Undoped and Al doped MgO films have been produced on glass substrates.•XRD analysis confirmed the cubic structure.•Al doping decreased optical band gaps of the MgO film. |
doi_str_mv | 10.1016/j.physb.2019.06.020 |
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•Undoped and Al doped MgO films have been produced on glass substrates.•XRD analysis confirmed the cubic structure.•Al doping decreased optical band gaps of the MgO film.</description><identifier>ISSN: 0921-4526</identifier><identifier>EISSN: 1873-2135</identifier><identifier>DOI: 10.1016/j.physb.2019.06.020</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Absorption spectra ; Al doping ; Crystallites ; Diffraction ; Dopants ; Fourier transforms ; FT-IR ; Infrared spectra ; Infrared spectroscopy ; Magnesium oxide ; MgO films ; Morphology ; Optical properties ; Scanning electron microscopy ; Semiconductor doping ; Sol-gel processes ; Sol–gel spin coating ; Spin coating ; Thin films ; X-ray diffraction</subject><ispartof>Physica. B, Condensed matter, 2019-10, Vol.570, p.280-284</ispartof><rights>2019 Elsevier B.V.</rights><rights>Copyright Elsevier BV Oct 1, 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c331t-eed3bdf4ec0d29c152164f4c8d461f6c7e41b0318166e3ab0548da0a4d7f59033</citedby><cites>FETCH-LOGICAL-c331t-eed3bdf4ec0d29c152164f4c8d461f6c7e41b0318166e3ab0548da0a4d7f59033</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.physb.2019.06.020$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,777,781,3537,27905,27906,45976</link.rule.ids></links><search><creatorcontrib>Aksay, Sabiha</creatorcontrib><title>Effects of Al dopant on XRD, FT-IR and UV–vis properties of MgO films</title><title>Physica. B, Condensed matter</title><description>Undoped and Al doped MgO films have been prepared by a sol–gel spin coating method. The crystalline structural, optical, vibrational and morphological properties of the Al doped MgO films were characterized by different techniques including scanning electron microscopy (SEM), X-ray diffraction (XRD), UV–vis absorption spectra, and Fourier transform infrared (FT-IR) measurements. XRD patterns confirm that the films were polycrystalline cubic nature. The crystallite size of the films slightly changed with increasing the Al dopant content. The optical band gap of the films was found to decrease from 3.92 to 3.84 eV by Al incorporation. The FT-IR spectroscopy confirms the presence of MgO. The observed vibrational bands at 679 and 862 cm−1 revealed the existence of the cubic MgO bonds. Surface morphology of the films was significantly affected by Al doping.
•Undoped and Al doped MgO films have been produced on glass substrates.•XRD analysis confirmed the cubic structure.•Al doping decreased optical band gaps of the MgO film.</description><subject>Absorption spectra</subject><subject>Al doping</subject><subject>Crystallites</subject><subject>Diffraction</subject><subject>Dopants</subject><subject>Fourier transforms</subject><subject>FT-IR</subject><subject>Infrared spectra</subject><subject>Infrared spectroscopy</subject><subject>Magnesium oxide</subject><subject>MgO films</subject><subject>Morphology</subject><subject>Optical properties</subject><subject>Scanning electron microscopy</subject><subject>Semiconductor doping</subject><subject>Sol-gel processes</subject><subject>Sol–gel spin coating</subject><subject>Spin coating</subject><subject>Thin films</subject><subject>X-ray diffraction</subject><issn>0921-4526</issn><issn>1873-2135</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwkAUhidGExF9AjeTuLV1zsx02i5cEAQkwZAQMO4m7Vy0DbR1ppCw8x18Q5_EAq49m7P5v3P5ELoFEgIB8VCGzcfe5yElkIZEhISSM9SDJGYBBRadox5JKQQ8ouISXXlfkq4ghh6ajKw1qvW4tniwxrpusqrFdYXfFk_3eLwMpgucVRqvXn--vneFx42rG-PawhyRl_c5tsV646_Rhc3W3tz89T5ajUfL4XMwm0-mw8EsUIxBGxijWa4tN4pomiqIKAhuuUo0F2CFig2HnDBIQAjDspxEPNEZybiObZQSxvro7jS3u-Nza3wry3rrqm6lpAx4HEWxgC7FTinlau-dsbJxxSZzewlEHozJUh6NyYMxSYTsjHXU44ky3QO7wjjpVWEqZXThOkdS18W__C_Kk3Ol</recordid><startdate>20191001</startdate><enddate>20191001</enddate><creator>Aksay, Sabiha</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20191001</creationdate><title>Effects of Al dopant on XRD, FT-IR and UV–vis properties of MgO films</title><author>Aksay, Sabiha</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c331t-eed3bdf4ec0d29c152164f4c8d461f6c7e41b0318166e3ab0548da0a4d7f59033</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Absorption spectra</topic><topic>Al doping</topic><topic>Crystallites</topic><topic>Diffraction</topic><topic>Dopants</topic><topic>Fourier transforms</topic><topic>FT-IR</topic><topic>Infrared spectra</topic><topic>Infrared spectroscopy</topic><topic>Magnesium oxide</topic><topic>MgO films</topic><topic>Morphology</topic><topic>Optical properties</topic><topic>Scanning electron microscopy</topic><topic>Semiconductor doping</topic><topic>Sol-gel processes</topic><topic>Sol–gel spin coating</topic><topic>Spin coating</topic><topic>Thin films</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Aksay, Sabiha</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Physica. B, Condensed matter</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aksay, Sabiha</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effects of Al dopant on XRD, FT-IR and UV–vis properties of MgO films</atitle><jtitle>Physica. B, Condensed matter</jtitle><date>2019-10-01</date><risdate>2019</risdate><volume>570</volume><spage>280</spage><epage>284</epage><pages>280-284</pages><issn>0921-4526</issn><eissn>1873-2135</eissn><abstract>Undoped and Al doped MgO films have been prepared by a sol–gel spin coating method. The crystalline structural, optical, vibrational and morphological properties of the Al doped MgO films were characterized by different techniques including scanning electron microscopy (SEM), X-ray diffraction (XRD), UV–vis absorption spectra, and Fourier transform infrared (FT-IR) measurements. XRD patterns confirm that the films were polycrystalline cubic nature. The crystallite size of the films slightly changed with increasing the Al dopant content. The optical band gap of the films was found to decrease from 3.92 to 3.84 eV by Al incorporation. The FT-IR spectroscopy confirms the presence of MgO. The observed vibrational bands at 679 and 862 cm−1 revealed the existence of the cubic MgO bonds. Surface morphology of the films was significantly affected by Al doping.
•Undoped and Al doped MgO films have been produced on glass substrates.•XRD analysis confirmed the cubic structure.•Al doping decreased optical band gaps of the MgO film.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.physb.2019.06.020</doi><tpages>5</tpages></addata></record> |
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subjects | Absorption spectra Al doping Crystallites Diffraction Dopants Fourier transforms FT-IR Infrared spectra Infrared spectroscopy Magnesium oxide MgO films Morphology Optical properties Scanning electron microscopy Semiconductor doping Sol-gel processes Sol–gel spin coating Spin coating Thin films X-ray diffraction |
title | Effects of Al dopant on XRD, FT-IR and UV–vis properties of MgO films |
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