MOF-derived cobalt-nickel phosphide nanoboxes as electrocatalysts for the hydrogen evolution reaction
The development of high-efficiency nonprecious electrocatalysts based on inexpensive and Earth abundant elements is of great significance for renewable energy technologies. Group VIII transition metal phosphides (TMPs) gradually stand out due to their intriguing properties including low resistance a...
Gespeichert in:
| Veröffentlicht in: | Nanoscale 2019-11, Vol.11 (44), p.21259-21265 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 21265 |
|---|---|
| container_issue | 44 |
| container_start_page | 21259 |
| container_title | Nanoscale |
| container_volume | 11 |
| creator | Lu, Yidong Deng, Yaoyao Lu, Shuanglong Liu, Yayuan Lang, Jianping Cao, Xueqin Gu, Hongwei |
| description | The development of high-efficiency nonprecious electrocatalysts based on inexpensive and Earth abundant elements is of great significance for renewable energy technologies. Group VIII transition metal phosphides (TMPs) gradually stand out due to their intriguing properties including low resistance and superior catalytic activity and stability. Herein, we adopt a unique MOF-derived strategy to synthesize transition metal phosphide nanoboxes which can be employed as electrocatalysts for the hydrogen evolution reaction. During this process, we converted a Co-MOF to a CoNi-MOF by ion exchange and low-temperature phosphating to achieve CoNiP nanoboxes. The CoNiP nanoboxes can reach a current density of 10 mA cm
−2
at a low overpotential of 138 mV with a small Tafel slope of 65 mV dec
−1
.
The CoNi-MOF which was synthesised using a Co-MOF was converted into a CoNiP nanobox by low temperature phosphating. The CoNiP nanobox exhibits outstanding catalytic activity and long durability for the HER in alkaline electrolytes. |
| doi_str_mv | 10.1039/c9nr07002h |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2314198285</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2310713442</sourcerecordid><originalsourceid>FETCH-LOGICAL-c351t-2c261054284895a812fa56bf728d4a51d522701587b8a3f9fe1530a4c6de1a5f3</originalsourceid><addsrcrecordid>eNpd0U1Lw0AQBuAgCtbqxbuw4EWE6H4mm6MUa4VqQfQcNpuJSd1m4-6m2H9vaqWCp3kPD8PwThSdE3xDMMtuddY6nGJM64NoRDHHMWMpPdznhB9HJ94vMU4ylrBRBE-LaVyCa9ZQIm0LZULcNvoDDOpq67u6KQG1qrWF_QKPlEdgQAdntQrKbHzwqLIOhRpQvSmdfYcWwdqaPjS2RQ6U3obT6KhSxsPZ7xxHb9P718ksni8eHid381gzQUJMNU0IFpxKLjOhJKGVEklRpVSWXAlSCkpTTIRMC6lYlVVABMOK66QEokTFxtHVbm_n7GcPPuSrxmswRrVge59TRnBKGOd0oJf_6NL2rh2u2ypOMkmlGNT1TmlnvXdQ5Z1rVsptcoLzbeP5JHt--Wl8NuCLHXZe793fR9g3upp9eg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2314198285</pqid></control><display><type>article</type><title>MOF-derived cobalt-nickel phosphide nanoboxes as electrocatalysts for the hydrogen evolution reaction</title><source>Royal Society Of Chemistry Journals 2008-</source><creator>Lu, Yidong ; Deng, Yaoyao ; Lu, Shuanglong ; Liu, Yayuan ; Lang, Jianping ; Cao, Xueqin ; Gu, Hongwei</creator><creatorcontrib>Lu, Yidong ; Deng, Yaoyao ; Lu, Shuanglong ; Liu, Yayuan ; Lang, Jianping ; Cao, Xueqin ; Gu, Hongwei</creatorcontrib><description>The development of high-efficiency nonprecious electrocatalysts based on inexpensive and Earth abundant elements is of great significance for renewable energy technologies. Group VIII transition metal phosphides (TMPs) gradually stand out due to their intriguing properties including low resistance and superior catalytic activity and stability. Herein, we adopt a unique MOF-derived strategy to synthesize transition metal phosphide nanoboxes which can be employed as electrocatalysts for the hydrogen evolution reaction. During this process, we converted a Co-MOF to a CoNi-MOF by ion exchange and low-temperature phosphating to achieve CoNiP nanoboxes. The CoNiP nanoboxes can reach a current density of 10 mA cm
−2
at a low overpotential of 138 mV with a small Tafel slope of 65 mV dec
−1
.
The CoNi-MOF which was synthesised using a Co-MOF was converted into a CoNiP nanobox by low temperature phosphating. The CoNiP nanobox exhibits outstanding catalytic activity and long durability for the HER in alkaline electrolytes.</description><identifier>ISSN: 2040-3364</identifier><identifier>EISSN: 2040-3372</identifier><identifier>DOI: 10.1039/c9nr07002h</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Catalytic activity ; Electrocatalysts ; Energy technology ; Hydrogen evolution reactions ; Ion exchange ; Low resistance ; Low temperature ; Metal-organic frameworks ; Nickel ; Phosphating (coating) ; Phosphides ; Transition metals</subject><ispartof>Nanoscale, 2019-11, Vol.11 (44), p.21259-21265</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c351t-2c261054284895a812fa56bf728d4a51d522701587b8a3f9fe1530a4c6de1a5f3</citedby><cites>FETCH-LOGICAL-c351t-2c261054284895a812fa56bf728d4a51d522701587b8a3f9fe1530a4c6de1a5f3</cites><orcidid>0000-0003-2942-7385 ; 0000-0001-9962-4662</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27929,27930</link.rule.ids></links><search><creatorcontrib>Lu, Yidong</creatorcontrib><creatorcontrib>Deng, Yaoyao</creatorcontrib><creatorcontrib>Lu, Shuanglong</creatorcontrib><creatorcontrib>Liu, Yayuan</creatorcontrib><creatorcontrib>Lang, Jianping</creatorcontrib><creatorcontrib>Cao, Xueqin</creatorcontrib><creatorcontrib>Gu, Hongwei</creatorcontrib><title>MOF-derived cobalt-nickel phosphide nanoboxes as electrocatalysts for the hydrogen evolution reaction</title><title>Nanoscale</title><description>The development of high-efficiency nonprecious electrocatalysts based on inexpensive and Earth abundant elements is of great significance for renewable energy technologies. Group VIII transition metal phosphides (TMPs) gradually stand out due to their intriguing properties including low resistance and superior catalytic activity and stability. Herein, we adopt a unique MOF-derived strategy to synthesize transition metal phosphide nanoboxes which can be employed as electrocatalysts for the hydrogen evolution reaction. During this process, we converted a Co-MOF to a CoNi-MOF by ion exchange and low-temperature phosphating to achieve CoNiP nanoboxes. The CoNiP nanoboxes can reach a current density of 10 mA cm
−2
at a low overpotential of 138 mV with a small Tafel slope of 65 mV dec
−1
.
The CoNi-MOF which was synthesised using a Co-MOF was converted into a CoNiP nanobox by low temperature phosphating. The CoNiP nanobox exhibits outstanding catalytic activity and long durability for the HER in alkaline electrolytes.</description><subject>Catalytic activity</subject><subject>Electrocatalysts</subject><subject>Energy technology</subject><subject>Hydrogen evolution reactions</subject><subject>Ion exchange</subject><subject>Low resistance</subject><subject>Low temperature</subject><subject>Metal-organic frameworks</subject><subject>Nickel</subject><subject>Phosphating (coating)</subject><subject>Phosphides</subject><subject>Transition metals</subject><issn>2040-3364</issn><issn>2040-3372</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpd0U1Lw0AQBuAgCtbqxbuw4EWE6H4mm6MUa4VqQfQcNpuJSd1m4-6m2H9vaqWCp3kPD8PwThSdE3xDMMtuddY6nGJM64NoRDHHMWMpPdznhB9HJ94vMU4ylrBRBE-LaVyCa9ZQIm0LZULcNvoDDOpq67u6KQG1qrWF_QKPlEdgQAdntQrKbHzwqLIOhRpQvSmdfYcWwdqaPjS2RQ6U3obT6KhSxsPZ7xxHb9P718ksni8eHid381gzQUJMNU0IFpxKLjOhJKGVEklRpVSWXAlSCkpTTIRMC6lYlVVABMOK66QEokTFxtHVbm_n7GcPPuSrxmswRrVge59TRnBKGOd0oJf_6NL2rh2u2ypOMkmlGNT1TmlnvXdQ5Z1rVsptcoLzbeP5JHt--Wl8NuCLHXZe793fR9g3upp9eg</recordid><startdate>20191128</startdate><enddate>20191128</enddate><creator>Lu, Yidong</creator><creator>Deng, Yaoyao</creator><creator>Lu, Shuanglong</creator><creator>Liu, Yayuan</creator><creator>Lang, Jianping</creator><creator>Cao, Xueqin</creator><creator>Gu, Hongwei</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-2942-7385</orcidid><orcidid>https://orcid.org/0000-0001-9962-4662</orcidid></search><sort><creationdate>20191128</creationdate><title>MOF-derived cobalt-nickel phosphide nanoboxes as electrocatalysts for the hydrogen evolution reaction</title><author>Lu, Yidong ; Deng, Yaoyao ; Lu, Shuanglong ; Liu, Yayuan ; Lang, Jianping ; Cao, Xueqin ; Gu, Hongwei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c351t-2c261054284895a812fa56bf728d4a51d522701587b8a3f9fe1530a4c6de1a5f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Catalytic activity</topic><topic>Electrocatalysts</topic><topic>Energy technology</topic><topic>Hydrogen evolution reactions</topic><topic>Ion exchange</topic><topic>Low resistance</topic><topic>Low temperature</topic><topic>Metal-organic frameworks</topic><topic>Nickel</topic><topic>Phosphating (coating)</topic><topic>Phosphides</topic><topic>Transition metals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lu, Yidong</creatorcontrib><creatorcontrib>Deng, Yaoyao</creatorcontrib><creatorcontrib>Lu, Shuanglong</creatorcontrib><creatorcontrib>Liu, Yayuan</creatorcontrib><creatorcontrib>Lang, Jianping</creatorcontrib><creatorcontrib>Cao, Xueqin</creatorcontrib><creatorcontrib>Gu, Hongwei</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Nanoscale</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lu, Yidong</au><au>Deng, Yaoyao</au><au>Lu, Shuanglong</au><au>Liu, Yayuan</au><au>Lang, Jianping</au><au>Cao, Xueqin</au><au>Gu, Hongwei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>MOF-derived cobalt-nickel phosphide nanoboxes as electrocatalysts for the hydrogen evolution reaction</atitle><jtitle>Nanoscale</jtitle><date>2019-11-28</date><risdate>2019</risdate><volume>11</volume><issue>44</issue><spage>21259</spage><epage>21265</epage><pages>21259-21265</pages><issn>2040-3364</issn><eissn>2040-3372</eissn><abstract>The development of high-efficiency nonprecious electrocatalysts based on inexpensive and Earth abundant elements is of great significance for renewable energy technologies. Group VIII transition metal phosphides (TMPs) gradually stand out due to their intriguing properties including low resistance and superior catalytic activity and stability. Herein, we adopt a unique MOF-derived strategy to synthesize transition metal phosphide nanoboxes which can be employed as electrocatalysts for the hydrogen evolution reaction. During this process, we converted a Co-MOF to a CoNi-MOF by ion exchange and low-temperature phosphating to achieve CoNiP nanoboxes. The CoNiP nanoboxes can reach a current density of 10 mA cm
−2
at a low overpotential of 138 mV with a small Tafel slope of 65 mV dec
−1
.
The CoNi-MOF which was synthesised using a Co-MOF was converted into a CoNiP nanobox by low temperature phosphating. The CoNiP nanobox exhibits outstanding catalytic activity and long durability for the HER in alkaline electrolytes.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c9nr07002h</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-2942-7385</orcidid><orcidid>https://orcid.org/0000-0001-9962-4662</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2040-3364 |
| ispartof | Nanoscale, 2019-11, Vol.11 (44), p.21259-21265 |
| issn | 2040-3364 2040-3372 |
| language | eng |
| recordid | cdi_proquest_journals_2314198285 |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Catalytic activity Electrocatalysts Energy technology Hydrogen evolution reactions Ion exchange Low resistance Low temperature Metal-organic frameworks Nickel Phosphating (coating) Phosphides Transition metals |
| title | MOF-derived cobalt-nickel phosphide nanoboxes as electrocatalysts for the hydrogen evolution reaction |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-15T12%3A40%3A59IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=MOF-derived%20cobalt-nickel%20phosphide%20nanoboxes%20as%20electrocatalysts%20for%20the%20hydrogen%20evolution%20reaction&rft.jtitle=Nanoscale&rft.au=Lu,%20Yidong&rft.date=2019-11-28&rft.volume=11&rft.issue=44&rft.spage=21259&rft.epage=21265&rft.pages=21259-21265&rft.issn=2040-3364&rft.eissn=2040-3372&rft_id=info:doi/10.1039/c9nr07002h&rft_dat=%3Cproquest_cross%3E2310713442%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2314198285&rft_id=info:pmid/&rfr_iscdi=true |