Ultrafine Fibers of Poly-(3-Hydroxybutyrate) with Zinc–Tetraphenylporphyrin Obtained by Electrospinning
Ultrathin fibers of poly(3-hydroxybutyrate) (PHB) with a zinc–tetraphenylporphyrin complex (0-5%) were obtained by electrospinning. Optical microscopy, differential scanning calorimetry, electron paramagnetic resonance, and x-ray structural analysis were used to study the structure of the fibers. It...
Gespeichert in:
| Veröffentlicht in: | Fibre chemistry 2019-07, Vol.51 (2), p.83-91 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 91 |
|---|---|
| container_issue | 2 |
| container_start_page | 83 |
| container_title | Fibre chemistry |
| container_volume | 51 |
| creator | Ol’khov, A. A. Karpova, S. G. Tyubaeva, P. M. Lobanov, A. V. Filatova, A. G. Iordanskii, A. L. |
| description | Ultrathin fibers of poly(3-hydroxybutyrate) (PHB) with a zinc–tetraphenylporphyrin complex (0-5%) were obtained by electrospinning. Optical microscopy, differential scanning calorimetry, electron paramagnetic resonance, and x-ray structural analysis were used to study the structure of the fibers. It was shown that addition of the ZnTPP complex to the PHB fiber increases the crystallinity and lowers the molecular mobility in the amorphous regions of the polymer. The action of heat on the fiber (annealing at 140°C) leads to significant increase of crystallinity and molecular mobility in the amorphous regions of fibers of PHB and of PHB with 1% of ZnTPP. With 3-5% content of the complexes the crystallinity of the fiber is substantially reduced. The results of the work make it possible to recommend the investigated materials for biomedical application as matrices with antibacterial activity |
| doi_str_mv | 10.1007/s10692-019-10063-y |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_journals_2313715198</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A605549078</galeid><sourcerecordid>A605549078</sourcerecordid><originalsourceid>FETCH-LOGICAL-c358t-24480968f51e15877808ccf63b982acc8aa8e8b58046d19c13089fc230c6c9493</originalsourceid><addsrcrecordid>eNp9kUFPHCEYhompiVv1D3iaxEt7YPsxDDNwNEa7TUz0oBcvhGFhl80II8ymcvM_-A_7S8p2mvTWcCCQ93m_782L0AWBJQHoviUCragxEIHLu6U4H6EFYR3FvBH0E1oAEIaBNeQEfU5pBwCiY2KB3NMwRWWdN9Wt601MVbDVQxgy_kLxKq9jeMv9fspRTeZr9dNN2-rZef3r_ePRFHDcGp-HMcRxm6Pz1X0_qeK1rvpc3QxGTzGk0Xnv_OYMHVs1JHP-9z5FT7c3j9crfHf__cf11R3WlPEJ103DQbTcMmII413HgWttW9oLXiutuVLc8J5xaNo1EZpQ4MLqmoJutShhT9Hl7DvG8Lo3aZK7sI--jJQ1JbQjjAheVMtZtVGDkc7bUNLoctbmxengjXXl_6oFxhoB3QGoZ0CXSCkaK8foXlTMkoA8dCDnDmTpQP7pQOYC0RlKRew3Jv7b5T_Ub_8ki5E</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2313715198</pqid></control><display><type>article</type><title>Ultrafine Fibers of Poly-(3-Hydroxybutyrate) with Zinc–Tetraphenylporphyrin Obtained by Electrospinning</title><source>SpringerLink Journals - AutoHoldings</source><creator>Ol’khov, A. A. ; Karpova, S. G. ; Tyubaeva, P. M. ; Lobanov, A. V. ; Filatova, A. G. ; Iordanskii, A. L.</creator><creatorcontrib>Ol’khov, A. A. ; Karpova, S. G. ; Tyubaeva, P. M. ; Lobanov, A. V. ; Filatova, A. G. ; Iordanskii, A. L.</creatorcontrib><description>Ultrathin fibers of poly(3-hydroxybutyrate) (PHB) with a zinc–tetraphenylporphyrin complex (0-5%) were obtained by electrospinning. Optical microscopy, differential scanning calorimetry, electron paramagnetic resonance, and x-ray structural analysis were used to study the structure of the fibers. It was shown that addition of the ZnTPP complex to the PHB fiber increases the crystallinity and lowers the molecular mobility in the amorphous regions of the polymer. The action of heat on the fiber (annealing at 140°C) leads to significant increase of crystallinity and molecular mobility in the amorphous regions of fibers of PHB and of PHB with 1% of ZnTPP. With 3-5% content of the complexes the crystallinity of the fiber is substantially reduced. The results of the work make it possible to recommend the investigated materials for biomedical application as matrices with antibacterial activity</description><identifier>ISSN: 0015-0541</identifier><identifier>EISSN: 1573-8493</identifier><identifier>DOI: 10.1007/s10692-019-10063-y</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Biomedical materials ; Calorimetry ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; Crystallinity ; Electron paramagnetic resonance ; Electrospinning ; Fibers ; Optical microscopy ; Organic Chemistry ; Polyhydroxybutyrate ; Polymer Sciences ; Polymers ; Structural analysis ; Ultrafines ; Zinc</subject><ispartof>Fibre chemistry, 2019-07, Vol.51 (2), p.83-91</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019</rights><rights>COPYRIGHT 2019 Springer</rights><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c358t-24480968f51e15877808ccf63b982acc8aa8e8b58046d19c13089fc230c6c9493</citedby><cites>FETCH-LOGICAL-c358t-24480968f51e15877808ccf63b982acc8aa8e8b58046d19c13089fc230c6c9493</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10692-019-10063-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10692-019-10063-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Ol’khov, A. A.</creatorcontrib><creatorcontrib>Karpova, S. G.</creatorcontrib><creatorcontrib>Tyubaeva, P. M.</creatorcontrib><creatorcontrib>Lobanov, A. V.</creatorcontrib><creatorcontrib>Filatova, A. G.</creatorcontrib><creatorcontrib>Iordanskii, A. L.</creatorcontrib><title>Ultrafine Fibers of Poly-(3-Hydroxybutyrate) with Zinc–Tetraphenylporphyrin Obtained by Electrospinning</title><title>Fibre chemistry</title><addtitle>Fibre Chem</addtitle><description>Ultrathin fibers of poly(3-hydroxybutyrate) (PHB) with a zinc–tetraphenylporphyrin complex (0-5%) were obtained by electrospinning. Optical microscopy, differential scanning calorimetry, electron paramagnetic resonance, and x-ray structural analysis were used to study the structure of the fibers. It was shown that addition of the ZnTPP complex to the PHB fiber increases the crystallinity and lowers the molecular mobility in the amorphous regions of the polymer. The action of heat on the fiber (annealing at 140°C) leads to significant increase of crystallinity and molecular mobility in the amorphous regions of fibers of PHB and of PHB with 1% of ZnTPP. With 3-5% content of the complexes the crystallinity of the fiber is substantially reduced. The results of the work make it possible to recommend the investigated materials for biomedical application as matrices with antibacterial activity</description><subject>Biomedical materials</subject><subject>Calorimetry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Crystallinity</subject><subject>Electron paramagnetic resonance</subject><subject>Electrospinning</subject><subject>Fibers</subject><subject>Optical microscopy</subject><subject>Organic Chemistry</subject><subject>Polyhydroxybutyrate</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Structural analysis</subject><subject>Ultrafines</subject><subject>Zinc</subject><issn>0015-0541</issn><issn>1573-8493</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kUFPHCEYhompiVv1D3iaxEt7YPsxDDNwNEa7TUz0oBcvhGFhl80II8ymcvM_-A_7S8p2mvTWcCCQ93m_782L0AWBJQHoviUCragxEIHLu6U4H6EFYR3FvBH0E1oAEIaBNeQEfU5pBwCiY2KB3NMwRWWdN9Wt601MVbDVQxgy_kLxKq9jeMv9fspRTeZr9dNN2-rZef3r_ePRFHDcGp-HMcRxm6Pz1X0_qeK1rvpc3QxGTzGk0Xnv_OYMHVs1JHP-9z5FT7c3j9crfHf__cf11R3WlPEJ103DQbTcMmII413HgWttW9oLXiutuVLc8J5xaNo1EZpQ4MLqmoJutShhT9Hl7DvG8Lo3aZK7sI--jJQ1JbQjjAheVMtZtVGDkc7bUNLoctbmxengjXXl_6oFxhoB3QGoZ0CXSCkaK8foXlTMkoA8dCDnDmTpQP7pQOYC0RlKRew3Jv7b5T_Ub_8ki5E</recordid><startdate>20190701</startdate><enddate>20190701</enddate><creator>Ol’khov, A. A.</creator><creator>Karpova, S. G.</creator><creator>Tyubaeva, P. M.</creator><creator>Lobanov, A. V.</creator><creator>Filatova, A. G.</creator><creator>Iordanskii, A. L.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope></search><sort><creationdate>20190701</creationdate><title>Ultrafine Fibers of Poly-(3-Hydroxybutyrate) with Zinc–Tetraphenylporphyrin Obtained by Electrospinning</title><author>Ol’khov, A. A. ; Karpova, S. G. ; Tyubaeva, P. M. ; Lobanov, A. V. ; Filatova, A. G. ; Iordanskii, A. L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-24480968f51e15877808ccf63b982acc8aa8e8b58046d19c13089fc230c6c9493</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Biomedical materials</topic><topic>Calorimetry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Crystallinity</topic><topic>Electron paramagnetic resonance</topic><topic>Electrospinning</topic><topic>Fibers</topic><topic>Optical microscopy</topic><topic>Organic Chemistry</topic><topic>Polyhydroxybutyrate</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Structural analysis</topic><topic>Ultrafines</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ol’khov, A. A.</creatorcontrib><creatorcontrib>Karpova, S. G.</creatorcontrib><creatorcontrib>Tyubaeva, P. M.</creatorcontrib><creatorcontrib>Lobanov, A. V.</creatorcontrib><creatorcontrib>Filatova, A. G.</creatorcontrib><creatorcontrib>Iordanskii, A. L.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><jtitle>Fibre chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ol’khov, A. A.</au><au>Karpova, S. G.</au><au>Tyubaeva, P. M.</au><au>Lobanov, A. V.</au><au>Filatova, A. G.</au><au>Iordanskii, A. L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ultrafine Fibers of Poly-(3-Hydroxybutyrate) with Zinc–Tetraphenylporphyrin Obtained by Electrospinning</atitle><jtitle>Fibre chemistry</jtitle><stitle>Fibre Chem</stitle><date>2019-07-01</date><risdate>2019</risdate><volume>51</volume><issue>2</issue><spage>83</spage><epage>91</epage><pages>83-91</pages><issn>0015-0541</issn><eissn>1573-8493</eissn><abstract>Ultrathin fibers of poly(3-hydroxybutyrate) (PHB) with a zinc–tetraphenylporphyrin complex (0-5%) were obtained by electrospinning. Optical microscopy, differential scanning calorimetry, electron paramagnetic resonance, and x-ray structural analysis were used to study the structure of the fibers. It was shown that addition of the ZnTPP complex to the PHB fiber increases the crystallinity and lowers the molecular mobility in the amorphous regions of the polymer. The action of heat on the fiber (annealing at 140°C) leads to significant increase of crystallinity and molecular mobility in the amorphous regions of fibers of PHB and of PHB with 1% of ZnTPP. With 3-5% content of the complexes the crystallinity of the fiber is substantially reduced. The results of the work make it possible to recommend the investigated materials for biomedical application as matrices with antibacterial activity</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10692-019-10063-y</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0015-0541 |
| ispartof | Fibre chemistry, 2019-07, Vol.51 (2), p.83-91 |
| issn | 0015-0541 1573-8493 |
| language | eng |
| recordid | cdi_proquest_journals_2313715198 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Biomedical materials Calorimetry Chemistry Chemistry and Materials Science Crystal structure Crystallinity Electron paramagnetic resonance Electrospinning Fibers Optical microscopy Organic Chemistry Polyhydroxybutyrate Polymer Sciences Polymers Structural analysis Ultrafines Zinc |
| title | Ultrafine Fibers of Poly-(3-Hydroxybutyrate) with Zinc–Tetraphenylporphyrin Obtained by Electrospinning |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-19T16%3A27%3A06IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_proqu&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Ultrafine%20Fibers%20of%20Poly-(3-Hydroxybutyrate)%20with%20Zinc%E2%80%93Tetraphenylporphyrin%20Obtained%20by%20Electrospinning&rft.jtitle=Fibre%20chemistry&rft.au=Ol%E2%80%99khov,%20A.%20A.&rft.date=2019-07-01&rft.volume=51&rft.issue=2&rft.spage=83&rft.epage=91&rft.pages=83-91&rft.issn=0015-0541&rft.eissn=1573-8493&rft_id=info:doi/10.1007/s10692-019-10063-y&rft_dat=%3Cgale_proqu%3EA605549078%3C/gale_proqu%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2313715198&rft_id=info:pmid/&rft_galeid=A605549078&rfr_iscdi=true |