Functionalization of graphene oxide by radiation grafting polyhedral oligomeric silsesquioxane with improved thermal stability and hydrophilicity
Functionalization of graphene oxide (GO) with octavinyl polyhedral oligomeric silsesquioxane (OvPOSS) is achieved by gamma-ray radiation-induced grafting under mild conditions. The grafting yield of OvPOSS-grafted GO (GOP), calculated by the content of silicon in GOP using X-ray photoelectron spectr...
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| Veröffentlicht in: | Journal of materials science 2020-02, Vol.55 (4), p.1489-1498 |
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| creator | Shi, Mengni Lin, Tingrui Hu, Yang Peng, Jing Li, Jiuqiang Zhai, Maolin |
| description | Functionalization of graphene oxide (GO) with octavinyl polyhedral oligomeric silsesquioxane (OvPOSS) is achieved by gamma-ray radiation-induced grafting under mild conditions. The grafting yield of OvPOSS-grafted GO (GOP), calculated by the content of silicon in GOP using X-ray photoelectron spectroscopy, increases gradually with the increase in the absorbed dose. The grafting of OvPOSS onto GO not only improves its thermal stability, but also increases its distance between the adjacent graphitic layers which could improve the reactivity of GO. In contrary to the hydrophobic GOP prepared via the traditional chemical method, it dramatically becomes more hydrophilic with the increase in the absorbed dose due to the introduction of nitrogen-containing group under irradiation, and the surface of GOP becomes super-hydrophilic at an absorbed dose of 50 kGy. Furthermore, GOP still has excellent electrical insulation property due to the grafting of insulated OvPOSS. Consequently, this work paves a feasible and green way for the functionalization of GO with improved performances. |
| doi_str_mv | 10.1007/s10853-019-04098-z |
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The grafting yield of OvPOSS-grafted GO (GOP), calculated by the content of silicon in GOP using X-ray photoelectron spectroscopy, increases gradually with the increase in the absorbed dose. The grafting of OvPOSS onto GO not only improves its thermal stability, but also increases its distance between the adjacent graphitic layers which could improve the reactivity of GO. In contrary to the hydrophobic GOP prepared via the traditional chemical method, it dramatically becomes more hydrophilic with the increase in the absorbed dose due to the introduction of nitrogen-containing group under irradiation, and the surface of GOP becomes super-hydrophilic at an absorbed dose of 50 kGy. Furthermore, GOP still has excellent electrical insulation property due to the grafting of insulated OvPOSS. Consequently, this work paves a feasible and green way for the functionalization of GO with improved performances.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-019-04098-z</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Boron nitride ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Classical Mechanics ; Composites & Nanocomposites ; Crystallography and Scattering Methods ; Electrical insulation ; Gamma rays ; Grafting ; Graphene ; Graphite ; Hydrophilicity ; Materials Science ; Organic chemistry ; Performance enhancement ; Photoelectrons ; Political aspects ; Polyhedral oligomeric silsesquioxane ; Polymer Sciences ; Radiation effects ; Solid Mechanics ; Thermal stability ; X-ray spectroscopy</subject><ispartof>Journal of materials science, 2020-02, Vol.55 (4), p.1489-1498</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019</rights><rights>COPYRIGHT 2020 Springer</rights><rights>Journal of Materials Science is a copyright of Springer, (2019). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c392t-46bba09998d7fe76a275323ba33b67ebc2a5ee1dba577774bd700c1c4808e3043</citedby><cites>FETCH-LOGICAL-c392t-46bba09998d7fe76a275323ba33b67ebc2a5ee1dba577774bd700c1c4808e3043</cites><orcidid>0000-0002-6038-3512 ; 0000-0003-4804-5745 ; 0000-0002-5922-4899 ; 0000-0003-4727-5864 ; 0000-0003-1564-2527 ; 0000-0003-2294-9682</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-019-04098-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-019-04098-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Shi, Mengni</creatorcontrib><creatorcontrib>Lin, Tingrui</creatorcontrib><creatorcontrib>Hu, Yang</creatorcontrib><creatorcontrib>Peng, Jing</creatorcontrib><creatorcontrib>Li, Jiuqiang</creatorcontrib><creatorcontrib>Zhai, Maolin</creatorcontrib><title>Functionalization of graphene oxide by radiation grafting polyhedral oligomeric silsesquioxane with improved thermal stability and hydrophilicity</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>Functionalization of graphene oxide (GO) with octavinyl polyhedral oligomeric silsesquioxane (OvPOSS) is achieved by gamma-ray radiation-induced grafting under mild conditions. The grafting yield of OvPOSS-grafted GO (GOP), calculated by the content of silicon in GOP using X-ray photoelectron spectroscopy, increases gradually with the increase in the absorbed dose. The grafting of OvPOSS onto GO not only improves its thermal stability, but also increases its distance between the adjacent graphitic layers which could improve the reactivity of GO. In contrary to the hydrophobic GOP prepared via the traditional chemical method, it dramatically becomes more hydrophilic with the increase in the absorbed dose due to the introduction of nitrogen-containing group under irradiation, and the surface of GOP becomes super-hydrophilic at an absorbed dose of 50 kGy. Furthermore, GOP still has excellent electrical insulation property due to the grafting of insulated OvPOSS. 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| subjects | Boron nitride Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Composites & Nanocomposites Crystallography and Scattering Methods Electrical insulation Gamma rays Grafting Graphene Graphite Hydrophilicity Materials Science Organic chemistry Performance enhancement Photoelectrons Political aspects Polyhedral oligomeric silsesquioxane Polymer Sciences Radiation effects Solid Mechanics Thermal stability X-ray spectroscopy |
| title | Functionalization of graphene oxide by radiation grafting polyhedral oligomeric silsesquioxane with improved thermal stability and hydrophilicity |
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