Degradation of tetracycline by a novel MIL-101(Fe)/TiO2 composite with persulfate
An effective catalyst of MIL-101(Fe)/TiO 2 composite was synthesized by solvothermal method. The resultant MIL-101(Fe)/TiO 2 was used for advanced oxidation degradation of tetracycline (TC) for the first time. The results indicated that the MIL-101(Fe)/TiO 2 showed higher TC degradation efficiency t...
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| Veröffentlicht in: | Journal of porous materials 2019-12, Vol.26 (6), p.1839-1850 |
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| container_title | Journal of porous materials |
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| creator | He, Lei Zhang, Yaqin Zheng, Yane Jia, Qingming Shan, Shaoyun Dong, Yanan |
| description | An effective catalyst of MIL-101(Fe)/TiO
2
composite was synthesized by solvothermal method. The resultant MIL-101(Fe)/TiO
2
was used for advanced oxidation degradation of tetracycline (TC) for the first time. The results indicated that the MIL-101(Fe)/TiO
2
showed higher TC degradation efficiency than pure MIL-101(Fe) or TiO
2
with the persulfate. Using 1 g L
−1
MIL-101(Fe)/TiO
2
and persulfate at pH 7, 90.15% degradation rate was achieved under xenon lamp irradiation in 5 min for 20 mg L
−1
TC. TiO
2
introduced in the composite played an important role in the degradation process, in which TiO
2
had a synergetic effect with Fe
3+
to generate Fe
2+
, Ti
3+
and radicals. Fe
2+
reacted with persulfate to produce Fe
3+
and a number of
·
OH to degrade TC. This reaction process was so fast that MIL-101(Fe)/TiO
2
with persulfate could degrade TC fairly rapidly. A novel TiO
2
-based metal–organic frameworks (MOFs) composite was more efficient for degrading pharmaceutical wastewater. |
| doi_str_mv | 10.1007/s10934-019-00778-y |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2313382975</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2313382975</sourcerecordid><originalsourceid>FETCH-LOGICAL-c356t-7b8c2aab1556c4fb906eaffb5ba10b338ff11d02c4c558dc27078fad7ff3dba93</originalsourceid><addsrcrecordid>eNp9kM1KAzEURoMoWKsv4CrgRhex-Zk0maVUq4VKEeo6JJmkTpnO1CRV5u2NjuDO1b0XzvddOABcEnxLMBaTSHDJCoRJifIpJOqPwIhwwVAheXGcdyYxopQWp-Asxi3GuJRCjMDLvdsEXelUdy3sPEwuBW1729Stg6aHGrbdh2vg82KJCCbXc3czWdcrCm2323exTg5-1ukN7l2Ih8br5M7BiddNdBe_cwxe5w_r2RNarh4Xs7slsoxPExJGWqq1IZxPbeFNiadOe2-40QQbxqT3hFSY2sJyLitLBRbS60p4zyqjSzYGV0PvPnTvBxeT2naH0OaXijKSC2gpeKboQNnQxRicV_tQ73ToFcHqW50a1KmsTv2oU30OsSEUM9xuXPir_if1BftHcbQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2313382975</pqid></control><display><type>article</type><title>Degradation of tetracycline by a novel MIL-101(Fe)/TiO2 composite with persulfate</title><source>Springer Nature - Complete Springer Journals</source><creator>He, Lei ; Zhang, Yaqin ; Zheng, Yane ; Jia, Qingming ; Shan, Shaoyun ; Dong, Yanan</creator><creatorcontrib>He, Lei ; Zhang, Yaqin ; Zheng, Yane ; Jia, Qingming ; Shan, Shaoyun ; Dong, Yanan</creatorcontrib><description>An effective catalyst of MIL-101(Fe)/TiO
2
composite was synthesized by solvothermal method. The resultant MIL-101(Fe)/TiO
2
was used for advanced oxidation degradation of tetracycline (TC) for the first time. The results indicated that the MIL-101(Fe)/TiO
2
showed higher TC degradation efficiency than pure MIL-101(Fe) or TiO
2
with the persulfate. Using 1 g L
−1
MIL-101(Fe)/TiO
2
and persulfate at pH 7, 90.15% degradation rate was achieved under xenon lamp irradiation in 5 min for 20 mg L
−1
TC. TiO
2
introduced in the composite played an important role in the degradation process, in which TiO
2
had a synergetic effect with Fe
3+
to generate Fe
2+
, Ti
3+
and radicals. Fe
2+
reacted with persulfate to produce Fe
3+
and a number of
·
OH to degrade TC. This reaction process was so fast that MIL-101(Fe)/TiO
2
with persulfate could degrade TC fairly rapidly. A novel TiO
2
-based metal–organic frameworks (MOFs) composite was more efficient for degrading pharmaceutical wastewater.</description><identifier>ISSN: 1380-2224</identifier><identifier>EISSN: 1573-4854</identifier><identifier>DOI: 10.1007/s10934-019-00778-y</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Catalysis ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Degradation ; Metal-organic frameworks ; Oxidation ; Physical Chemistry ; Titanium dioxide ; Wastewater ; Xenon lamps</subject><ispartof>Journal of porous materials, 2019-12, Vol.26 (6), p.1839-1850</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019</rights><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-7b8c2aab1556c4fb906eaffb5ba10b338ff11d02c4c558dc27078fad7ff3dba93</citedby><cites>FETCH-LOGICAL-c356t-7b8c2aab1556c4fb906eaffb5ba10b338ff11d02c4c558dc27078fad7ff3dba93</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10934-019-00778-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10934-019-00778-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51298</link.rule.ids></links><search><creatorcontrib>He, Lei</creatorcontrib><creatorcontrib>Zhang, Yaqin</creatorcontrib><creatorcontrib>Zheng, Yane</creatorcontrib><creatorcontrib>Jia, Qingming</creatorcontrib><creatorcontrib>Shan, Shaoyun</creatorcontrib><creatorcontrib>Dong, Yanan</creatorcontrib><title>Degradation of tetracycline by a novel MIL-101(Fe)/TiO2 composite with persulfate</title><title>Journal of porous materials</title><addtitle>J Porous Mater</addtitle><description>An effective catalyst of MIL-101(Fe)/TiO
2
composite was synthesized by solvothermal method. The resultant MIL-101(Fe)/TiO
2
was used for advanced oxidation degradation of tetracycline (TC) for the first time. The results indicated that the MIL-101(Fe)/TiO
2
showed higher TC degradation efficiency than pure MIL-101(Fe) or TiO
2
with the persulfate. Using 1 g L
−1
MIL-101(Fe)/TiO
2
and persulfate at pH 7, 90.15% degradation rate was achieved under xenon lamp irradiation in 5 min for 20 mg L
−1
TC. TiO
2
introduced in the composite played an important role in the degradation process, in which TiO
2
had a synergetic effect with Fe
3+
to generate Fe
2+
, Ti
3+
and radicals. Fe
2+
reacted with persulfate to produce Fe
3+
and a number of
·
OH to degrade TC. This reaction process was so fast that MIL-101(Fe)/TiO
2
with persulfate could degrade TC fairly rapidly. A novel TiO
2
-based metal–organic frameworks (MOFs) composite was more efficient for degrading pharmaceutical wastewater.</description><subject>Catalysis</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Degradation</subject><subject>Metal-organic frameworks</subject><subject>Oxidation</subject><subject>Physical Chemistry</subject><subject>Titanium dioxide</subject><subject>Wastewater</subject><subject>Xenon lamps</subject><issn>1380-2224</issn><issn>1573-4854</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kM1KAzEURoMoWKsv4CrgRhex-Zk0maVUq4VKEeo6JJmkTpnO1CRV5u2NjuDO1b0XzvddOABcEnxLMBaTSHDJCoRJifIpJOqPwIhwwVAheXGcdyYxopQWp-Asxi3GuJRCjMDLvdsEXelUdy3sPEwuBW1729Stg6aHGrbdh2vg82KJCCbXc3czWdcrCm2323exTg5-1ukN7l2Ih8br5M7BiddNdBe_cwxe5w_r2RNarh4Xs7slsoxPExJGWqq1IZxPbeFNiadOe2-40QQbxqT3hFSY2sJyLitLBRbS60p4zyqjSzYGV0PvPnTvBxeT2naH0OaXijKSC2gpeKboQNnQxRicV_tQ73ToFcHqW50a1KmsTv2oU30OsSEUM9xuXPir_if1BftHcbQ</recordid><startdate>20191201</startdate><enddate>20191201</enddate><creator>He, Lei</creator><creator>Zhang, Yaqin</creator><creator>Zheng, Yane</creator><creator>Jia, Qingming</creator><creator>Shan, Shaoyun</creator><creator>Dong, Yanan</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20191201</creationdate><title>Degradation of tetracycline by a novel MIL-101(Fe)/TiO2 composite with persulfate</title><author>He, Lei ; Zhang, Yaqin ; Zheng, Yane ; Jia, Qingming ; Shan, Shaoyun ; Dong, Yanan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-7b8c2aab1556c4fb906eaffb5ba10b338ff11d02c4c558dc27078fad7ff3dba93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Catalysis</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Degradation</topic><topic>Metal-organic frameworks</topic><topic>Oxidation</topic><topic>Physical Chemistry</topic><topic>Titanium dioxide</topic><topic>Wastewater</topic><topic>Xenon lamps</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>He, Lei</creatorcontrib><creatorcontrib>Zhang, Yaqin</creatorcontrib><creatorcontrib>Zheng, Yane</creatorcontrib><creatorcontrib>Jia, Qingming</creatorcontrib><creatorcontrib>Shan, Shaoyun</creatorcontrib><creatorcontrib>Dong, Yanan</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of porous materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>He, Lei</au><au>Zhang, Yaqin</au><au>Zheng, Yane</au><au>Jia, Qingming</au><au>Shan, Shaoyun</au><au>Dong, Yanan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Degradation of tetracycline by a novel MIL-101(Fe)/TiO2 composite with persulfate</atitle><jtitle>Journal of porous materials</jtitle><stitle>J Porous Mater</stitle><date>2019-12-01</date><risdate>2019</risdate><volume>26</volume><issue>6</issue><spage>1839</spage><epage>1850</epage><pages>1839-1850</pages><issn>1380-2224</issn><eissn>1573-4854</eissn><abstract>An effective catalyst of MIL-101(Fe)/TiO
2
composite was synthesized by solvothermal method. The resultant MIL-101(Fe)/TiO
2
was used for advanced oxidation degradation of tetracycline (TC) for the first time. The results indicated that the MIL-101(Fe)/TiO
2
showed higher TC degradation efficiency than pure MIL-101(Fe) or TiO
2
with the persulfate. Using 1 g L
−1
MIL-101(Fe)/TiO
2
and persulfate at pH 7, 90.15% degradation rate was achieved under xenon lamp irradiation in 5 min for 20 mg L
−1
TC. TiO
2
introduced in the composite played an important role in the degradation process, in which TiO
2
had a synergetic effect with Fe
3+
to generate Fe
2+
, Ti
3+
and radicals. Fe
2+
reacted with persulfate to produce Fe
3+
and a number of
·
OH to degrade TC. This reaction process was so fast that MIL-101(Fe)/TiO
2
with persulfate could degrade TC fairly rapidly. A novel TiO
2
-based metal–organic frameworks (MOFs) composite was more efficient for degrading pharmaceutical wastewater.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10934-019-00778-y</doi><tpages>12</tpages></addata></record> |
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| issn | 1380-2224 1573-4854 |
| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Catalysis Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Degradation Metal-organic frameworks Oxidation Physical Chemistry Titanium dioxide Wastewater Xenon lamps |
| title | Degradation of tetracycline by a novel MIL-101(Fe)/TiO2 composite with persulfate |
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