Pushing the Lewis Acidity Boundaries of Boron Compounds With Non‐Planar Triarylboranes Derived from Triptycenes

Bending the planar trigonal boron center of triphenylborane by connecting its aryl rings with carbon or phosphorus linkers gave access to a series of 9‐boratriptycene derivatives with unprecedented structures and reactivities. NMR spectroscopy and X‐ray diffraction of the Lewis adducts of these non‐...

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Veröffentlicht in:Angewandte Chemie 2019-11, Vol.131 (47), p.17045-17049
Hauptverfasser: Ben Saida, Ali, Chardon, Aurélien, Osi, Arnaud, Tumanov, Nikolay, Wouters, Johan, Adjieufack, Abel I., Champagne, Benoît, Berionni, Guillaume
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Sprache:eng
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