Synthesis of a Redox-active Metal–Organic Framework MIL-116(Fe) and Its Lithium Ion Battery Cathode Properties

Synthesis of a Redox-active Metal–Organic Framework MIL-116(Fe) and Its Lithium Ion Battery Cathode Properties

A metal–organic framework of iron (III) and mellitic acid was synthesized. The crystal structure of the MOF determined by single crystal X-ray analysis was isostructural to MIL-116. It was applied as a lithium-ion battery cathode active material and showed a performance of ca. 100 mAh/g after 60 cyc...

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Veröffentlicht in:Chemistry letters 2019-11, Vol.48 (11), p.1379-1382
Hauptverfasser: Yamada, Teppei, Shiraishi, Kanji, Kimizuka, Nobuo
Format: Artikel
Sprache:eng
Schlagworte:
Cathodes
Crystal structure
Iron
Lithium
Lithium-ion batteries
Metal-organic frameworks
Rechargeable batteries
Single crystals
X ray analysis
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Zusammenfassung:A metal–organic framework of iron (III) and mellitic acid was synthesized. The crystal structure of the MOF determined by single crystal X-ray analysis was isostructural to MIL-116. It was applied as a lithium-ion battery cathode active material and showed a performance of ca. 100 mAh/g after 60 cycles. It also showed capacitance of 43 mAh/g at a 10 C rate.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.190613