Characterization of bio-crude components derived from pyrolysis of soft wood and its esterified product by ultrahigh resolution mass spectrometry and spectroscopic techniques
[Display omitted] In this work, a detailed analysis of a bio-oil obtained by pyrolysis of softwoods and its esterified product is described. Information of the type of chemical function groups were obtained by 13C and 1H nuclear magnetic resonance (NMR) and Fourier transform infrared spectroscopy (F...
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| Veröffentlicht in: | Fuel (Guildford) 2020-01, Vol.259, p.116085, Article 116085 |
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| creator | Palacio Lozano, Diana Catalina Ramírez, Claudia X. Sarmiento Chaparro, José Aristóbulo Thomas, Mary J. Gavard, Remy Jones, Hugh E. Cabanzo Hernández, Rafael Mejia-Ospino, Enrique Barrow, Mark P. |
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In this work, a detailed analysis of a bio-oil obtained by pyrolysis of softwoods and its esterified product is described. Information of the type of chemical function groups were obtained by 13C and 1H nuclear magnetic resonance (NMR) and Fourier transform infrared spectroscopy (FT-IR) and compositional analysis was obtained by Fourier transform ion cyclotron resonance mass spectrometry (FTICR MS). The results obtained indicate that aliphatic hydrogen and carbon atoms are found in higher abundance, compared with aromatic hydrogen-carbon frameworks. Furthermore, a decrease in oxygen functional groups was observed after esterification. According to the FTICR MS results, the samples contain highly oxygenated species corresponding to compound classes Ox, NOx and BOx, with a high predominance of Ox species. After esterification, the compositions shifted towards lower oxygen-content, lower number of rings and double bonds, and longer alkyl chains as a consequence of the water removal via the condensation reaction. |
| doi_str_mv | 10.1016/j.fuel.2019.116085 |
| format | Article |
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In this work, a detailed analysis of a bio-oil obtained by pyrolysis of softwoods and its esterified product is described. Information of the type of chemical function groups were obtained by 13C and 1H nuclear magnetic resonance (NMR) and Fourier transform infrared spectroscopy (FT-IR) and compositional analysis was obtained by Fourier transform ion cyclotron resonance mass spectrometry (FTICR MS). The results obtained indicate that aliphatic hydrogen and carbon atoms are found in higher abundance, compared with aromatic hydrogen-carbon frameworks. Furthermore, a decrease in oxygen functional groups was observed after esterification. According to the FTICR MS results, the samples contain highly oxygenated species corresponding to compound classes Ox, NOx and BOx, with a high predominance of Ox species. After esterification, the compositions shifted towards lower oxygen-content, lower number of rings and double bonds, and longer alkyl chains as a consequence of the water removal via the condensation reaction.</description><identifier>ISSN: 0016-2361</identifier><identifier>EISSN: 1873-7153</identifier><identifier>DOI: 10.1016/j.fuel.2019.116085</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Aliphatic compounds ; Bio-oils ; Carbon ; Condensates ; Cyclotron resonance ; Esterification ; Fourier analysis ; Fourier transforms ; Functional groups ; Infrared analysis ; Infrared spectroscopy ; Ions ; Mass spectrometry ; Mass spectroscopy ; NMR ; Nuclear magnetic resonance ; Organic chemistry ; Oxygen ; Pyrolysis ; Resonance ; Scientific imaging ; Softwoods ; Spectroscopy ; Ultrahigh resolution mass spectrometry ; Water treatment</subject><ispartof>Fuel (Guildford), 2020-01, Vol.259, p.116085, Article 116085</ispartof><rights>2019 Elsevier Ltd</rights><rights>Copyright Elsevier BV Jan 1, 2020</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c409t-d66c71fb3d3938eab16bd4c0c6e3830915e19242ecce3ad2cec74dcca8139f153</citedby><cites>FETCH-LOGICAL-c409t-d66c71fb3d3938eab16bd4c0c6e3830915e19242ecce3ad2cec74dcca8139f153</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.fuel.2019.116085$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3548,27923,27924,45994</link.rule.ids></links><search><creatorcontrib>Palacio Lozano, Diana Catalina</creatorcontrib><creatorcontrib>Ramírez, Claudia X.</creatorcontrib><creatorcontrib>Sarmiento Chaparro, José Aristóbulo</creatorcontrib><creatorcontrib>Thomas, Mary J.</creatorcontrib><creatorcontrib>Gavard, Remy</creatorcontrib><creatorcontrib>Jones, Hugh E.</creatorcontrib><creatorcontrib>Cabanzo Hernández, Rafael</creatorcontrib><creatorcontrib>Mejia-Ospino, Enrique</creatorcontrib><creatorcontrib>Barrow, Mark P.</creatorcontrib><title>Characterization of bio-crude components derived from pyrolysis of soft wood and its esterified product by ultrahigh resolution mass spectrometry and spectroscopic techniques</title><title>Fuel (Guildford)</title><description>[Display omitted]
In this work, a detailed analysis of a bio-oil obtained by pyrolysis of softwoods and its esterified product is described. Information of the type of chemical function groups were obtained by 13C and 1H nuclear magnetic resonance (NMR) and Fourier transform infrared spectroscopy (FT-IR) and compositional analysis was obtained by Fourier transform ion cyclotron resonance mass spectrometry (FTICR MS). The results obtained indicate that aliphatic hydrogen and carbon atoms are found in higher abundance, compared with aromatic hydrogen-carbon frameworks. Furthermore, a decrease in oxygen functional groups was observed after esterification. According to the FTICR MS results, the samples contain highly oxygenated species corresponding to compound classes Ox, NOx and BOx, with a high predominance of Ox species. After esterification, the compositions shifted towards lower oxygen-content, lower number of rings and double bonds, and longer alkyl chains as a consequence of the water removal via the condensation reaction.</description><subject>Aliphatic compounds</subject><subject>Bio-oils</subject><subject>Carbon</subject><subject>Condensates</subject><subject>Cyclotron resonance</subject><subject>Esterification</subject><subject>Fourier analysis</subject><subject>Fourier transforms</subject><subject>Functional groups</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Ions</subject><subject>Mass spectrometry</subject><subject>Mass spectroscopy</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Organic chemistry</subject><subject>Oxygen</subject><subject>Pyrolysis</subject><subject>Resonance</subject><subject>Scientific imaging</subject><subject>Softwoods</subject><subject>Spectroscopy</subject><subject>Ultrahigh resolution mass spectrometry</subject><subject>Water treatment</subject><issn>0016-2361</issn><issn>1873-7153</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kc1K7DAYhoMcwTnqDbgKuO6YNP0FNzJ4VBDc6DqkX744GTpNTVKl56K8RlPHtatAeN6f5CXkgrM1Z7y62q3NhP06Z7xdc16xpjwiK97UIqt5Kf6QFUtUlouKn5C_IewYY3VTFivyudkqryCit_9VtG6gztDOugz8pJGC249uwCEGqhPyjpoa7_Z0nL3r52DDggdnIv1wTlM1aGoTi2ExNDbho3d6gki7mU599GprX7fUY3D99B23VyHQMCLE5IvRz98mPxcB3GiBRoTtYN8mDGfk2Kg-4PnPeUpe_t0-b-6zx6e7h83NYwYFa2OmqwpqbjqhRSsaVB2vOl0AgwpFI1jLS-RtXuQIgELpHBDqQgOohovWpB87JZcH31R_yY1y5yY_pEiZC56XLKkXKj9QkKoGj0aO3u6VnyVnctlF7uSyi1x2kYddkuj6IMLU_92ilwEsDoDa-vRoqZ39Tf4FHRGdDg</recordid><startdate>20200101</startdate><enddate>20200101</enddate><creator>Palacio Lozano, Diana Catalina</creator><creator>Ramírez, Claudia X.</creator><creator>Sarmiento Chaparro, José Aristóbulo</creator><creator>Thomas, Mary J.</creator><creator>Gavard, Remy</creator><creator>Jones, Hugh E.</creator><creator>Cabanzo Hernández, Rafael</creator><creator>Mejia-Ospino, Enrique</creator><creator>Barrow, Mark P.</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope></search><sort><creationdate>20200101</creationdate><title>Characterization of bio-crude components derived from pyrolysis of soft wood and its esterified product by ultrahigh resolution mass spectrometry and spectroscopic techniques</title><author>Palacio Lozano, Diana Catalina ; Ramírez, Claudia X. ; Sarmiento Chaparro, José Aristóbulo ; Thomas, Mary J. ; Gavard, Remy ; Jones, Hugh E. ; Cabanzo Hernández, Rafael ; Mejia-Ospino, Enrique ; Barrow, Mark P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c409t-d66c71fb3d3938eab16bd4c0c6e3830915e19242ecce3ad2cec74dcca8139f153</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Aliphatic compounds</topic><topic>Bio-oils</topic><topic>Carbon</topic><topic>Condensates</topic><topic>Cyclotron resonance</topic><topic>Esterification</topic><topic>Fourier analysis</topic><topic>Fourier transforms</topic><topic>Functional groups</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Ions</topic><topic>Mass spectrometry</topic><topic>Mass spectroscopy</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Organic chemistry</topic><topic>Oxygen</topic><topic>Pyrolysis</topic><topic>Resonance</topic><topic>Scientific imaging</topic><topic>Softwoods</topic><topic>Spectroscopy</topic><topic>Ultrahigh resolution mass spectrometry</topic><topic>Water treatment</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Palacio Lozano, Diana Catalina</creatorcontrib><creatorcontrib>Ramírez, Claudia X.</creatorcontrib><creatorcontrib>Sarmiento Chaparro, José Aristóbulo</creatorcontrib><creatorcontrib>Thomas, Mary J.</creatorcontrib><creatorcontrib>Gavard, Remy</creatorcontrib><creatorcontrib>Jones, Hugh E.</creatorcontrib><creatorcontrib>Cabanzo Hernández, Rafael</creatorcontrib><creatorcontrib>Mejia-Ospino, Enrique</creatorcontrib><creatorcontrib>Barrow, Mark P.</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Fuel (Guildford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Palacio Lozano, Diana Catalina</au><au>Ramírez, Claudia X.</au><au>Sarmiento Chaparro, José Aristóbulo</au><au>Thomas, Mary J.</au><au>Gavard, Remy</au><au>Jones, Hugh E.</au><au>Cabanzo Hernández, Rafael</au><au>Mejia-Ospino, Enrique</au><au>Barrow, Mark P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Characterization of bio-crude components derived from pyrolysis of soft wood and its esterified product by ultrahigh resolution mass spectrometry and spectroscopic techniques</atitle><jtitle>Fuel (Guildford)</jtitle><date>2020-01-01</date><risdate>2020</risdate><volume>259</volume><spage>116085</spage><pages>116085-</pages><artnum>116085</artnum><issn>0016-2361</issn><eissn>1873-7153</eissn><abstract>[Display omitted]
In this work, a detailed analysis of a bio-oil obtained by pyrolysis of softwoods and its esterified product is described. Information of the type of chemical function groups were obtained by 13C and 1H nuclear magnetic resonance (NMR) and Fourier transform infrared spectroscopy (FT-IR) and compositional analysis was obtained by Fourier transform ion cyclotron resonance mass spectrometry (FTICR MS). The results obtained indicate that aliphatic hydrogen and carbon atoms are found in higher abundance, compared with aromatic hydrogen-carbon frameworks. Furthermore, a decrease in oxygen functional groups was observed after esterification. According to the FTICR MS results, the samples contain highly oxygenated species corresponding to compound classes Ox, NOx and BOx, with a high predominance of Ox species. After esterification, the compositions shifted towards lower oxygen-content, lower number of rings and double bonds, and longer alkyl chains as a consequence of the water removal via the condensation reaction.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.fuel.2019.116085</doi><oa>free_for_read</oa></addata></record> |
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| subjects | Aliphatic compounds Bio-oils Carbon Condensates Cyclotron resonance Esterification Fourier analysis Fourier transforms Functional groups Infrared analysis Infrared spectroscopy Ions Mass spectrometry Mass spectroscopy NMR Nuclear magnetic resonance Organic chemistry Oxygen Pyrolysis Resonance Scientific imaging Softwoods Spectroscopy Ultrahigh resolution mass spectrometry Water treatment |
| title | Characterization of bio-crude components derived from pyrolysis of soft wood and its esterified product by ultrahigh resolution mass spectrometry and spectroscopic techniques |
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