Thermomechanical characterization of thermoplastic polyimides to improve the chain collaboration via ureidopyrimidone endcaps
In this report, we explored the effect of incorporating ureidopyrimidone (UPy) linkers in a series of polyimides (PIs) previously studied in our laboratory. The polymers consist of an aromatic diamine monomer with a methylene linker, 4,4′’‐methylenebis (2,6‐dimethylaniline), used to make a robust ma...
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| Veröffentlicht in: | Polymer engineering and science 2019-11, Vol.59 (11), p.2231-2246 |
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| container_title | Polymer engineering and science |
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| creator | Nicholls, Alejandro Rivera Perez, Yesenia Pellisier, Matthew Rodde, Arnaud Lanusse, Pierre Stock, John Allan Kull, Ken Eubank, Jarrod Harmon, Julie P. |
| description | In this report, we explored the effect of incorporating ureidopyrimidone (UPy) linkers in a series of polyimides (PIs) previously studied in our laboratory. The polymers consist of an aromatic diamine monomer with a methylene linker, 4,4′’‐methylenebis (2,6‐dimethylaniline), used to make a robust main chain along with aliphatic polyetherdiamine backbone linkers to decrease rigidity. The polymers were designed to exhibit thermal properties in between those of conventional aromatic PIs and polymers with wholly aliphatic ether diamine links, with an aim to improve the mechanical characteristics. Through dynamic mechanical analysis and differential scanning calorimetry, it is shown that the UPy linkers with their four‐hydrogen bond sites are introduced to connect the chains in series. The connection strengthens the chain interactions and increases the range of the thermal and mechanical properties of the PI. Furthermore, the connecting regions are an important component to preserve the thermal stability of PIs while maintaining the processability. The polymers were characterized by FTIR, nuclear magnetic resonance, GPC, thermogravimetric analysis, differential scanning calorimetry, dynamic mechanical analysis, microhardness, and tensile testing. POLYM. ENG. SCI., 59:2231–2246, 2019. © 2019 Society of Plastics Engineers |
| doi_str_mv | 10.1002/pen.25226 |
| format | Article |
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The polymers consist of an aromatic diamine monomer with a methylene linker, 4,4′’‐methylenebis (2,6‐dimethylaniline), used to make a robust main chain along with aliphatic polyetherdiamine backbone linkers to decrease rigidity. The polymers were designed to exhibit thermal properties in between those of conventional aromatic PIs and polymers with wholly aliphatic ether diamine links, with an aim to improve the mechanical characteristics. Through dynamic mechanical analysis and differential scanning calorimetry, it is shown that the UPy linkers with their four‐hydrogen bond sites are introduced to connect the chains in series. The connection strengthens the chain interactions and increases the range of the thermal and mechanical properties of the PI. Furthermore, the connecting regions are an important component to preserve the thermal stability of PIs while maintaining the processability. The polymers were characterized by FTIR, nuclear magnetic resonance, GPC, thermogravimetric analysis, differential scanning calorimetry, dynamic mechanical analysis, microhardness, and tensile testing. POLYM. ENG. 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The polymers consist of an aromatic diamine monomer with a methylene linker, 4,4′’‐methylenebis (2,6‐dimethylaniline), used to make a robust main chain along with aliphatic polyetherdiamine backbone linkers to decrease rigidity. The polymers were designed to exhibit thermal properties in between those of conventional aromatic PIs and polymers with wholly aliphatic ether diamine links, with an aim to improve the mechanical characteristics. Through dynamic mechanical analysis and differential scanning calorimetry, it is shown that the UPy linkers with their four‐hydrogen bond sites are introduced to connect the chains in series. The connection strengthens the chain interactions and increases the range of the thermal and mechanical properties of the PI. Furthermore, the connecting regions are an important component to preserve the thermal stability of PIs while maintaining the processability. The polymers were characterized by FTIR, nuclear magnetic resonance, GPC, thermogravimetric analysis, differential scanning calorimetry, dynamic mechanical analysis, microhardness, and tensile testing. POLYM. ENG. SCI., 59:2231–2246, 2019. © 2019 Society of Plastics Engineers</description><subject>Aliphatic compounds</subject><subject>Bisphenol-A</subject><subject>Bonds (Securities)</subject><subject>Calorimetry</subject><subject>Chemical plants</subject><subject>Diagnostic imaging</subject><subject>Differential scanning calorimetry</subject><subject>Dynamic mechanical analysis</subject><subject>Heat measurement</subject><subject>Hydrogen</subject><subject>Hydrogen bonds</subject><subject>Mechanical properties</subject><subject>Microhardness</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Polyimide resins</subject><subject>Polyimides</subject><subject>Polymer industry</subject><subject>Polymers</subject><subject>Thermal properties</subject><subject>Thermal stability</subject><subject>Thermodynamic properties</subject><subject>Thermogravimetric analysis</subject><subject>Thermomechanical properties</subject><subject>Thermoplastics</subject><issn>0032-3888</issn><issn>1548-2634</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>N95</sourceid><recordid>eNp1kltrHCEUgCU00M3lof9AyFMhs_EyF-cxhKQNhLbk8iyOc2bXMKNTdZJuof-9bqbQLmwRVOT7zjnqQegDJUtKCLsYwS5ZwVh5gBa0yEXGSp6_QwtCOMu4EOI9OgrhmSSWF_UC_Xpcgx_cAHqtrNGqx2njlY7gzU8VjbPYdTi-QWOvQjQaj67fmMG0EHB02Ayjdy-wZbausVi7vleN87P-YhSePJjWjRu_1ZwFDLbVagwn6LBTfYDTP-sxerq5frz6nN19_XR7dXmX6YKSMmNCV5oqkde8rTghQGuRF7QRTaGBU1aTSjcqJ4woVmvBWyqgK5uKd0AEr0p-jM7muKnU7xOEKJ_d5G1KKVnymagpzf9SK9WDNLZzMb3EYIKWlyWp6hSpLBKV7aFWYMGrPt2tM-l4h1_u4dNoYTB6r_BxR0hMhB9xpaYQ5O3D_S57_g_bTMFYCGkKZrWOYVb2hdbeheChk2P6EuU3khK57R-Z-ke-9U9iL2b2NdW3-T8ov11_mY3fEQvGdg</recordid><startdate>201911</startdate><enddate>201911</enddate><creator>Nicholls, Alejandro Rivera</creator><creator>Perez, Yesenia</creator><creator>Pellisier, Matthew</creator><creator>Rodde, Arnaud</creator><creator>Lanusse, Pierre</creator><creator>Stock, John Allan</creator><creator>Kull, Ken</creator><creator>Eubank, Jarrod</creator><creator>Harmon, Julie P.</creator><general>John Wiley & Sons, Inc</general><general>Society of Plastics Engineers, Inc</general><general>Blackwell Publishing Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>N95</scope><scope>XI7</scope><scope>ISR</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-9438-8883</orcidid><orcidid>https://orcid.org/0000-0003-3175-9637</orcidid></search><sort><creationdate>201911</creationdate><title>Thermomechanical characterization of thermoplastic polyimides to improve the chain collaboration via ureidopyrimidone endcaps</title><author>Nicholls, Alejandro Rivera ; Perez, Yesenia ; Pellisier, Matthew ; Rodde, Arnaud ; Lanusse, Pierre ; Stock, John Allan ; Kull, Ken ; Eubank, Jarrod ; Harmon, Julie P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5106-28c7c1a8493d7300e198451b8b5ce312907cba4020a29c83d18ef6b73fe083763</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Aliphatic compounds</topic><topic>Bisphenol-A</topic><topic>Bonds (Securities)</topic><topic>Calorimetry</topic><topic>Chemical plants</topic><topic>Diagnostic imaging</topic><topic>Differential scanning calorimetry</topic><topic>Dynamic mechanical analysis</topic><topic>Heat measurement</topic><topic>Hydrogen</topic><topic>Hydrogen bonds</topic><topic>Mechanical properties</topic><topic>Microhardness</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Polyimide resins</topic><topic>Polyimides</topic><topic>Polymer industry</topic><topic>Polymers</topic><topic>Thermal properties</topic><topic>Thermal stability</topic><topic>Thermodynamic properties</topic><topic>Thermogravimetric analysis</topic><topic>Thermomechanical properties</topic><topic>Thermoplastics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nicholls, Alejandro Rivera</creatorcontrib><creatorcontrib>Perez, Yesenia</creatorcontrib><creatorcontrib>Pellisier, Matthew</creatorcontrib><creatorcontrib>Rodde, Arnaud</creatorcontrib><creatorcontrib>Lanusse, Pierre</creatorcontrib><creatorcontrib>Stock, John Allan</creatorcontrib><creatorcontrib>Kull, Ken</creatorcontrib><creatorcontrib>Eubank, Jarrod</creatorcontrib><creatorcontrib>Harmon, Julie P.</creatorcontrib><collection>CrossRef</collection><collection>Gale Business: Insights</collection><collection>Business Insights: Essentials</collection><collection>Gale In Context: Science</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer engineering and science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nicholls, Alejandro Rivera</au><au>Perez, Yesenia</au><au>Pellisier, Matthew</au><au>Rodde, Arnaud</au><au>Lanusse, Pierre</au><au>Stock, John Allan</au><au>Kull, Ken</au><au>Eubank, Jarrod</au><au>Harmon, Julie P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermomechanical characterization of thermoplastic polyimides to improve the chain collaboration via ureidopyrimidone endcaps</atitle><jtitle>Polymer engineering and science</jtitle><date>2019-11</date><risdate>2019</risdate><volume>59</volume><issue>11</issue><spage>2231</spage><epage>2246</epage><pages>2231-2246</pages><issn>0032-3888</issn><eissn>1548-2634</eissn><abstract>In this report, we explored the effect of incorporating ureidopyrimidone (UPy) linkers in a series of polyimides (PIs) previously studied in our laboratory. The polymers consist of an aromatic diamine monomer with a methylene linker, 4,4′’‐methylenebis (2,6‐dimethylaniline), used to make a robust main chain along with aliphatic polyetherdiamine backbone linkers to decrease rigidity. The polymers were designed to exhibit thermal properties in between those of conventional aromatic PIs and polymers with wholly aliphatic ether diamine links, with an aim to improve the mechanical characteristics. Through dynamic mechanical analysis and differential scanning calorimetry, it is shown that the UPy linkers with their four‐hydrogen bond sites are introduced to connect the chains in series. The connection strengthens the chain interactions and increases the range of the thermal and mechanical properties of the PI. Furthermore, the connecting regions are an important component to preserve the thermal stability of PIs while maintaining the processability. 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| ispartof | Polymer engineering and science, 2019-11, Vol.59 (11), p.2231-2246 |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Aliphatic compounds Bisphenol-A Bonds (Securities) Calorimetry Chemical plants Diagnostic imaging Differential scanning calorimetry Dynamic mechanical analysis Heat measurement Hydrogen Hydrogen bonds Mechanical properties Microhardness NMR Nuclear magnetic resonance Polyimide resins Polyimides Polymer industry Polymers Thermal properties Thermal stability Thermodynamic properties Thermogravimetric analysis Thermomechanical properties Thermoplastics |
| title | Thermomechanical characterization of thermoplastic polyimides to improve the chain collaboration via ureidopyrimidone endcaps |
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