The first evidence of the high oxidation resistance of the novel ternary tantalum-iridium-boron phase

[Display omitted] •Iridium-based material was formed from Ta, Ir and B with SiC additive at 1600 °C.•Novel ternary Ta7Ir6B8 phase presents as a one of the components of material.•The oxidation resistance of the material was studied at 2000 °C.•The first evidence of ability of novel phase to resist s...

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Veröffentlicht in:Corrosion science 2019-11, Vol.160, p.108178, Article 108178
Hauptverfasser: Baklanova, Natalya I., Lozanov, Victor V., Titov, Anatoly T.
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creator Baklanova, Natalya I.
Lozanov, Victor V.
Titov, Anatoly T.
description [Display omitted] •Iridium-based material was formed from Ta, Ir and B with SiC additive at 1600 °C.•Novel ternary Ta7Ir6B8 phase presents as a one of the components of material.•The oxidation resistance of the material was studied at 2000 °C.•The first evidence of ability of novel phase to resist severe conditions is given. An iridium-based intermetallic material was fabricated at 1600 °C from the powdered mixture of tantalum, iridium, boron, and silicon carbide. The ternary phase Ta7Ir6B8 phase was formed with other refractory compounds including TaC, TaIr3, IrSi, and Ta3B4. The ablation resistance was evaluated at 2000–2100 °C. The ablation rate was 7·10−5 g/cm2·s and correlates well with the evaporation rate of Ta2O5. The first evidence of the ability of the ternary Ta7Ir6B8 phase to withstand severe environmental conditions was given. The reasons of the improved oxidation resistance are discussed.
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An iridium-based intermetallic material was fabricated at 1600 °C from the powdered mixture of tantalum, iridium, boron, and silicon carbide. The ternary phase Ta7Ir6B8 phase was formed with other refractory compounds including TaC, TaIr3, IrSi, and Ta3B4. The ablation resistance was evaluated at 2000–2100 °C. The ablation rate was 7·10−5 g/cm2·s and correlates well with the evaporation rate of Ta2O5. The first evidence of the ability of the ternary Ta7Ir6B8 phase to withstand severe environmental conditions was given. The reasons of the improved oxidation resistance are discussed.</description><identifier>ISSN: 0010-938X</identifier><identifier>EISSN: 1879-0496</identifier><identifier>DOI: 10.1016/j.corsci.2019.108178</identifier><language>eng</language><publisher>Amsterdam: Elsevier Ltd</publisher><subject>A. Ta – Ir – B intermetallics, tantalum oxide ; Ablation ; B. 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An iridium-based intermetallic material was fabricated at 1600 °C from the powdered mixture of tantalum, iridium, boron, and silicon carbide. The ternary phase Ta7Ir6B8 phase was formed with other refractory compounds including TaC, TaIr3, IrSi, and Ta3B4. The ablation resistance was evaluated at 2000–2100 °C. The ablation rate was 7·10−5 g/cm2·s and correlates well with the evaporation rate of Ta2O5. The first evidence of the ability of the ternary Ta7Ir6B8 phase to withstand severe environmental conditions was given. The reasons of the improved oxidation resistance are discussed.</description><subject>A. Ta – Ir – B intermetallics, tantalum oxide</subject><subject>Ablation</subject><subject>B. X-ray diffraction, SEM</subject><subject>C. high temperature corrosion, oxidation</subject><subject>Evaporation rate</subject><subject>Iridium</subject><subject>Oxidation</subject><subject>Oxidation resistance</subject><subject>Refractory compounds</subject><subject>Refractory materials</subject><subject>Silicon carbide</subject><subject>Tantalum</subject><subject>Tantalum oxides</subject><subject>Ternary systems</subject><issn>0010-938X</issn><issn>1879-0496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWKv_wEPA89ZJss0mF0GKX1DwUsFbSHdn3SzbpiZp0X9vynrw5Glg5nmHmYeQawYzBkze9rPah1i7GQemc0uxSp2QCVOVLqDU8pRMABgUWqj3c3IRYw8AmYUJwVWHtHUhJooH1-C2RupbmnK3cx8d9V-uscn5LQ0YXUz2D7D1BxxowrC14ZvmUbLDflO44BqX69qHHNt1NuIlOWvtEPHqt07J2-PDavFcLF-fXhb3y6IWokxFW_Kq4o3lgoNYt0Kzeq4rUVZSirbUms3XtUILTckUSKY1R8mtliCYnAsFYkpuxr274D_3GJPp_T6fN0TDBeOcK6Z0psqRqoOPMWBrdsFt8g-GgTkKNb0ZhZqjUDMKzbG7MYb5g4PDYDJxFNa4gHUyjXf_L_gBOqV_4w</recordid><startdate>201911</startdate><enddate>201911</enddate><creator>Baklanova, Natalya I.</creator><creator>Lozanov, Victor V.</creator><creator>Titov, Anatoly T.</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SE</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope></search><sort><creationdate>201911</creationdate><title>The first evidence of the high oxidation resistance of the novel ternary tantalum-iridium-boron phase</title><author>Baklanova, Natalya I. ; Lozanov, Victor V. ; Titov, Anatoly T.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c334t-f42772da23203bf391c597347663f49915bc8ea0d418061992e62a96031653803</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>A. Ta – Ir – B intermetallics, tantalum oxide</topic><topic>Ablation</topic><topic>B. X-ray diffraction, SEM</topic><topic>C. high temperature corrosion, oxidation</topic><topic>Evaporation rate</topic><topic>Iridium</topic><topic>Oxidation</topic><topic>Oxidation resistance</topic><topic>Refractory compounds</topic><topic>Refractory materials</topic><topic>Silicon carbide</topic><topic>Tantalum</topic><topic>Tantalum oxides</topic><topic>Ternary systems</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Baklanova, Natalya I.</creatorcontrib><creatorcontrib>Lozanov, Victor V.</creatorcontrib><creatorcontrib>Titov, Anatoly T.</creatorcontrib><collection>CrossRef</collection><collection>Corrosion Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology &amp; Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><jtitle>Corrosion science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Baklanova, Natalya I.</au><au>Lozanov, Victor V.</au><au>Titov, Anatoly T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The first evidence of the high oxidation resistance of the novel ternary tantalum-iridium-boron phase</atitle><jtitle>Corrosion science</jtitle><date>2019-11</date><risdate>2019</risdate><volume>160</volume><spage>108178</spage><pages>108178-</pages><artnum>108178</artnum><issn>0010-938X</issn><eissn>1879-0496</eissn><abstract>[Display omitted] •Iridium-based material was formed from Ta, Ir and B with SiC additive at 1600 °C.•Novel ternary Ta7Ir6B8 phase presents as a one of the components of material.•The oxidation resistance of the material was studied at 2000 °C.•The first evidence of ability of novel phase to resist severe conditions is given. An iridium-based intermetallic material was fabricated at 1600 °C from the powdered mixture of tantalum, iridium, boron, and silicon carbide. The ternary phase Ta7Ir6B8 phase was formed with other refractory compounds including TaC, TaIr3, IrSi, and Ta3B4. The ablation resistance was evaluated at 2000–2100 °C. The ablation rate was 7·10−5 g/cm2·s and correlates well with the evaporation rate of Ta2O5. The first evidence of the ability of the ternary Ta7Ir6B8 phase to withstand severe environmental conditions was given. The reasons of the improved oxidation resistance are discussed.</abstract><cop>Amsterdam</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.corsci.2019.108178</doi></addata></record>
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subjects A. Ta – Ir – B intermetallics, tantalum oxide
Ablation
B. X-ray diffraction, SEM
C. high temperature corrosion, oxidation
Evaporation rate
Iridium
Oxidation
Oxidation resistance
Refractory compounds
Refractory materials
Silicon carbide
Tantalum
Tantalum oxides
Ternary systems
title The first evidence of the high oxidation resistance of the novel ternary tantalum-iridium-boron phase
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