Understanding the intramolecular vibrational energy transfer and structural dynamics of anionic ligands in a photo-catalytic CO2 reduction catalyst

The knowledge of intramolecular vibrational energy redistribution (IVR) and structural dynamics of rhenium photo-catalysts is essential for understanding the mechanism of the photo-catalytic process of CO2 reduction. In this study, the rhenium compound Re(dcbyp)(CO)3NCS (Re-NCS), which served as a m...

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