Transesterification of Exocyclic Ester Group of Methyl Pheophorbide a
The reaction of methyl pheophorbide a with various alcohols in toluene in the presence of dimethylaminopyridine as a base was investigated. Under these conditions, a chemoselective transesterification of the exocyclic ring proceeds without the use of an activating agent ( N -methyl-2-chloropyridiniu...
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Veröffentlicht in: | Russian journal of general chemistry 2019-09, Vol.89 (9), p.1772-1776 |
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container_issue | 9 |
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container_title | Russian journal of general chemistry |
container_volume | 89 |
creator | Tulaeva, L. A. Gileva, N. V. Belykh, D. V. |
description | The reaction of methyl pheophorbide
a
with various alcohols in toluene in the presence of dimethylaminopyridine as a base was investigated. Under these conditions, a chemoselective transesterification of the exocyclic ring proceeds without the use of an activating agent (
N
-methyl-2-chloropyridinium iodide) or a catalyst (molecular iodine). |
doi_str_mv | 10.1134/S107036321909007X |
format | Article |
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a
with various alcohols in toluene in the presence of dimethylaminopyridine as a base was investigated. Under these conditions, a chemoselective transesterification of the exocyclic ring proceeds without the use of an activating agent (
N
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a
with various alcohols in toluene in the presence of dimethylaminopyridine as a base was investigated. Under these conditions, a chemoselective transesterification of the exocyclic ring proceeds without the use of an activating agent (
N
-methyl-2-chloropyridinium iodide) or a catalyst (molecular iodine).</description><subject>Alcohols</subject><subject>Chemical properties</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Chlorophyll</subject><subject>Iodine</subject><subject>Toluene</subject><subject>Transesterification</subject><issn>1070-3632</issn><issn>1608-3350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kFFLwzAQx4MoOKcfwLeCz52XJkvSxzHqFCYKTvCtpGmyZXRNTTpw396UCj6I5CDhfv__5e4QusUww5jQ-zcMHAgjGc4hB-AfZ2iCGYiUkDmcx3fE6cAv0VUIewAMwLIJKjZetkGHXntrrJK9dW3iTFJ8OXVSjVVJMbBk5d2xG8Cz7nenJnndadftnK9srRN5jS6MbIK--bmn6P2h2Cwf0_XL6mm5WKeKZrhP5RwE51xLlmssBc0Zz5UwVBks5FwIWkUgq0pVRAkgRiii65rLnGGS05iZoruxbufd5zF2Xe7d0bfxyzIjIOLwMaJqNqq2stGlbY3rvVTx1PpglWu1sTG_4BljHFPKogGPBuVdCF6bsvP2IP2pxFAO6y3_rDd6stETorbdav_byv-mbw4Deyg</recordid><startdate>20190901</startdate><enddate>20190901</enddate><creator>Tulaeva, L. A.</creator><creator>Gileva, N. V.</creator><creator>Belykh, D. V.</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20190901</creationdate><title>Transesterification of Exocyclic Ester Group of Methyl Pheophorbide a</title><author>Tulaeva, L. A. ; Gileva, N. V. ; Belykh, D. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c421t-a508777ea69e1a849679c8f4cf18a5884b69eabbcb3c803f8c3edd7a961394803</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Alcohols</topic><topic>Chemical properties</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Chlorophyll</topic><topic>Iodine</topic><topic>Toluene</topic><topic>Transesterification</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tulaeva, L. A.</creatorcontrib><creatorcontrib>Gileva, N. V.</creatorcontrib><creatorcontrib>Belykh, D. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of general chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tulaeva, L. A.</au><au>Gileva, N. V.</au><au>Belykh, D. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Transesterification of Exocyclic Ester Group of Methyl Pheophorbide a</atitle><jtitle>Russian journal of general chemistry</jtitle><stitle>Russ J Gen Chem</stitle><date>2019-09-01</date><risdate>2019</risdate><volume>89</volume><issue>9</issue><spage>1772</spage><epage>1776</epage><pages>1772-1776</pages><issn>1070-3632</issn><eissn>1608-3350</eissn><abstract>The reaction of methyl pheophorbide
a
with various alcohols in toluene in the presence of dimethylaminopyridine as a base was investigated. Under these conditions, a chemoselective transesterification of the exocyclic ring proceeds without the use of an activating agent (
N
-methyl-2-chloropyridinium iodide) or a catalyst (molecular iodine).</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S107036321909007X</doi><tpages>5</tpages></addata></record> |
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subjects | Alcohols Chemical properties Chemistry Chemistry and Materials Science Chemistry/Food Science Chlorophyll Iodine Toluene Transesterification |
title | Transesterification of Exocyclic Ester Group of Methyl Pheophorbide a |
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