Correlating magnetic anisotropy with the subtle coordination geometry variation of a series of cobalt()-sulfonamide complexes

Systematic substitution on the N -(pyridine-2-ylmethyl)-sulfonamide ligand leads to the subtle variation of the CoN 4 coordination geometry in a series of cobalt( ii ) complexes sharing the common formula of Co[R 1 (C 6 N 2 H 5 )R 2 ] 2 , where R 1 = H, R 2 = 4- tert -butylphenylsulfonyl ( t Buphs)...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2019-10, Vol.48 (41), p.15419-15426
Hauptverfasser:	Wu, Tao, Zhai, Yuan-Qi, Deng, Yi-Fei, Chen, Wei-Peng, Zhang, Tao, Zheng, Yan-Zhen
Format:	Artikel
Sprache:	eng
Schlagworte:	Cobalt compounds Coordination Crystallography Distortion Geometry Magnetic anisotropy Sulfonamides Symmetry Tensors Tetrahedra
Online-Zugang:	Volltext
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