A New Perspective on Geometric Thermodynamic Models
To estimate the thermodynamic properties of a multi-component system using traditional geometric models, lack of a physical meaning generates many puzzles during choosing a concrete method. In this paper, we introduced a perspective in terms of the molar quantity of the components in the sub-binary...
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| Veröffentlicht in: | Journal of phase equilibria and diffusion 2019-10, Vol.40 (5), p.715-724 |
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| container_title | Journal of phase equilibria and diffusion |
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| creator | Ju, Tianhua Ding, Xueyong Chen, Weiliang Yan, Xinlin Dong, Yue |
| description | To estimate the thermodynamic properties of a multi-component system using traditional geometric models, lack of a physical meaning generates many puzzles during choosing a concrete method. In this paper, we introduced a perspective in terms of the molar quantity of the components in the sub-binary of a ternary system affected by the third component and deduced a new model to unify all other traditional geometric models (e.g. Kohler, Muggianu, Toop-Kohler, etc.) into one model. The effects could be represented by so-called contribution coefficients, whose values only depend on the degree of identity between the thermodynamic properties of the third component and those of the selected components in the sub-binary, and which gives the physical meaning for the present model. |
| doi_str_mv | 10.1007/s11669-019-00757-5 |
| format | Article |
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| subjects | Ceramics Composites Crystallography and Scattering Methods Engineering Thermodynamics Glass Heat and Mass Transfer Mathematical models Metallic Materials Natural Materials Physics Physics and Astronomy Ternary systems Thermodynamic models Thermodynamic properties Thermodynamics |
| title | A New Perspective on Geometric Thermodynamic Models |
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