Effect of pine resin derivatives on the structural, thermal, and mechanical properties of Mater‐Bi type bioplastic
ABSTRACT The effect of three additives derived from pine resin, namely, gum rosin (GR) and two pentaerythritol ester of GR, Lurefor (LF) and Unik Tack (UT), in 5, 10, and 15 wt %, on the properties of Mater‐Bi, based on plasticized starch, poly(butylene adipate‐co‐terephthalate), and poly(ε‐caprolac...
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| creator | Aldas, M. Ferri, J. M. Lopez‐Martinez, J. Samper, M. D. Arrieta, M. P. |
| description | ABSTRACT
The effect of three additives derived from pine resin, namely, gum rosin (GR) and two pentaerythritol ester of GR, Lurefor (LF) and Unik Tack (UT), in 5, 10, and 15 wt %, on the properties of Mater‐Bi, based on plasticized starch, poly(butylene adipate‐co‐terephthalate), and poly(ε‐caprolactone) (PCL), obtained by injection molding processes, was studied. The mechanical, microstructural, and thermal properties were evaluated. LF had a cohesive behavior with the components of Mater‐Bi, increasing the toughness of the material up to 250% accompanied by an increase of tensile modulus and tensile strength. UT had an intermediate behavior, conferring cohesive and plasticizing effects, allowing an increase of 105% in impact resistance. GR had a more marked plasticizing effect. This allows processing temperatures of about 50 °C lower than those used for neat Mater‐Bi. In addition, an increase of the elongation at break, toughness, and impact resistance in 370, 480, and 250%, respectively, was achieved. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 48236. |
| doi_str_mv | 10.1002/app.48236 |
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The effect of three additives derived from pine resin, namely, gum rosin (GR) and two pentaerythritol ester of GR, Lurefor (LF) and Unik Tack (UT), in 5, 10, and 15 wt %, on the properties of Mater‐Bi, based on plasticized starch, poly(butylene adipate‐co‐terephthalate), and poly(ε‐caprolactone) (PCL), obtained by injection molding processes, was studied. The mechanical, microstructural, and thermal properties were evaluated. LF had a cohesive behavior with the components of Mater‐Bi, increasing the toughness of the material up to 250% accompanied by an increase of tensile modulus and tensile strength. UT had an intermediate behavior, conferring cohesive and plasticizing effects, allowing an increase of 105% in impact resistance. GR had a more marked plasticizing effect. This allows processing temperatures of about 50 °C lower than those used for neat Mater‐Bi. In addition, an increase of the elongation at break, toughness, and impact resistance in 370, 480, and 250%, respectively, was achieved. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 48236.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.48236</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley & Sons, Inc</publisher><subject>Additives ; biodegradable polymers ; compatibilizer ; Elongation ; gum rosin ; Impact resistance ; Impact strength ; Injection molding ; Materials science ; Mechanical properties ; Modulus of elasticity ; Oleoresins ; pine resin derivatives ; plasticizer ; Polymers ; Rosin ; Terephthalate ; Thermodynamic properties ; thermoplastic starch ; Toughness</subject><ispartof>Journal of applied polymer science, 2020-01, Vol.137 (4), p.n/a</ispartof><rights>2019 Wiley Periodicals, Inc.</rights><rights>2020 Wiley Periodicals, Inc.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3696-fde9a05125cf242aa4e7cd09e2f2bf38086883546546c5f87a5db93e8d5da92c3</citedby><cites>FETCH-LOGICAL-c3696-fde9a05125cf242aa4e7cd09e2f2bf38086883546546c5f87a5db93e8d5da92c3</cites><orcidid>0000-0002-1269-4973 ; 0000-0003-3491-6618 ; 0000-0002-5102-8412 ; 0000-0003-1816-011X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.48236$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.48236$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,777,781,1412,27905,27906,45555,45556</link.rule.ids></links><search><creatorcontrib>Aldas, M.</creatorcontrib><creatorcontrib>Ferri, J. M.</creatorcontrib><creatorcontrib>Lopez‐Martinez, J.</creatorcontrib><creatorcontrib>Samper, M. D.</creatorcontrib><creatorcontrib>Arrieta, M. P.</creatorcontrib><title>Effect of pine resin derivatives on the structural, thermal, and mechanical properties of Mater‐Bi type bioplastic</title><title>Journal of applied polymer science</title><description>ABSTRACT
The effect of three additives derived from pine resin, namely, gum rosin (GR) and two pentaerythritol ester of GR, Lurefor (LF) and Unik Tack (UT), in 5, 10, and 15 wt %, on the properties of Mater‐Bi, based on plasticized starch, poly(butylene adipate‐co‐terephthalate), and poly(ε‐caprolactone) (PCL), obtained by injection molding processes, was studied. The mechanical, microstructural, and thermal properties were evaluated. LF had a cohesive behavior with the components of Mater‐Bi, increasing the toughness of the material up to 250% accompanied by an increase of tensile modulus and tensile strength. UT had an intermediate behavior, conferring cohesive and plasticizing effects, allowing an increase of 105% in impact resistance. GR had a more marked plasticizing effect. This allows processing temperatures of about 50 °C lower than those used for neat Mater‐Bi. In addition, an increase of the elongation at break, toughness, and impact resistance in 370, 480, and 250%, respectively, was achieved. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 48236.</description><subject>Additives</subject><subject>biodegradable polymers</subject><subject>compatibilizer</subject><subject>Elongation</subject><subject>gum rosin</subject><subject>Impact resistance</subject><subject>Impact strength</subject><subject>Injection molding</subject><subject>Materials science</subject><subject>Mechanical properties</subject><subject>Modulus of elasticity</subject><subject>Oleoresins</subject><subject>pine resin derivatives</subject><subject>plasticizer</subject><subject>Polymers</subject><subject>Rosin</subject><subject>Terephthalate</subject><subject>Thermodynamic properties</subject><subject>thermoplastic starch</subject><subject>Toughness</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1kM9OwzAMxiMEEmNw4A0icUKiW5I2WXoc0_gjgdgBzlWWOlqmrg1JOrQbj8Az8iS0lCuSJdvy77OtD6FLSiaUEDZVzk0yyVJxhEaU5LMkE0weo1E3o4nMc36KzkLYEkIpJ2KE4tIY0BE3BjtbA_YQbI1L8Havot1DwE2N4wZwiL7VsfWquul7v-sLVZd4B3qjaqtVhZ1vHPhoe5XBzyqC__78urU4HhzgtW1cpUK0-hydGFUFuPjLY_R2t3xdPCRPL_ePi_lTolORi8SUkCvCKePasIwplcFMlyQHZtjapJJIIWXKM9GF5kbOFC_XeQqy5KXKmU7H6GrY2z323kKIxbZpfd2dLFhKeMYEFVlHXQ-U9k0IHkzhvN0pfygoKXpTi87U4tfUjp0O7Iet4PA_WMxXq0HxA1J1et4</recordid><startdate>20200120</startdate><enddate>20200120</enddate><creator>Aldas, M.</creator><creator>Ferri, J. M.</creator><creator>Lopez‐Martinez, J.</creator><creator>Samper, M. D.</creator><creator>Arrieta, M. P.</creator><general>John Wiley & Sons, Inc</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-1269-4973</orcidid><orcidid>https://orcid.org/0000-0003-3491-6618</orcidid><orcidid>https://orcid.org/0000-0002-5102-8412</orcidid><orcidid>https://orcid.org/0000-0003-1816-011X</orcidid></search><sort><creationdate>20200120</creationdate><title>Effect of pine resin derivatives on the structural, thermal, and mechanical properties of Mater‐Bi type bioplastic</title><author>Aldas, M. ; Ferri, J. M. ; Lopez‐Martinez, J. ; Samper, M. D. ; Arrieta, M. P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3696-fde9a05125cf242aa4e7cd09e2f2bf38086883546546c5f87a5db93e8d5da92c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Additives</topic><topic>biodegradable polymers</topic><topic>compatibilizer</topic><topic>Elongation</topic><topic>gum rosin</topic><topic>Impact resistance</topic><topic>Impact strength</topic><topic>Injection molding</topic><topic>Materials science</topic><topic>Mechanical properties</topic><topic>Modulus of elasticity</topic><topic>Oleoresins</topic><topic>pine resin derivatives</topic><topic>plasticizer</topic><topic>Polymers</topic><topic>Rosin</topic><topic>Terephthalate</topic><topic>Thermodynamic properties</topic><topic>thermoplastic starch</topic><topic>Toughness</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Aldas, M.</creatorcontrib><creatorcontrib>Ferri, J. 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P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of pine resin derivatives on the structural, thermal, and mechanical properties of Mater‐Bi type bioplastic</atitle><jtitle>Journal of applied polymer science</jtitle><date>2020-01-20</date><risdate>2020</risdate><volume>137</volume><issue>4</issue><epage>n/a</epage><issn>0021-8995</issn><eissn>1097-4628</eissn><abstract>ABSTRACT
The effect of three additives derived from pine resin, namely, gum rosin (GR) and two pentaerythritol ester of GR, Lurefor (LF) and Unik Tack (UT), in 5, 10, and 15 wt %, on the properties of Mater‐Bi, based on plasticized starch, poly(butylene adipate‐co‐terephthalate), and poly(ε‐caprolactone) (PCL), obtained by injection molding processes, was studied. The mechanical, microstructural, and thermal properties were evaluated. LF had a cohesive behavior with the components of Mater‐Bi, increasing the toughness of the material up to 250% accompanied by an increase of tensile modulus and tensile strength. UT had an intermediate behavior, conferring cohesive and plasticizing effects, allowing an increase of 105% in impact resistance. GR had a more marked plasticizing effect. This allows processing temperatures of about 50 °C lower than those used for neat Mater‐Bi. In addition, an increase of the elongation at break, toughness, and impact resistance in 370, 480, and 250%, respectively, was achieved. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 48236.</abstract><cop>Hoboken, USA</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/app.48236</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0002-1269-4973</orcidid><orcidid>https://orcid.org/0000-0003-3491-6618</orcidid><orcidid>https://orcid.org/0000-0002-5102-8412</orcidid><orcidid>https://orcid.org/0000-0003-1816-011X</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Additives biodegradable polymers compatibilizer Elongation gum rosin Impact resistance Impact strength Injection molding Materials science Mechanical properties Modulus of elasticity Oleoresins pine resin derivatives plasticizer Polymers Rosin Terephthalate Thermodynamic properties thermoplastic starch Toughness |
| title | Effect of pine resin derivatives on the structural, thermal, and mechanical properties of Mater‐Bi type bioplastic |
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