Nanoelectrode-emitter spectral overlap amplifies surface enhanced electrogenerated chemiluminescence
Electrogenerated chemiluminescence (ECL) is a promising technique for low concentration molecular detection. To improve the detection limit, plasmonic nanoparticles have been proposed as signal boosting antennas to amplify ECL. Previous ensemble studies have hinted that spectral overlap between the...
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| Veröffentlicht in: | The Journal of chemical physics 2019-10, Vol.151 (14), p.144712-144712 |
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| creator | Heiderscheit, Thomas S. Gallagher, Miranda J. Baiyasi, Rashad Collins, Sean S. E. Hosseini Jebeli, Seyyed Ali Scarabelli, Leonardo Al-Zubeidi, Alexander Flatebo, Charlotte Chang, Wei-Shun Landes, Christy F. Link, Stephan |
| description | Electrogenerated chemiluminescence (ECL) is a promising technique for low concentration molecular detection. To improve the detection limit, plasmonic nanoparticles have been proposed as signal boosting antennas to amplify ECL. Previous ensemble studies have hinted that spectral overlap between the nanoparticle antenna and the ECL emitter may play a role in signal enhancement. Ensemble spectroscopy, however, cannot resolve heterogeneities arising from colloidal nanoparticle size and shape distributions, leading to an incomplete picture of the impact of spectral overlap. Here, we isolate the effect of nanoparticle-emitter spectral overlap for a model ECL system, coreaction of tris(2,2′-bipyridyl)dichlororuthenium(ii) hexahydrate and tripropylamine, at the single-particle level while minimizing other factors influencing ECL intensities. We found a 10-fold enhancement of ECL among 952 gold nanoparticles. This signal enhancement is attributed exclusively to spectral overlap between the nanoparticle and the emitter. Our study provides new mechanistic insight into plasmonic enhancement of ECL, creating opportunities for low concentration ECL sensing. |
| doi_str_mv | 10.1063/1.5118669 |
| format | Article |
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Ensemble spectroscopy, however, cannot resolve heterogeneities arising from colloidal nanoparticle size and shape distributions, leading to an incomplete picture of the impact of spectral overlap. Here, we isolate the effect of nanoparticle-emitter spectral overlap for a model ECL system, coreaction of tris(2,2′-bipyridyl)dichlororuthenium(ii) hexahydrate and tripropylamine, at the single-particle level while minimizing other factors influencing ECL intensities. We found a 10-fold enhancement of ECL among 952 gold nanoparticles. This signal enhancement is attributed exclusively to spectral overlap between the nanoparticle and the emitter. Our study provides new mechanistic insight into plasmonic enhancement of ECL, creating opportunities for low concentration ECL sensing.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.5118669</identifier><identifier>CODEN: JCPSA6</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Amplification ; Antennas ; Chemiluminescence ; Electrons ; Emitters ; Nanoparticles ; NANOSCIENCE AND NANOTECHNOLOGY ; Organic chemistry ; Spectra ; Spectral emittance</subject><ispartof>The Journal of chemical physics, 2019-10, Vol.151 (14), p.144712-144712</ispartof><rights>Author(s)</rights><rights>2019 Author(s). 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E.</au><au>Hosseini Jebeli, Seyyed Ali</au><au>Scarabelli, Leonardo</au><au>Al-Zubeidi, Alexander</au><au>Flatebo, Charlotte</au><au>Chang, Wei-Shun</au><au>Landes, Christy F.</au><au>Link, Stephan</au><aucorp>Rice Univ., Houston, TX (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nanoelectrode-emitter spectral overlap amplifies surface enhanced electrogenerated chemiluminescence</atitle><jtitle>The Journal of chemical physics</jtitle><date>2019-10-14</date><risdate>2019</risdate><volume>151</volume><issue>14</issue><spage>144712</spage><epage>144712</epage><pages>144712-144712</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><coden>JCPSA6</coden><abstract>Electrogenerated chemiluminescence (ECL) is a promising technique for low concentration molecular detection. To improve the detection limit, plasmonic nanoparticles have been proposed as signal boosting antennas to amplify ECL. Previous ensemble studies have hinted that spectral overlap between the nanoparticle antenna and the ECL emitter may play a role in signal enhancement. Ensemble spectroscopy, however, cannot resolve heterogeneities arising from colloidal nanoparticle size and shape distributions, leading to an incomplete picture of the impact of spectral overlap. Here, we isolate the effect of nanoparticle-emitter spectral overlap for a model ECL system, coreaction of tris(2,2′-bipyridyl)dichlororuthenium(ii) hexahydrate and tripropylamine, at the single-particle level while minimizing other factors influencing ECL intensities. We found a 10-fold enhancement of ECL among 952 gold nanoparticles. This signal enhancement is attributed exclusively to spectral overlap between the nanoparticle and the emitter. 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| subjects | Amplification Antennas Chemiluminescence Electrons Emitters Nanoparticles NANOSCIENCE AND NANOTECHNOLOGY Organic chemistry Spectra Spectral emittance |
| title | Nanoelectrode-emitter spectral overlap amplifies surface enhanced electrogenerated chemiluminescence |
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