Dianionic Mononuclear Cyclo‐P4 Complexes of Zero‐Valent Molybdenum: Coordination of the Cyclo‐P4 Dianion in the Absence of Intramolecular Charge Transfer

Relative to other cyclic poly‐phosphorus species (that is, cyclo‐Pn), the planar cyclo‐P4 group is unique in its requirement of two additional electrons to achieve aromaticity. These electrons are supplied from one or more metal centers. However, the degree of charge transfer is dependent on the nat...

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Veröffentlicht in:Angewandte Chemie 2019-10, Vol.131 (43), p.15473-15477
Hauptverfasser: Mandla, Kyle A., Neville, Michael L., Moore, Curtis E., Rheingold, Arnold L., Figueroa, Joshua S.
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Sprache:eng
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