Experimental and theoretical study of electronic structure of disordered MWCNTs
Experimental study of electronic structure of the initial multi-walled carbon nanotubes (MWCNTs) as well as the exposed to annealing and irradiation N-MWCNTs, was carried out by XPS and NEXAFS methods. Based on the obtained photoelectron valence band spectra and C K-edge absorption spectra, a theore...
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Veröffentlicht in: | Carbon (New York) 2019-11, Vol.153, p.40-51 |
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creator | Bobenko, N.G. Bolotov, V.V. Egorushkin, V.E. Korusenko, P.M. Melnikova, N.V. Nesov, S.N. Ponomarev, A.N. Povoroznyuk, S.N. |
description | Experimental study of electronic structure of the initial multi-walled carbon nanotubes (MWCNTs) as well as the exposed to annealing and irradiation N-MWCNTs, was carried out by XPS and NEXAFS methods. Based on the obtained photoelectron valence band spectra and C K-edge absorption spectra, a theoretical description of the density of electronic states (DOS) near the Fermi level was proposed to explain the dependence of the DOS and the band gap on temperature, concentration of doping atoms and various atomic configurations formed in a system during synthesis, subsequent ion-beam and heat treatment of MWCNTs.
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doi_str_mv | 10.1016/j.carbon.2019.06.104 |
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[Display omitted]</description><subject>Absorption spectra</subject><subject>Carbon</subject><subject>Chemical synthesis</subject><subject>Density of states</subject><subject>Dependence</subject><subject>Electron states</subject><subject>Electronic structure</subject><subject>Heat treatment</subject><subject>Ion beams</subject><subject>Multi wall carbon nanotubes</subject><subject>Nanotubes</subject><subject>Photoelectrons</subject><subject>Semiconductor doping</subject><subject>Temperature</subject><subject>Valence band</subject><issn>0008-6223</issn><issn>1873-3891</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9UE1LAzEUDKJgrf4DDwued83XptmLIKV-QLWXiseQTd5ilrqpSVbsvzdlPcs7PN4wM48ZhK4Jrggm4ravjA6tHyqKSVNhkVF-gmZELljJZENO0QxjLEtBKTtHFzH2-eSS8BnarH72ENwnDEnvCj3YIn2AD5CcyXdMoz0UvitgByYFPziTsTCaNAY44tZFHywEsMXL-_J1Gy_RWad3Ea7-9hy9Pay2y6dyvXl8Xt6vS8MYT2UnqTaiM7yrpWh000pqWgm1MA3YhcCY6DyYabLQzApJa8AN053FNZe1btkc3Uy---C_RohJ9X4MQ36pKMOckFowmll8YpngYwzQqX3OqsNBEayO1aleTdWpY3UKi4zyLLubZJATfDsIKhoHgwHrQu5BWe_-N_gFEcd5nQ</recordid><startdate>201911</startdate><enddate>201911</enddate><creator>Bobenko, N.G.</creator><creator>Bolotov, V.V.</creator><creator>Egorushkin, V.E.</creator><creator>Korusenko, P.M.</creator><creator>Melnikova, N.V.</creator><creator>Nesov, S.N.</creator><creator>Ponomarev, A.N.</creator><creator>Povoroznyuk, S.N.</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-9251-5842</orcidid><orcidid>https://orcid.org/0000-0003-1524-7842</orcidid><orcidid>https://orcid.org/0000-0003-3048-1821</orcidid></search><sort><creationdate>201911</creationdate><title>Experimental and theoretical study of electronic structure of disordered MWCNTs</title><author>Bobenko, N.G. ; Bolotov, V.V. ; Egorushkin, V.E. ; Korusenko, P.M. ; Melnikova, N.V. ; Nesov, S.N. ; Ponomarev, A.N. ; Povoroznyuk, S.N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c334t-f82ac6fc4f5869a9b82cb8e56c9ed76001a1a103a17a3d6825e093afd05485ab3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Absorption spectra</topic><topic>Carbon</topic><topic>Chemical synthesis</topic><topic>Density of states</topic><topic>Dependence</topic><topic>Electron states</topic><topic>Electronic structure</topic><topic>Heat treatment</topic><topic>Ion beams</topic><topic>Multi wall carbon nanotubes</topic><topic>Nanotubes</topic><topic>Photoelectrons</topic><topic>Semiconductor doping</topic><topic>Temperature</topic><topic>Valence band</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bobenko, N.G.</creatorcontrib><creatorcontrib>Bolotov, V.V.</creatorcontrib><creatorcontrib>Egorushkin, V.E.</creatorcontrib><creatorcontrib>Korusenko, P.M.</creatorcontrib><creatorcontrib>Melnikova, N.V.</creatorcontrib><creatorcontrib>Nesov, S.N.</creatorcontrib><creatorcontrib>Ponomarev, A.N.</creatorcontrib><creatorcontrib>Povoroznyuk, S.N.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Carbon (New York)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bobenko, N.G.</au><au>Bolotov, V.V.</au><au>Egorushkin, V.E.</au><au>Korusenko, P.M.</au><au>Melnikova, N.V.</au><au>Nesov, S.N.</au><au>Ponomarev, A.N.</au><au>Povoroznyuk, S.N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Experimental and theoretical study of electronic structure of disordered MWCNTs</atitle><jtitle>Carbon (New York)</jtitle><date>2019-11</date><risdate>2019</risdate><volume>153</volume><spage>40</spage><epage>51</epage><pages>40-51</pages><issn>0008-6223</issn><eissn>1873-3891</eissn><abstract>Experimental study of electronic structure of the initial multi-walled carbon nanotubes (MWCNTs) as well as the exposed to annealing and irradiation N-MWCNTs, was carried out by XPS and NEXAFS methods. Based on the obtained photoelectron valence band spectra and C K-edge absorption spectra, a theoretical description of the density of electronic states (DOS) near the Fermi level was proposed to explain the dependence of the DOS and the band gap on temperature, concentration of doping atoms and various atomic configurations formed in a system during synthesis, subsequent ion-beam and heat treatment of MWCNTs.
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subjects | Absorption spectra Carbon Chemical synthesis Density of states Dependence Electron states Electronic structure Heat treatment Ion beams Multi wall carbon nanotubes Nanotubes Photoelectrons Semiconductor doping Temperature Valence band |
title | Experimental and theoretical study of electronic structure of disordered MWCNTs |
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