Experimental and theoretical study of electronic structure of disordered MWCNTs

Experimental study of electronic structure of the initial multi-walled carbon nanotubes (MWCNTs) as well as the exposed to annealing and irradiation N-MWCNTs, was carried out by XPS and NEXAFS methods. Based on the obtained photoelectron valence band spectra and C K-edge absorption spectra, a theore...

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Veröffentlicht in:Carbon (New York) 2019-11, Vol.153, p.40-51
Hauptverfasser: Bobenko, N.G., Bolotov, V.V., Egorushkin, V.E., Korusenko, P.M., Melnikova, N.V., Nesov, S.N., Ponomarev, A.N., Povoroznyuk, S.N.
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container_end_page 51
container_issue
container_start_page 40
container_title Carbon (New York)
container_volume 153
creator Bobenko, N.G.
Bolotov, V.V.
Egorushkin, V.E.
Korusenko, P.M.
Melnikova, N.V.
Nesov, S.N.
Ponomarev, A.N.
Povoroznyuk, S.N.
description Experimental study of electronic structure of the initial multi-walled carbon nanotubes (MWCNTs) as well as the exposed to annealing and irradiation N-MWCNTs, was carried out by XPS and NEXAFS methods. Based on the obtained photoelectron valence band spectra and C K-edge absorption spectra, a theoretical description of the density of electronic states (DOS) near the Fermi level was proposed to explain the dependence of the DOS and the band gap on temperature, concentration of doping atoms and various atomic configurations formed in a system during synthesis, subsequent ion-beam and heat treatment of MWCNTs. [Display omitted]
doi_str_mv 10.1016/j.carbon.2019.06.104
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subjects Absorption spectra
Carbon
Chemical synthesis
Density of states
Dependence
Electron states
Electronic structure
Heat treatment
Ion beams
Multi wall carbon nanotubes
Nanotubes
Photoelectrons
Semiconductor doping
Temperature
Valence band
title Experimental and theoretical study of electronic structure of disordered MWCNTs
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