Oxygen vacancy and Mn2+ induced ferromagnetism in Mn-doped ZnO thin films

With the purpose of investigating the origin of ferromagnetism (FM), Mn-doped ZnO thin films had been fabricated by radio frequency (rf) magnetron sputtering and subsequent anneal process. The characterization of the Mn-doped ZnO thin films was conducted by X-ray diffraction (XRD), X-ray photoelectr...

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Veröffentlicht in:Science China. Technological sciences 2019-10, Vol.62 (10), p.1755-1759
Hauptverfasser: Guan, SuJun, Nasu, Naho, Zhang, Yu, Tamamoto, Yuri, Yamanobe, Maria, Zhao, XinWei
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container_issue 10
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container_title Science China. Technological sciences
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creator Guan, SuJun
Nasu, Naho
Zhang, Yu
Tamamoto, Yuri
Yamanobe, Maria
Zhao, XinWei
description With the purpose of investigating the origin of ferromagnetism (FM), Mn-doped ZnO thin films had been fabricated by radio frequency (rf) magnetron sputtering and subsequent anneal process. The characterization of the Mn-doped ZnO thin films was conducted by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and superconducting quantum interference device (SQUID). With increasing the anneal temperature from 300°C to 700°C for 3 min, the influence on magnetism of the Mn-doped ZnO thin films is slight. While extending the anneal time from 3 to 50 min at 300°C, the influence on magnetism is obvious and the Mn-doped ZnO thin films with 30 min clearly demonstrate FM. Compared with the effect of oxygen vacancy and substitutional Mn 2+ on the ferromagnetic behavior, O V plays the main role in inducing FM of the Mn-doped ZnO thin films with good crystal structure.
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subjects Annealing
Crystal structure
Engineering
Ferromagnetism
Magnetism
Magnetron sputtering
Photoelectrons
Photovoltaic cells
Superconducting quantum interference devices
Thin films
Vacancies
X ray photoelectron spectroscopy
Zinc oxide
title Oxygen vacancy and Mn2+ induced ferromagnetism in Mn-doped ZnO thin films
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