A new thin film modified glassy carbon electrode based on melaminium chloride pentachlorocuprate(II) for selective determination of nitrate in water
A new electrochemical thin film glassy carbon sensor for nitrate detection based on a copper complex, namely melaminium chloride pentachlorocuprate (H 2 mela)ClCuCl 5 (mela = melamine), as a novel ionophore in plasticized polyvinyl chloride matrix was elaborated. The title complex was synthesized an...
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| Veröffentlicht in: | Monatshefte für Chemie 2019-10, Vol.150 (10), p.1737-1744 |
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| creator | Araar, Hala Benounis, Messaoud Direm, Amani Touati, Amina Atailia, Sara Barhoumi, Houcine Jaffrezic-Renault, Nicole |
| description | A new electrochemical thin film glassy carbon sensor for nitrate detection based on a copper complex, namely melaminium chloride pentachlorocuprate (H
2
mela)ClCuCl
5
(mela = melamine), as a novel ionophore in plasticized polyvinyl chloride matrix was elaborated. The title complex was synthesized and characterized using FT-IR spectroscopy and single-crystal X-ray diffraction. To improve the sensitivity, the optimal pH value was evaluated and the effect of plasticizer was performed using three different plasticizing solvent mediators: dioctyl sebacate, dibutyl phthalate, and
o
-nitrophenyl octyl ether. The optimum performance was observed at pH 4 with the membrane incorporating dioctyl sebacate as a plasticizer. Cyclic voltammetry and square wave voltammetry were used to characterize the (H
2
mela)[CuCl
5
]Cl-GC sensor with a potential between 0.3 and 1 V. This sensor was characterized by a wide linear range from 1.2 × 10
−10
M to 1.2 × 10
−7
M, a low limit of detection of 1.2 × 10
−10
M and low response time less than 1 min. This proposed sensor gave good results in the determination of nitrate in water and, therefore, can be used successfully in real samples.
Graphic abstract |
| doi_str_mv | 10.1007/s00706-019-02483-7 |
| format | Article |
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2
mela)ClCuCl
5
(mela = melamine), as a novel ionophore in plasticized polyvinyl chloride matrix was elaborated. The title complex was synthesized and characterized using FT-IR spectroscopy and single-crystal X-ray diffraction. To improve the sensitivity, the optimal pH value was evaluated and the effect of plasticizer was performed using three different plasticizing solvent mediators: dioctyl sebacate, dibutyl phthalate, and
o
-nitrophenyl octyl ether. The optimum performance was observed at pH 4 with the membrane incorporating dioctyl sebacate as a plasticizer. Cyclic voltammetry and square wave voltammetry were used to characterize the (H
2
mela)[CuCl
5
]Cl-GC sensor with a potential between 0.3 and 1 V. This sensor was characterized by a wide linear range from 1.2 × 10
−10
M to 1.2 × 10
−7
M, a low limit of detection of 1.2 × 10
−10
M and low response time less than 1 min. This proposed sensor gave good results in the determination of nitrate in water and, therefore, can be used successfully in real samples.
Graphic abstract</description><identifier>ISSN: 0026-9247</identifier><identifier>EISSN: 1434-4475</identifier><identifier>DOI: 10.1007/s00706-019-02483-7</identifier><language>eng</language><publisher>Vienna: Springer Vienna</publisher><subject>Analytical Chemistry ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Coordination compounds ; Copper compounds ; Crystals ; Dibutyl phthalate ; Glassy carbon ; Infrared spectroscopy ; Inorganic Chemistry ; Melamine ; Optimization ; Organic Chemistry ; Original Paper ; Physical Chemistry ; Polyvinyl chloride ; Response time ; Sensitivity analysis ; Sensors ; Single crystals ; Square waves ; Theoretical and Computational Chemistry ; Thin films ; Voltammetry</subject><ispartof>Monatshefte für Chemie, 2019-10, Vol.150 (10), p.1737-1744</ispartof><rights>Springer-Verlag GmbH Austria, part of Springer Nature 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-b711e46869415fc72de792aaee6511f55d49ab5dd0cb64352a5b36d694192d2b3</citedby><cites>FETCH-LOGICAL-c356t-b711e46869415fc72de792aaee6511f55d49ab5dd0cb64352a5b36d694192d2b3</cites><orcidid>0000-0002-6347-9173</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00706-019-02483-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00706-019-02483-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Araar, Hala</creatorcontrib><creatorcontrib>Benounis, Messaoud</creatorcontrib><creatorcontrib>Direm, Amani</creatorcontrib><creatorcontrib>Touati, Amina</creatorcontrib><creatorcontrib>Atailia, Sara</creatorcontrib><creatorcontrib>Barhoumi, Houcine</creatorcontrib><creatorcontrib>Jaffrezic-Renault, Nicole</creatorcontrib><title>A new thin film modified glassy carbon electrode based on melaminium chloride pentachlorocuprate(II) for selective determination of nitrate in water</title><title>Monatshefte für Chemie</title><addtitle>Monatsh Chem</addtitle><description>A new electrochemical thin film glassy carbon sensor for nitrate detection based on a copper complex, namely melaminium chloride pentachlorocuprate (H
2
mela)ClCuCl
5
(mela = melamine), as a novel ionophore in plasticized polyvinyl chloride matrix was elaborated. The title complex was synthesized and characterized using FT-IR spectroscopy and single-crystal X-ray diffraction. To improve the sensitivity, the optimal pH value was evaluated and the effect of plasticizer was performed using three different plasticizing solvent mediators: dioctyl sebacate, dibutyl phthalate, and
o
-nitrophenyl octyl ether. The optimum performance was observed at pH 4 with the membrane incorporating dioctyl sebacate as a plasticizer. Cyclic voltammetry and square wave voltammetry were used to characterize the (H
2
mela)[CuCl
5
]Cl-GC sensor with a potential between 0.3 and 1 V. This sensor was characterized by a wide linear range from 1.2 × 10
−10
M to 1.2 × 10
−7
M, a low limit of detection of 1.2 × 10
−10
M and low response time less than 1 min. This proposed sensor gave good results in the determination of nitrate in water and, therefore, can be used successfully in real samples.
Graphic abstract</description><subject>Analytical Chemistry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Coordination compounds</subject><subject>Copper compounds</subject><subject>Crystals</subject><subject>Dibutyl phthalate</subject><subject>Glassy carbon</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Melamine</subject><subject>Optimization</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Polyvinyl chloride</subject><subject>Response time</subject><subject>Sensitivity analysis</subject><subject>Sensors</subject><subject>Single crystals</subject><subject>Square waves</subject><subject>Theoretical and Computational Chemistry</subject><subject>Thin films</subject><subject>Voltammetry</subject><issn>0026-9247</issn><issn>1434-4475</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwzAQRS0EEuXxA6wssYFFwM-kWVYVj0qV2MDacuJJ6yqJi-1Q9T_4YNwGiR0LezSec-9YF6EbSh4oIcVjSBfJM0LLjDAx5VlxgiZUcJEJUchTNCGE5VnJRHGOLkLYkNQLwifoe4Z72OG4tj1ubNvhzhnbWDB41eoQ9rjWvnI9hhbq6J0BXOmQpumpg1Z3trdDh-t167xNwy30UR87Vw9bryPcLRb3uHEeh6OF_QJsIIJPSh1tsnEN7m08oDj9YZeqv0JnjW4DXP_WS_Tx_PQ-f82Wby-L-WyZ1VzmMasKSkHk07wUVDZ1wQwUJdMaIJeUNlIaUepKGkPqKhdcMi0rnpsDXjLDKn6JbkffrXefA4SoNm7wfVqpGCc8nangiWIjVXsXgodGbb3ttN8rStQhfTWmr1L66pi-KpKIj6KQ4H4F_s_6H9UPYp6KRw</recordid><startdate>20191001</startdate><enddate>20191001</enddate><creator>Araar, Hala</creator><creator>Benounis, Messaoud</creator><creator>Direm, Amani</creator><creator>Touati, Amina</creator><creator>Atailia, Sara</creator><creator>Barhoumi, Houcine</creator><creator>Jaffrezic-Renault, Nicole</creator><general>Springer Vienna</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-6347-9173</orcidid></search><sort><creationdate>20191001</creationdate><title>A new thin film modified glassy carbon electrode based on melaminium chloride pentachlorocuprate(II) for selective determination of nitrate in water</title><author>Araar, Hala ; Benounis, Messaoud ; Direm, Amani ; Touati, Amina ; Atailia, Sara ; Barhoumi, Houcine ; Jaffrezic-Renault, Nicole</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-b711e46869415fc72de792aaee6511f55d49ab5dd0cb64352a5b36d694192d2b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Analytical Chemistry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Coordination compounds</topic><topic>Copper compounds</topic><topic>Crystals</topic><topic>Dibutyl phthalate</topic><topic>Glassy carbon</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Melamine</topic><topic>Optimization</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Polyvinyl chloride</topic><topic>Response time</topic><topic>Sensitivity analysis</topic><topic>Sensors</topic><topic>Single crystals</topic><topic>Square waves</topic><topic>Theoretical and Computational Chemistry</topic><topic>Thin films</topic><topic>Voltammetry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Araar, Hala</creatorcontrib><creatorcontrib>Benounis, Messaoud</creatorcontrib><creatorcontrib>Direm, Amani</creatorcontrib><creatorcontrib>Touati, Amina</creatorcontrib><creatorcontrib>Atailia, Sara</creatorcontrib><creatorcontrib>Barhoumi, Houcine</creatorcontrib><creatorcontrib>Jaffrezic-Renault, Nicole</creatorcontrib><collection>CrossRef</collection><jtitle>Monatshefte für Chemie</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Araar, Hala</au><au>Benounis, Messaoud</au><au>Direm, Amani</au><au>Touati, Amina</au><au>Atailia, Sara</au><au>Barhoumi, Houcine</au><au>Jaffrezic-Renault, Nicole</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A new thin film modified glassy carbon electrode based on melaminium chloride pentachlorocuprate(II) for selective determination of nitrate in water</atitle><jtitle>Monatshefte für Chemie</jtitle><stitle>Monatsh Chem</stitle><date>2019-10-01</date><risdate>2019</risdate><volume>150</volume><issue>10</issue><spage>1737</spage><epage>1744</epage><pages>1737-1744</pages><issn>0026-9247</issn><eissn>1434-4475</eissn><abstract>A new electrochemical thin film glassy carbon sensor for nitrate detection based on a copper complex, namely melaminium chloride pentachlorocuprate (H
2
mela)ClCuCl
5
(mela = melamine), as a novel ionophore in plasticized polyvinyl chloride matrix was elaborated. The title complex was synthesized and characterized using FT-IR spectroscopy and single-crystal X-ray diffraction. To improve the sensitivity, the optimal pH value was evaluated and the effect of plasticizer was performed using three different plasticizing solvent mediators: dioctyl sebacate, dibutyl phthalate, and
o
-nitrophenyl octyl ether. The optimum performance was observed at pH 4 with the membrane incorporating dioctyl sebacate as a plasticizer. Cyclic voltammetry and square wave voltammetry were used to characterize the (H
2
mela)[CuCl
5
]Cl-GC sensor with a potential between 0.3 and 1 V. This sensor was characterized by a wide linear range from 1.2 × 10
−10
M to 1.2 × 10
−7
M, a low limit of detection of 1.2 × 10
−10
M and low response time less than 1 min. This proposed sensor gave good results in the determination of nitrate in water and, therefore, can be used successfully in real samples.
Graphic abstract</abstract><cop>Vienna</cop><pub>Springer Vienna</pub><doi>10.1007/s00706-019-02483-7</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-6347-9173</orcidid></addata></record> |
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| subjects | Analytical Chemistry Chemistry Chemistry and Materials Science Chemistry/Food Science Coordination compounds Copper compounds Crystals Dibutyl phthalate Glassy carbon Infrared spectroscopy Inorganic Chemistry Melamine Optimization Organic Chemistry Original Paper Physical Chemistry Polyvinyl chloride Response time Sensitivity analysis Sensors Single crystals Square waves Theoretical and Computational Chemistry Thin films Voltammetry |
| title | A new thin film modified glassy carbon electrode based on melaminium chloride pentachlorocuprate(II) for selective determination of nitrate in water |
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