Highly transparent films of new copolyesters derived from terephthalic and 2,4-furandicarboxylic acids
In this study transparent films of poly(ethylene terephthalate)- co -(ethylene 2,4-furandicarboxylate) (PET- co -2,4-PEF) copolymers were developed for the first time, exploring the ability of 2,4-furandicarboxylic acid (2,4-FDCA) to impart excellent optical properties to the polymers thereof. The p...
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| Veröffentlicht in: | Polymer chemistry 2019-10, Vol.1 (39), p.5324-5332 |
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| container_title | Polymer chemistry |
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| creator | Zaidi, Sami Thiyagarajan, Shanmugam Bougarech, Abdelkader Sebti, Fouzia Abid, Souhir Majdi, Abid Silvestre, Armando J. D Sousa, Andreia F |
| description | In this study transparent films of poly(ethylene terephthalate)-
co
-(ethylene 2,4-furandicarboxylate) (PET-
co
-2,4-PEF) copolymers were developed for the first time, exploring the ability of 2,4-furandicarboxylic acid (2,4-FDCA) to impart excellent optical properties to the polymers thereof. The properties were fine-tuned by feeding this furan monomer content. For example, specifically up to 15 mol% the copolyesters were semi-crystalline in nature, and they were amorphous materials when exceeding the limits of 50 mol% and above. The amorphous polymers had excellent thermal stability over 400 °C, in combination with high transmittance at the wavelength of 555 nm.
Transparent films of poly(ethylene terephthalate)-
co
-(ethylene 2,4-furandicarboxylate)s (PET-
co
-2,4-PEFs) were developed here for the first time, exploring the ability of 2,4-FDCA to impart excellent optical properties to the polymers thereof. |
| doi_str_mv | 10.1039/c9py00844f |
| format | Article |
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co
-(ethylene 2,4-furandicarboxylate) (PET-
co
-2,4-PEF) copolymers were developed for the first time, exploring the ability of 2,4-furandicarboxylic acid (2,4-FDCA) to impart excellent optical properties to the polymers thereof. The properties were fine-tuned by feeding this furan monomer content. For example, specifically up to 15 mol% the copolyesters were semi-crystalline in nature, and they were amorphous materials when exceeding the limits of 50 mol% and above. The amorphous polymers had excellent thermal stability over 400 °C, in combination with high transmittance at the wavelength of 555 nm.
Transparent films of poly(ethylene terephthalate)-
co
-(ethylene 2,4-furandicarboxylate)s (PET-
co
-2,4-PEFs) were developed here for the first time, exploring the ability of 2,4-FDCA to impart excellent optical properties to the polymers thereof.</description><identifier>ISSN: 1759-9954</identifier><identifier>EISSN: 1759-9962</identifier><identifier>DOI: 10.1039/c9py00844f</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Amorphous materials ; Ethylene ; NMR ; Nuclear magnetic resonance ; Optical properties ; Polyethylene terephthalate ; Polymer chemistry ; Polymers ; Thermal stability ; Tin</subject><ispartof>Polymer chemistry, 2019-10, Vol.1 (39), p.5324-5332</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c307t-9ff4ab0f9d5791f377300afdbbb92a9b7f4f7d1492f1fc5e1caa029e265243f33</citedby><cites>FETCH-LOGICAL-c307t-9ff4ab0f9d5791f377300afdbbb92a9b7f4f7d1492f1fc5e1caa029e265243f33</cites><orcidid>0000-0002-7905-4233 ; 0000-0001-5403-8416 ; 0000-0003-3044-3016 ; 0000-0003-0456-0876 ; 0000-0001-8646-7696 ; 0000-0003-3100-7777 ; 0000-0002-4574-3786</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Zaidi, Sami</creatorcontrib><creatorcontrib>Thiyagarajan, Shanmugam</creatorcontrib><creatorcontrib>Bougarech, Abdelkader</creatorcontrib><creatorcontrib>Sebti, Fouzia</creatorcontrib><creatorcontrib>Abid, Souhir</creatorcontrib><creatorcontrib>Majdi, Abid</creatorcontrib><creatorcontrib>Silvestre, Armando J. D</creatorcontrib><creatorcontrib>Sousa, Andreia F</creatorcontrib><title>Highly transparent films of new copolyesters derived from terephthalic and 2,4-furandicarboxylic acids</title><title>Polymer chemistry</title><description>In this study transparent films of poly(ethylene terephthalate)-
co
-(ethylene 2,4-furandicarboxylate) (PET-
co
-2,4-PEF) copolymers were developed for the first time, exploring the ability of 2,4-furandicarboxylic acid (2,4-FDCA) to impart excellent optical properties to the polymers thereof. The properties were fine-tuned by feeding this furan monomer content. For example, specifically up to 15 mol% the copolyesters were semi-crystalline in nature, and they were amorphous materials when exceeding the limits of 50 mol% and above. The amorphous polymers had excellent thermal stability over 400 °C, in combination with high transmittance at the wavelength of 555 nm.
Transparent films of poly(ethylene terephthalate)-
co
-(ethylene 2,4-furandicarboxylate)s (PET-
co
-2,4-PEFs) were developed here for the first time, exploring the ability of 2,4-FDCA to impart excellent optical properties to the polymers thereof.</description><subject>Amorphous materials</subject><subject>Ethylene</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Optical properties</subject><subject>Polyethylene terephthalate</subject><subject>Polymer chemistry</subject><subject>Polymers</subject><subject>Thermal stability</subject><subject>Tin</subject><issn>1759-9954</issn><issn>1759-9962</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kM1LAzEQxYMoWGov3oWIN3E1X9uYoxRrhYIe9OBpySYZu2W7WZOtuv-9aSv15lxmmPfjzfAQOqXkmhKuboxqe0JuhYADNKAyV5lSY3a4n3NxjEYxLkkqTgXj4wGCWfW-qHvcBd3EVgfXdBiqehWxB9y4L2x86-vexc6FiK0L1aezGIJf4bRx7aJb6LoyWDcWsyuRwToZ2croUPrvfquYysYTdAS6jm7024fodXr_Mpll86eHx8ndPDOcyC5TAEKXBJTNpaLApeSEaLBlWSqmVSlBgLRUKAYUTO6o0Zow5dg4Z4ID50N0sfNtg_9Yp6-LpV-HJp0sGE8kIUJuqMsdZYKPMTgo2lCtdOgLSopNlMVEPb9to5wm-GwHh2j23F_UST__Ty9aC_wHoJV9cw</recordid><startdate>20191021</startdate><enddate>20191021</enddate><creator>Zaidi, Sami</creator><creator>Thiyagarajan, Shanmugam</creator><creator>Bougarech, Abdelkader</creator><creator>Sebti, Fouzia</creator><creator>Abid, Souhir</creator><creator>Majdi, Abid</creator><creator>Silvestre, Armando J. D</creator><creator>Sousa, Andreia F</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-7905-4233</orcidid><orcidid>https://orcid.org/0000-0001-5403-8416</orcidid><orcidid>https://orcid.org/0000-0003-3044-3016</orcidid><orcidid>https://orcid.org/0000-0003-0456-0876</orcidid><orcidid>https://orcid.org/0000-0001-8646-7696</orcidid><orcidid>https://orcid.org/0000-0003-3100-7777</orcidid><orcidid>https://orcid.org/0000-0002-4574-3786</orcidid></search><sort><creationdate>20191021</creationdate><title>Highly transparent films of new copolyesters derived from terephthalic and 2,4-furandicarboxylic acids</title><author>Zaidi, Sami ; Thiyagarajan, Shanmugam ; Bougarech, Abdelkader ; Sebti, Fouzia ; Abid, Souhir ; Majdi, Abid ; Silvestre, Armando J. D ; Sousa, Andreia F</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c307t-9ff4ab0f9d5791f377300afdbbb92a9b7f4f7d1492f1fc5e1caa029e265243f33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Amorphous materials</topic><topic>Ethylene</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Optical properties</topic><topic>Polyethylene terephthalate</topic><topic>Polymer chemistry</topic><topic>Polymers</topic><topic>Thermal stability</topic><topic>Tin</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zaidi, Sami</creatorcontrib><creatorcontrib>Thiyagarajan, Shanmugam</creatorcontrib><creatorcontrib>Bougarech, Abdelkader</creatorcontrib><creatorcontrib>Sebti, Fouzia</creatorcontrib><creatorcontrib>Abid, Souhir</creatorcontrib><creatorcontrib>Majdi, Abid</creatorcontrib><creatorcontrib>Silvestre, Armando J. D</creatorcontrib><creatorcontrib>Sousa, Andreia F</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zaidi, Sami</au><au>Thiyagarajan, Shanmugam</au><au>Bougarech, Abdelkader</au><au>Sebti, Fouzia</au><au>Abid, Souhir</au><au>Majdi, Abid</au><au>Silvestre, Armando J. D</au><au>Sousa, Andreia F</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Highly transparent films of new copolyesters derived from terephthalic and 2,4-furandicarboxylic acids</atitle><jtitle>Polymer chemistry</jtitle><date>2019-10-21</date><risdate>2019</risdate><volume>1</volume><issue>39</issue><spage>5324</spage><epage>5332</epage><pages>5324-5332</pages><issn>1759-9954</issn><eissn>1759-9962</eissn><abstract>In this study transparent films of poly(ethylene terephthalate)-
co
-(ethylene 2,4-furandicarboxylate) (PET-
co
-2,4-PEF) copolymers were developed for the first time, exploring the ability of 2,4-furandicarboxylic acid (2,4-FDCA) to impart excellent optical properties to the polymers thereof. The properties were fine-tuned by feeding this furan monomer content. For example, specifically up to 15 mol% the copolyesters were semi-crystalline in nature, and they were amorphous materials when exceeding the limits of 50 mol% and above. The amorphous polymers had excellent thermal stability over 400 °C, in combination with high transmittance at the wavelength of 555 nm.
Transparent films of poly(ethylene terephthalate)-
co
-(ethylene 2,4-furandicarboxylate)s (PET-
co
-2,4-PEFs) were developed here for the first time, exploring the ability of 2,4-FDCA to impart excellent optical properties to the polymers thereof.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c9py00844f</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-7905-4233</orcidid><orcidid>https://orcid.org/0000-0001-5403-8416</orcidid><orcidid>https://orcid.org/0000-0003-3044-3016</orcidid><orcidid>https://orcid.org/0000-0003-0456-0876</orcidid><orcidid>https://orcid.org/0000-0001-8646-7696</orcidid><orcidid>https://orcid.org/0000-0003-3100-7777</orcidid><orcidid>https://orcid.org/0000-0002-4574-3786</orcidid></addata></record> |
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| ispartof | Polymer chemistry, 2019-10, Vol.1 (39), p.5324-5332 |
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| language | eng |
| recordid | cdi_proquest_journals_2302900473 |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Amorphous materials Ethylene NMR Nuclear magnetic resonance Optical properties Polyethylene terephthalate Polymer chemistry Polymers Thermal stability Tin |
| title | Highly transparent films of new copolyesters derived from terephthalic and 2,4-furandicarboxylic acids |
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