High‐efficiency preparation of polypropylene nanofiber by melt differential centrifugal electrospinning
ABSTRACT Melt differential centrifugal electrospinning (MDCE) method is proposed by integrating the advantages of centrifugal spinning and melt differential electrospinning, including high efficiency, solvent‐free, multiple jets formation from nozzle‐less spinning system, and small diameter. A mathe...
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| Veröffentlicht in: | Journal of applied polymer science 2020-01, Vol.137 (3), p.n/a |
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| container_title | Journal of applied polymer science |
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| creator | Liu, Yu‐Jian Tan, Jing Yu, Shao‐Yang Yousefzadeh, Maryam Lyu, Ting‐ting Jiao, Zhi‐Wei Li, Hao‐yi Ramakrishna, Seeram |
| description | ABSTRACT
Melt differential centrifugal electrospinning (MDCE) method is proposed by integrating the advantages of centrifugal spinning and melt differential electrospinning, including high efficiency, solvent‐free, multiple jets formation from nozzle‐less spinning system, and small diameter. A mathematical model of jet diameter in MDCE is established. An orthogonal experiment is carried out to explore the effects of main processing parameters on the average diameter and the diameter standard deviation of the prepared fibers. Ultimately, polypropylene (PP) nanofibers with an average diameter of 790 nm are successfully prepared in a higher flow rate of 124.26 g h−1 than that of other methods. The X‐ray diffraction and differential scanning calorimeter indicate that the introduction of high‐voltage electrostatic field in centrifugal spinning contribute to the crystal orientation of the PP molecular chain. Therefore, tensile mechanical strength is enhanced as the increase of the loading voltage. MDCE may provide an efficient and eco‐friendly method for nanofiber manufacturing in the future. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020, 137, 48299. |
| doi_str_mv | 10.1002/app.48299 |
| format | Article |
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Melt differential centrifugal electrospinning (MDCE) method is proposed by integrating the advantages of centrifugal spinning and melt differential electrospinning, including high efficiency, solvent‐free, multiple jets formation from nozzle‐less spinning system, and small diameter. A mathematical model of jet diameter in MDCE is established. An orthogonal experiment is carried out to explore the effects of main processing parameters on the average diameter and the diameter standard deviation of the prepared fibers. Ultimately, polypropylene (PP) nanofibers with an average diameter of 790 nm are successfully prepared in a higher flow rate of 124.26 g h−1 than that of other methods. The X‐ray diffraction and differential scanning calorimeter indicate that the introduction of high‐voltage electrostatic field in centrifugal spinning contribute to the crystal orientation of the PP molecular chain. Therefore, tensile mechanical strength is enhanced as the increase of the loading voltage. MDCE may provide an efficient and eco‐friendly method for nanofiber manufacturing in the future. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020, 137, 48299.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.48299</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley & Sons, Inc</publisher><subject>centrifugal electrospinning ; Crystal structure ; Electric fields ; Electric potential ; Electrospinning ; Flow velocity ; high production efficiency ; industrialization ; Materials science ; mathematical ; Molecular chains ; Nanofibers ; Nozzles ; Polymers ; Polypropylene ; Process parameters ; Voltage</subject><ispartof>Journal of applied polymer science, 2020-01, Vol.137 (3), p.n/a</ispartof><rights>2019 Wiley Periodicals, Inc.</rights><rights>2020 Wiley Periodicals, Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4009-346b4981f90cc2a0bb0622d238219e05a06d8e3de4b10c3cb17e6a623405daa63</citedby><cites>FETCH-LOGICAL-c4009-346b4981f90cc2a0bb0622d238219e05a06d8e3de4b10c3cb17e6a623405daa63</cites><orcidid>0000-0003-3892-9264</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.48299$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.48299$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Liu, Yu‐Jian</creatorcontrib><creatorcontrib>Tan, Jing</creatorcontrib><creatorcontrib>Yu, Shao‐Yang</creatorcontrib><creatorcontrib>Yousefzadeh, Maryam</creatorcontrib><creatorcontrib>Lyu, Ting‐ting</creatorcontrib><creatorcontrib>Jiao, Zhi‐Wei</creatorcontrib><creatorcontrib>Li, Hao‐yi</creatorcontrib><creatorcontrib>Ramakrishna, Seeram</creatorcontrib><title>High‐efficiency preparation of polypropylene nanofiber by melt differential centrifugal electrospinning</title><title>Journal of applied polymer science</title><description>ABSTRACT
Melt differential centrifugal electrospinning (MDCE) method is proposed by integrating the advantages of centrifugal spinning and melt differential electrospinning, including high efficiency, solvent‐free, multiple jets formation from nozzle‐less spinning system, and small diameter. A mathematical model of jet diameter in MDCE is established. An orthogonal experiment is carried out to explore the effects of main processing parameters on the average diameter and the diameter standard deviation of the prepared fibers. Ultimately, polypropylene (PP) nanofibers with an average diameter of 790 nm are successfully prepared in a higher flow rate of 124.26 g h−1 than that of other methods. The X‐ray diffraction and differential scanning calorimeter indicate that the introduction of high‐voltage electrostatic field in centrifugal spinning contribute to the crystal orientation of the PP molecular chain. Therefore, tensile mechanical strength is enhanced as the increase of the loading voltage. MDCE may provide an efficient and eco‐friendly method for nanofiber manufacturing in the future. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020, 137, 48299.</description><subject>centrifugal electrospinning</subject><subject>Crystal structure</subject><subject>Electric fields</subject><subject>Electric potential</subject><subject>Electrospinning</subject><subject>Flow velocity</subject><subject>high production efficiency</subject><subject>industrialization</subject><subject>Materials science</subject><subject>mathematical</subject><subject>Molecular chains</subject><subject>Nanofibers</subject><subject>Nozzles</subject><subject>Polymers</subject><subject>Polypropylene</subject><subject>Process parameters</subject><subject>Voltage</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1kEFOwzAQRS0EEqWw4AaRWLFIO3YcN15WFVCkSnQB68hxxsVV6hgnFcqOI3BGToIhbFn9keb9ma9PyDWFGQVgc-X9jBdMyhMyoSAXKResOCWTuKNpIWV-Ti66bg9AaQ5iQuza7l6_Pj7RGKstOj0kPqBXQfW2dUlrEt82gw-tHxp0mDjlWmMrDEk1JAds-qS2xmBA11vVJDpqsOa4izM2qPvQdt46Z93ukpwZ1XR49adT8nJ_97xap5unh8fVcpNqDiDTjIuKy4IaCVozBVUFgrGaZQWjEiFXIOoCsxp5RUFnuqILFEqwjENeKyWyKbkZ78bQb0fs-nLfHoOLL0uWActzTjMeqduR0jFhF9CUPtiDCkNJofxpsoxNlr9NRnY-su-2weF_sFxut6PjGzcteBg</recordid><startdate>20200115</startdate><enddate>20200115</enddate><creator>Liu, Yu‐Jian</creator><creator>Tan, Jing</creator><creator>Yu, Shao‐Yang</creator><creator>Yousefzadeh, Maryam</creator><creator>Lyu, Ting‐ting</creator><creator>Jiao, Zhi‐Wei</creator><creator>Li, Hao‐yi</creator><creator>Ramakrishna, Seeram</creator><general>John Wiley & Sons, Inc</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-3892-9264</orcidid></search><sort><creationdate>20200115</creationdate><title>High‐efficiency preparation of polypropylene nanofiber by melt differential centrifugal electrospinning</title><author>Liu, Yu‐Jian ; Tan, Jing ; Yu, Shao‐Yang ; Yousefzadeh, Maryam ; Lyu, Ting‐ting ; Jiao, Zhi‐Wei ; Li, Hao‐yi ; Ramakrishna, Seeram</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4009-346b4981f90cc2a0bb0622d238219e05a06d8e3de4b10c3cb17e6a623405daa63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>centrifugal electrospinning</topic><topic>Crystal structure</topic><topic>Electric fields</topic><topic>Electric potential</topic><topic>Electrospinning</topic><topic>Flow velocity</topic><topic>high production efficiency</topic><topic>industrialization</topic><topic>Materials science</topic><topic>mathematical</topic><topic>Molecular chains</topic><topic>Nanofibers</topic><topic>Nozzles</topic><topic>Polymers</topic><topic>Polypropylene</topic><topic>Process parameters</topic><topic>Voltage</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Yu‐Jian</creatorcontrib><creatorcontrib>Tan, Jing</creatorcontrib><creatorcontrib>Yu, Shao‐Yang</creatorcontrib><creatorcontrib>Yousefzadeh, Maryam</creatorcontrib><creatorcontrib>Lyu, Ting‐ting</creatorcontrib><creatorcontrib>Jiao, Zhi‐Wei</creatorcontrib><creatorcontrib>Li, Hao‐yi</creatorcontrib><creatorcontrib>Ramakrishna, Seeram</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Yu‐Jian</au><au>Tan, Jing</au><au>Yu, Shao‐Yang</au><au>Yousefzadeh, Maryam</au><au>Lyu, Ting‐ting</au><au>Jiao, Zhi‐Wei</au><au>Li, Hao‐yi</au><au>Ramakrishna, Seeram</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>High‐efficiency preparation of polypropylene nanofiber by melt differential centrifugal electrospinning</atitle><jtitle>Journal of applied polymer science</jtitle><date>2020-01-15</date><risdate>2020</risdate><volume>137</volume><issue>3</issue><epage>n/a</epage><issn>0021-8995</issn><eissn>1097-4628</eissn><abstract>ABSTRACT
Melt differential centrifugal electrospinning (MDCE) method is proposed by integrating the advantages of centrifugal spinning and melt differential electrospinning, including high efficiency, solvent‐free, multiple jets formation from nozzle‐less spinning system, and small diameter. A mathematical model of jet diameter in MDCE is established. An orthogonal experiment is carried out to explore the effects of main processing parameters on the average diameter and the diameter standard deviation of the prepared fibers. Ultimately, polypropylene (PP) nanofibers with an average diameter of 790 nm are successfully prepared in a higher flow rate of 124.26 g h−1 than that of other methods. The X‐ray diffraction and differential scanning calorimeter indicate that the introduction of high‐voltage electrostatic field in centrifugal spinning contribute to the crystal orientation of the PP molecular chain. Therefore, tensile mechanical strength is enhanced as the increase of the loading voltage. MDCE may provide an efficient and eco‐friendly method for nanofiber manufacturing in the future. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020, 137, 48299.</abstract><cop>Hoboken, USA</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/app.48299</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0003-3892-9264</orcidid></addata></record> |
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| subjects | centrifugal electrospinning Crystal structure Electric fields Electric potential Electrospinning Flow velocity high production efficiency industrialization Materials science mathematical Molecular chains Nanofibers Nozzles Polymers Polypropylene Process parameters Voltage |
| title | High‐efficiency preparation of polypropylene nanofiber by melt differential centrifugal electrospinning |
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