Conformation and Planar Chirality of Pillar[n]arenes

Conformation and Planar Chirality of Pillar[n]arenes

The conformations and planar chirality of macrocyclic hosts are of great importance because of their large influence on the complexation abilities and selectivities of the host molecules. Pillar[n]arenes are a class of macrocyclic hosts that have attracted great interest over the past decade since t...

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Veröffentlicht in:Chemistry letters 2019-10, Vol.48 (10), p.1278-1287
Hauptverfasser: Fa, Shixin, Kakuta, Takahiro, Yamagishi, Tada-aki, Ogoshi, Tomoki
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Aromatic compounds
Chirality
Enantiomers
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container_end_page 1287
container_issue 10
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container_title Chemistry letters
container_volume 48
creator Fa, Shixin
Kakuta, Takahiro
Yamagishi, Tada-aki
Ogoshi, Tomoki
description The conformations and planar chirality of macrocyclic hosts are of great importance because of their large influence on the complexation abilities and selectivities of the host molecules. Pillar[n]arenes are a class of macrocyclic hosts that have attracted great interest over the past decade since the first example was reported by our research group. Because their phenylene units are connected by methylene bridges at the para-position, pillar[n]arenes have abundant conformational and planar chiral stereoisomers in principle. In this review, we provide an overview of the conformational and planar chiral properties of pillar[n]arenes and their applications.
doi_str_mv 10.1246/cl.190544
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source Oxford University Press Journals All Titles (1996-Current)
subjects Aromatic compounds
Chirality
Enantiomers
title Conformation and Planar Chirality of Pillar[n]arenes
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