Electrochemical single-step obtention and characterization of a biomimetic TiO2-HA NTs covered by chitosan
Obtention of titanium (Ti)- and titanium dioxide (TiO2)–based nanocomposites is of great interest for biological nanomaterial applications, including for dental implants. Their mechanical properties can be improved by use of hydroxyapatite (HA) and chitosan through their biological anchorage with os...
Gespeichert in:
| Veröffentlicht in: | Journal of materials research 2019-06, Vol.34 (11), p.1868-1878 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1878 |
|---|---|
| container_issue | 11 |
| container_start_page | 1868 |
| container_title | Journal of materials research |
| container_volume | 34 |
| creator | Galvão, Rhauane Almeida Santa-Cruz, Larissa Agostinho de Barreto, Paloma Bantim Horta, Marla Karolyne dos Santos Andrade, Antonio Marcos Helgueira de Moura, Francisco José Aguilar, Marilza Sampaio Peripolli, Suzana Bottega Campos, José Brant de Arruda, Isabel Renata de Souza Machado, Giovanna |
| description | Obtention of titanium (Ti)- and titanium dioxide (TiO2)–based nanocomposites is of great interest for biological nanomaterial applications, including for dental implants. Their mechanical properties can be improved by use of hydroxyapatite (HA) and chitosan through their biological anchorage with osseointegration and antibacterial activity. Electrochemical methods were chosen to obtain these composites in a quick and controllable way. In this work, electrochemical synthesis in one (alternated potential) or two steps (alternated or constant potential) was successfully applied. The single step (SS) obtained TiO2 + HA sample had different optical properties, as shown using ultraviolet–visible spectrometry, and the HA phase formation was proved using Raman spectroscopy. Thereby, SS_TiO2 + HA increased the corrosion resistance of titanium in artificial saliva medium, as shown by linear polarization and electrochemical impedance spectroscopy results. When using chitosan, the samples showed two corrosion interfaces, indicating its dissolution in human medium. These results indicate that the samples are excellent materials for dental implants. |
| doi_str_mv | 10.1557/jmr.2019.23 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2300615665</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><cupid>10_1557_jmr_2019_23</cupid><sourcerecordid>2300615665</sourcerecordid><originalsourceid>FETCH-LOGICAL-c336t-2121f797d2dc1eca9448d42743b662c3017ca8ac15fc82ba105d1c55295fd5593</originalsourceid><addsrcrecordid>eNp90E1LAzEQBuAgCtbqyT8Q8Kip-dyPYynVCsVe6nnJzmbbLLubmkSh_nq3tuBFPA0Mz7wDL0K3jE6YUulj0_kJpyyfcHGGRpxKSZTgyTka0SyThOdMXqKrEBpKmaKpHKFm3hqI3sHWdBZ0i4PtN60hIZoddmU0fbSux7qvMGy11xCNt1_6Z-lqrHFpXWc7Ey3gtV1xspji13XA4D6NNxUu98OdjS7o_hpd1LoN5uY0x-jtab6eLchy9fwymy4JCJFEwhlndZqnFa-AGdC5lFkleSpFmSQcBGUp6EwDUzVkvNSMqoqBUjxXdaVULsbo7pi78-79w4RYNO7D98PLggtKE6aSRA3q_qjAuxC8qYudt532-4LR4lBmMZRZHMocrgb9cNRhUP3G-N_Mvzk5heuu9LbamP_9N2WXhXE</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2300615665</pqid></control><display><type>article</type><title>Electrochemical single-step obtention and characterization of a biomimetic TiO2-HA NTs covered by chitosan</title><source>Cambridge Journals</source><source>SpringerLink Journals - AutoHoldings</source><creator>Galvão, Rhauane Almeida ; Santa-Cruz, Larissa Agostinho de ; Barreto, Paloma Bantim ; Horta, Marla Karolyne dos Santos ; Andrade, Antonio Marcos Helgueira de ; Moura, Francisco José ; Aguilar, Marilza Sampaio ; Peripolli, Suzana Bottega ; Campos, José Brant de ; Arruda, Isabel Renata de Souza ; Machado, Giovanna</creator><creatorcontrib>Galvão, Rhauane Almeida ; Santa-Cruz, Larissa Agostinho de ; Barreto, Paloma Bantim ; Horta, Marla Karolyne dos Santos ; Andrade, Antonio Marcos Helgueira de ; Moura, Francisco José ; Aguilar, Marilza Sampaio ; Peripolli, Suzana Bottega ; Campos, José Brant de ; Arruda, Isabel Renata de Souza ; Machado, Giovanna</creatorcontrib><description>Obtention of titanium (Ti)- and titanium dioxide (TiO2)–based nanocomposites is of great interest for biological nanomaterial applications, including for dental implants. Their mechanical properties can be improved by use of hydroxyapatite (HA) and chitosan through their biological anchorage with osseointegration and antibacterial activity. Electrochemical methods were chosen to obtain these composites in a quick and controllable way. In this work, electrochemical synthesis in one (alternated potential) or two steps (alternated or constant potential) was successfully applied. The single step (SS) obtained TiO2 + HA sample had different optical properties, as shown using ultraviolet–visible spectrometry, and the HA phase formation was proved using Raman spectroscopy. Thereby, SS_TiO2 + HA increased the corrosion resistance of titanium in artificial saliva medium, as shown by linear polarization and electrochemical impedance spectroscopy results. When using chitosan, the samples showed two corrosion interfaces, indicating its dissolution in human medium. These results indicate that the samples are excellent materials for dental implants.</description><identifier>ISSN: 0884-2914</identifier><identifier>EISSN: 2044-5326</identifier><identifier>DOI: 10.1557/jmr.2019.23</identifier><language>eng</language><publisher>New York, USA: Cambridge University Press</publisher><subject>Applied and Technical Physics ; Biomaterials ; Biomedical materials ; Biomimetics ; Cell adhesion & migration ; Chitosan ; Corrosion ; Corrosion resistance ; Dental implants ; Dental materials ; Electrochemical impedance spectroscopy ; Electrode polarization ; Hydroxyapatite ; Inorganic Chemistry ; Linear polarization ; Materials Engineering ; Materials research ; Materials Science ; Mechanical properties ; Methods ; Morphology ; Nanocomposites ; Nanomaterials ; Nanotechnology ; Optical properties ; Oxidation ; Phase transitions ; Plasma sintering ; Protective coatings ; Quantum dots ; Raman spectroscopy ; Saliva ; Scanning electron microscopy ; Surgical implants ; Titanium ; Titanium dioxide ; Transplants & implants</subject><ispartof>Journal of materials research, 2019-06, Vol.34 (11), p.1868-1878</ispartof><rights>Copyright © Materials Research Society 2019</rights><rights>The Materials Research Society 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c336t-2121f797d2dc1eca9448d42743b662c3017ca8ac15fc82ba105d1c55295fd5593</citedby><cites>FETCH-LOGICAL-c336t-2121f797d2dc1eca9448d42743b662c3017ca8ac15fc82ba105d1c55295fd5593</cites><orcidid>0000-0002-9058-3056</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1557/jmr.2019.23$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.cambridge.org/core/product/identifier/S0884291419000232/type/journal_article$$EHTML$$P50$$Gcambridge$$H</linktohtml><link.rule.ids>164,314,777,781,27905,27906,41469,42538,51300,55609</link.rule.ids></links><search><creatorcontrib>Galvão, Rhauane Almeida</creatorcontrib><creatorcontrib>Santa-Cruz, Larissa Agostinho de</creatorcontrib><creatorcontrib>Barreto, Paloma Bantim</creatorcontrib><creatorcontrib>Horta, Marla Karolyne dos Santos</creatorcontrib><creatorcontrib>Andrade, Antonio Marcos Helgueira de</creatorcontrib><creatorcontrib>Moura, Francisco José</creatorcontrib><creatorcontrib>Aguilar, Marilza Sampaio</creatorcontrib><creatorcontrib>Peripolli, Suzana Bottega</creatorcontrib><creatorcontrib>Campos, José Brant de</creatorcontrib><creatorcontrib>Arruda, Isabel Renata de Souza</creatorcontrib><creatorcontrib>Machado, Giovanna</creatorcontrib><title>Electrochemical single-step obtention and characterization of a biomimetic TiO2-HA NTs covered by chitosan</title><title>Journal of materials research</title><addtitle>Journal of Materials Research</addtitle><addtitle>J. Mater. Res</addtitle><description>Obtention of titanium (Ti)- and titanium dioxide (TiO2)–based nanocomposites is of great interest for biological nanomaterial applications, including for dental implants. Their mechanical properties can be improved by use of hydroxyapatite (HA) and chitosan through their biological anchorage with osseointegration and antibacterial activity. Electrochemical methods were chosen to obtain these composites in a quick and controllable way. In this work, electrochemical synthesis in one (alternated potential) or two steps (alternated or constant potential) was successfully applied. The single step (SS) obtained TiO2 + HA sample had different optical properties, as shown using ultraviolet–visible spectrometry, and the HA phase formation was proved using Raman spectroscopy. Thereby, SS_TiO2 + HA increased the corrosion resistance of titanium in artificial saliva medium, as shown by linear polarization and electrochemical impedance spectroscopy results. When using chitosan, the samples showed two corrosion interfaces, indicating its dissolution in human medium. These results indicate that the samples are excellent materials for dental implants.</description><subject>Applied and Technical Physics</subject><subject>Biomaterials</subject><subject>Biomedical materials</subject><subject>Biomimetics</subject><subject>Cell adhesion & migration</subject><subject>Chitosan</subject><subject>Corrosion</subject><subject>Corrosion resistance</subject><subject>Dental implants</subject><subject>Dental materials</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrode polarization</subject><subject>Hydroxyapatite</subject><subject>Inorganic Chemistry</subject><subject>Linear polarization</subject><subject>Materials Engineering</subject><subject>Materials research</subject><subject>Materials Science</subject><subject>Mechanical properties</subject><subject>Methods</subject><subject>Morphology</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanotechnology</subject><subject>Optical properties</subject><subject>Oxidation</subject><subject>Phase transitions</subject><subject>Plasma sintering</subject><subject>Protective coatings</subject><subject>Quantum dots</subject><subject>Raman spectroscopy</subject><subject>Saliva</subject><subject>Scanning electron microscopy</subject><subject>Surgical implants</subject><subject>Titanium</subject><subject>Titanium dioxide</subject><subject>Transplants & implants</subject><issn>0884-2914</issn><issn>2044-5326</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp90E1LAzEQBuAgCtbqyT8Q8Kip-dyPYynVCsVe6nnJzmbbLLubmkSh_nq3tuBFPA0Mz7wDL0K3jE6YUulj0_kJpyyfcHGGRpxKSZTgyTka0SyThOdMXqKrEBpKmaKpHKFm3hqI3sHWdBZ0i4PtN60hIZoddmU0fbSux7qvMGy11xCNt1_6Z-lqrHFpXWc7Ey3gtV1xspji13XA4D6NNxUu98OdjS7o_hpd1LoN5uY0x-jtab6eLchy9fwymy4JCJFEwhlndZqnFa-AGdC5lFkleSpFmSQcBGUp6EwDUzVkvNSMqoqBUjxXdaVULsbo7pi78-79w4RYNO7D98PLggtKE6aSRA3q_qjAuxC8qYudt532-4LR4lBmMZRZHMocrgb9cNRhUP3G-N_Mvzk5heuu9LbamP_9N2WXhXE</recordid><startdate>20190614</startdate><enddate>20190614</enddate><creator>Galvão, Rhauane Almeida</creator><creator>Santa-Cruz, Larissa Agostinho de</creator><creator>Barreto, Paloma Bantim</creator><creator>Horta, Marla Karolyne dos Santos</creator><creator>Andrade, Antonio Marcos Helgueira de</creator><creator>Moura, Francisco José</creator><creator>Aguilar, Marilza Sampaio</creator><creator>Peripolli, Suzana Bottega</creator><creator>Campos, José Brant de</creator><creator>Arruda, Isabel Renata de Souza</creator><creator>Machado, Giovanna</creator><general>Cambridge University Press</general><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>0U~</scope><scope>1-H</scope><scope>3V.</scope><scope>7SR</scope><scope>7WY</scope><scope>7WZ</scope><scope>7XB</scope><scope>87Z</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8FL</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>FRNLG</scope><scope>F~G</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>K60</scope><scope>K6~</scope><scope>KB.</scope><scope>L.-</scope><scope>L.0</scope><scope>M0C</scope><scope>PDBOC</scope><scope>PQBIZ</scope><scope>PQBZA</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>S0W</scope><orcidid>https://orcid.org/0000-0002-9058-3056</orcidid></search><sort><creationdate>20190614</creationdate><title>Electrochemical single-step obtention and characterization of a biomimetic TiO2-HA NTs covered by chitosan</title><author>Galvão, Rhauane Almeida ; Santa-Cruz, Larissa Agostinho de ; Barreto, Paloma Bantim ; Horta, Marla Karolyne dos Santos ; Andrade, Antonio Marcos Helgueira de ; Moura, Francisco José ; Aguilar, Marilza Sampaio ; Peripolli, Suzana Bottega ; Campos, José Brant de ; Arruda, Isabel Renata de Souza ; Machado, Giovanna</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c336t-2121f797d2dc1eca9448d42743b662c3017ca8ac15fc82ba105d1c55295fd5593</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Applied and Technical Physics</topic><topic>Biomaterials</topic><topic>Biomedical materials</topic><topic>Biomimetics</topic><topic>Cell adhesion & migration</topic><topic>Chitosan</topic><topic>Corrosion</topic><topic>Corrosion resistance</topic><topic>Dental implants</topic><topic>Dental materials</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrode polarization</topic><topic>Hydroxyapatite</topic><topic>Inorganic Chemistry</topic><topic>Linear polarization</topic><topic>Materials Engineering</topic><topic>Materials research</topic><topic>Materials Science</topic><topic>Mechanical properties</topic><topic>Methods</topic><topic>Morphology</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Nanotechnology</topic><topic>Optical properties</topic><topic>Oxidation</topic><topic>Phase transitions</topic><topic>Plasma sintering</topic><topic>Protective coatings</topic><topic>Quantum dots</topic><topic>Raman spectroscopy</topic><topic>Saliva</topic><topic>Scanning electron microscopy</topic><topic>Surgical implants</topic><topic>Titanium</topic><topic>Titanium dioxide</topic><topic>Transplants & implants</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Galvão, Rhauane Almeida</creatorcontrib><creatorcontrib>Santa-Cruz, Larissa Agostinho de</creatorcontrib><creatorcontrib>Barreto, Paloma Bantim</creatorcontrib><creatorcontrib>Horta, Marla Karolyne dos Santos</creatorcontrib><creatorcontrib>Andrade, Antonio Marcos Helgueira de</creatorcontrib><creatorcontrib>Moura, Francisco José</creatorcontrib><creatorcontrib>Aguilar, Marilza Sampaio</creatorcontrib><creatorcontrib>Peripolli, Suzana Bottega</creatorcontrib><creatorcontrib>Campos, José Brant de</creatorcontrib><creatorcontrib>Arruda, Isabel Renata de Souza</creatorcontrib><creatorcontrib>Machado, Giovanna</creatorcontrib><collection>CrossRef</collection><collection>Global News & ABI/Inform Professional</collection><collection>Trade PRO</collection><collection>ProQuest Central (Corporate)</collection><collection>Engineered Materials Abstracts</collection><collection>ABI/INFORM Collection</collection><collection>ABI/INFORM Global (PDF only)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>ABI/INFORM Global (Alumni Edition)</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ABI/INFORM Collection (Alumni Edition)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Business Premium Collection</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>Business Premium Collection (Alumni)</collection><collection>ABI/INFORM Global (Corporate)</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>ProQuest Business Collection (Alumni Edition)</collection><collection>ProQuest Business Collection</collection><collection>Materials Science Database</collection><collection>ABI/INFORM Professional Advanced</collection><collection>ABI/INFORM Professional Standard</collection><collection>ABI/INFORM Global</collection><collection>Materials Science Collection</collection><collection>ProQuest One Business</collection><collection>ProQuest One Business (Alumni)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><collection>DELNET Engineering & Technology Collection</collection><jtitle>Journal of materials research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Galvão, Rhauane Almeida</au><au>Santa-Cruz, Larissa Agostinho de</au><au>Barreto, Paloma Bantim</au><au>Horta, Marla Karolyne dos Santos</au><au>Andrade, Antonio Marcos Helgueira de</au><au>Moura, Francisco José</au><au>Aguilar, Marilza Sampaio</au><au>Peripolli, Suzana Bottega</au><au>Campos, José Brant de</au><au>Arruda, Isabel Renata de Souza</au><au>Machado, Giovanna</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrochemical single-step obtention and characterization of a biomimetic TiO2-HA NTs covered by chitosan</atitle><jtitle>Journal of materials research</jtitle><stitle>Journal of Materials Research</stitle><addtitle>J. Mater. Res</addtitle><date>2019-06-14</date><risdate>2019</risdate><volume>34</volume><issue>11</issue><spage>1868</spage><epage>1878</epage><pages>1868-1878</pages><issn>0884-2914</issn><eissn>2044-5326</eissn><abstract>Obtention of titanium (Ti)- and titanium dioxide (TiO2)–based nanocomposites is of great interest for biological nanomaterial applications, including for dental implants. Their mechanical properties can be improved by use of hydroxyapatite (HA) and chitosan through their biological anchorage with osseointegration and antibacterial activity. Electrochemical methods were chosen to obtain these composites in a quick and controllable way. In this work, electrochemical synthesis in one (alternated potential) or two steps (alternated or constant potential) was successfully applied. The single step (SS) obtained TiO2 + HA sample had different optical properties, as shown using ultraviolet–visible spectrometry, and the HA phase formation was proved using Raman spectroscopy. Thereby, SS_TiO2 + HA increased the corrosion resistance of titanium in artificial saliva medium, as shown by linear polarization and electrochemical impedance spectroscopy results. When using chitosan, the samples showed two corrosion interfaces, indicating its dissolution in human medium. These results indicate that the samples are excellent materials for dental implants.</abstract><cop>New York, USA</cop><pub>Cambridge University Press</pub><doi>10.1557/jmr.2019.23</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-9058-3056</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0884-2914 |
| ispartof | Journal of materials research, 2019-06, Vol.34 (11), p.1868-1878 |
| issn | 0884-2914 2044-5326 |
| language | eng |
| recordid | cdi_proquest_journals_2300615665 |
| source | Cambridge Journals; SpringerLink Journals - AutoHoldings |
| subjects | Applied and Technical Physics Biomaterials Biomedical materials Biomimetics Cell adhesion & migration Chitosan Corrosion Corrosion resistance Dental implants Dental materials Electrochemical impedance spectroscopy Electrode polarization Hydroxyapatite Inorganic Chemistry Linear polarization Materials Engineering Materials research Materials Science Mechanical properties Methods Morphology Nanocomposites Nanomaterials Nanotechnology Optical properties Oxidation Phase transitions Plasma sintering Protective coatings Quantum dots Raman spectroscopy Saliva Scanning electron microscopy Surgical implants Titanium Titanium dioxide Transplants & implants |
| title | Electrochemical single-step obtention and characterization of a biomimetic TiO2-HA NTs covered by chitosan |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-19T00%3A56%3A11IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Electrochemical%20single-step%20obtention%20and%20characterization%20of%20a%20biomimetic%20TiO2-HA%20NTs%20covered%20by%20chitosan&rft.jtitle=Journal%20of%20materials%20research&rft.au=Galv%C3%A3o,%20Rhauane%20Almeida&rft.date=2019-06-14&rft.volume=34&rft.issue=11&rft.spage=1868&rft.epage=1878&rft.pages=1868-1878&rft.issn=0884-2914&rft.eissn=2044-5326&rft_id=info:doi/10.1557/jmr.2019.23&rft_dat=%3Cproquest_cross%3E2300615665%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2300615665&rft_id=info:pmid/&rft_cupid=10_1557_jmr_2019_23&rfr_iscdi=true |