Supramolecular gold(I) compounds with trithiocyanuric acid: Self‐assembly and luminescent properties
[(N3S3)Au(AuPMe3)2]2 (1) and [(N3S3)Au(AuPEt3)2]2 (2) were prepared by treating AuCl(PMe3) or AuCl(PEt3) with H3N3S3 upon deprotonation by trimethylamine to give respective Au6 supermolecules. Using dppm(AuCl)2 instead of AuCl(PMe3) or AuCl(PEt3) to react with H3N3S3 in a similar reaction condition...
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| Veröffentlicht in: | Journal of the Chinese Chemical Society (Taipei) 2019-09, Vol.66 (9), p.1064-1071 |
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| creator | Tzeng, Biing‐Chiau Chiu, Hsiu‐Hui Chang, Jia‐Hen Lee, Gene‐Hsiang |
| description | [(N3S3)Au(AuPMe3)2]2 (1) and [(N3S3)Au(AuPEt3)2]2 (2) were prepared by treating AuCl(PMe3) or AuCl(PEt3) with H3N3S3 upon deprotonation by trimethylamine to give respective Au6 supermolecules. Using dppm(AuCl)2 instead of AuCl(PMe3) or AuCl(PEt3) to react with H3N3S3 in a similar reaction condition led to a rare heptanuclear supermolecule of [(N3S3)2Au7(dppm)4]Cl (3). It is noted that besides short intramolecular gold(I)⋯gold(I) distances, both compounds 1 and 2 also show intermolecular gold(I)⋯gold(I) distances of 3.067(1) and 3.241(1) Å, resulting in two‐dimensional and one‐dimensional polymeric gold(I) solid, respectively. In fact, compound 1 shows a similar two‐dimensional polymeric gold(I) solid to that of the reported [(N3S3)Au(AuPPhMe2)2]2 with an intermolecular gold(I)⋯gold(I) distance of 3.130(2) Å. Significantly, these intermolecular gold(I)⋯gold(I) distances are well correlated with their cone angles and emission energies. For example, intermolecular gold(I)⋯gold(I) distances increase in the order of 3.067(1) Å |
| doi_str_mv | 10.1002/jccs.201900167 |
| format | Article |
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[(N3S3)2Au7(dppm)4]Cl is a rare heptanuclear gold(I) supermolecule. One important feature is that the N3S3(dppmAu2) moiety forms a 10‐mmbered ring with (dppmAu2)S2 instead of a more common 8‐membered ring of (dppmAu2)NS,22 and additionally there is a long intramolecular gold(I)⋯gold(I) distance of 3.725(5) Å.</description><identifier>ISSN: 0009-4536</identifier><identifier>EISSN: 2192-6549</identifier><identifier>DOI: 10.1002/jccs.201900167</identifier><language>eng</language><publisher>Weinheim: Wiley‐VCH Verlag GmbH & Co. KGaA</publisher><subject>Assembly ; aurophilic ; Charge transfer ; Emission ; Gold ; gold(I)⋯gold(I) ; luminescent ; Optical properties ; self‐assembly ; supramolecular ; Trimethylamine</subject><ispartof>Journal of the Chinese Chemical Society (Taipei), 2019-09, Vol.66 (9), p.1064-1071</ispartof><rights>2019 The Chemical Society Located in Taipei & Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3177-294d0c5653367013e997ff3b9ce5d1cdac719c4e215ad1ca82ecdce604f1b9593</citedby><cites>FETCH-LOGICAL-c3177-294d0c5653367013e997ff3b9ce5d1cdac719c4e215ad1ca82ecdce604f1b9593</cites><orcidid>0000-0001-6946-0281</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fjccs.201900167$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fjccs.201900167$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,27922,27923,45572,45573</link.rule.ids></links><search><creatorcontrib>Tzeng, Biing‐Chiau</creatorcontrib><creatorcontrib>Chiu, Hsiu‐Hui</creatorcontrib><creatorcontrib>Chang, Jia‐Hen</creatorcontrib><creatorcontrib>Lee, Gene‐Hsiang</creatorcontrib><title>Supramolecular gold(I) compounds with trithiocyanuric acid: Self‐assembly and luminescent properties</title><title>Journal of the Chinese Chemical Society (Taipei)</title><description>[(N3S3)Au(AuPMe3)2]2 (1) and [(N3S3)Au(AuPEt3)2]2 (2) were prepared by treating AuCl(PMe3) or AuCl(PEt3) with H3N3S3 upon deprotonation by trimethylamine to give respective Au6 supermolecules. Using dppm(AuCl)2 instead of AuCl(PMe3) or AuCl(PEt3) to react with H3N3S3 in a similar reaction condition led to a rare heptanuclear supermolecule of [(N3S3)2Au7(dppm)4]Cl (3). It is noted that besides short intramolecular gold(I)⋯gold(I) distances, both compounds 1 and 2 also show intermolecular gold(I)⋯gold(I) distances of 3.067(1) and 3.241(1) Å, resulting in two‐dimensional and one‐dimensional polymeric gold(I) solid, respectively. In fact, compound 1 shows a similar two‐dimensional polymeric gold(I) solid to that of the reported [(N3S3)Au(AuPPhMe2)2]2 with an intermolecular gold(I)⋯gold(I) distance of 3.130(2) Å. Significantly, these intermolecular gold(I)⋯gold(I) distances are well correlated with their cone angles and emission energies. For example, intermolecular gold(I)⋯gold(I) distances increase in the order of 3.067(1) Å < 3.130(2) Å < 3.241(1) Å for PMe3 (118°), PPhMe2 (122°), and PEt3 (132°), and their emission energies also increase in the order of 542 nm < 530 nm < 504 nm, respectively. This work highlights a very good correlation between intermolecular aurophilic interactions and emission energies for a series of Au6 supermolecules, where the cone angle plays a vital role in the self‐assembly process as well. Finally, the emissions for 1–3 are tentatively assigned to the S → Au charge‐transfer transition, whereas they are most probably modified by gold(I)⋯gold(I) interactions.
[(N3S3)2Au7(dppm)4]Cl is a rare heptanuclear gold(I) supermolecule. One important feature is that the N3S3(dppmAu2) moiety forms a 10‐mmbered ring with (dppmAu2)S2 instead of a more common 8‐membered ring of (dppmAu2)NS,22 and additionally there is a long intramolecular gold(I)⋯gold(I) distance of 3.725(5) Å.</description><subject>Assembly</subject><subject>aurophilic</subject><subject>Charge transfer</subject><subject>Emission</subject><subject>Gold</subject><subject>gold(I)⋯gold(I)</subject><subject>luminescent</subject><subject>Optical properties</subject><subject>self‐assembly</subject><subject>supramolecular</subject><subject>Trimethylamine</subject><issn>0009-4536</issn><issn>2192-6549</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkL1OwzAUhS0EEqWwMltigSHFP3GC2VDET1ElhsJsuTcOuHLiYCeqsvEIPCNPQqoiGFnu1ZW-c4_OQeiUkhklhF2uAeKMESoJoVm-hyaMSpZkIpX7aEIIkUkqeHaIjmJcE5JyJuQEVcu-Dbr2zkDvdMCv3pXn8wsMvm5935QRb2z3hrswTuth0E0fLGANtrzGS-Oqr49PHaOpV27Auimx62vbmAim6XAbfGtCZ008RgeVdtGc_Owperm7fS4eksXT_by4WSTAaZ4nTKYlAZEJzrOcUG6kzKuKryQYUVIoNeRUQmoYFXq89RUzUILJSFrRlRSST9HZ7u9o_d6b2Km170MzWirGx9Ai5ywdqdmOguBjDKZSbbC1DoOiRG27VNsu1W-Xo0DuBBvrzPAPrR6LYvmn_QbPi3tZ</recordid><startdate>201909</startdate><enddate>201909</enddate><creator>Tzeng, Biing‐Chiau</creator><creator>Chiu, Hsiu‐Hui</creator><creator>Chang, Jia‐Hen</creator><creator>Lee, Gene‐Hsiang</creator><general>Wiley‐VCH Verlag GmbH & Co. KGaA</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-6946-0281</orcidid></search><sort><creationdate>201909</creationdate><title>Supramolecular gold(I) compounds with trithiocyanuric acid: Self‐assembly and luminescent properties</title><author>Tzeng, Biing‐Chiau ; Chiu, Hsiu‐Hui ; Chang, Jia‐Hen ; Lee, Gene‐Hsiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3177-294d0c5653367013e997ff3b9ce5d1cdac719c4e215ad1ca82ecdce604f1b9593</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Assembly</topic><topic>aurophilic</topic><topic>Charge transfer</topic><topic>Emission</topic><topic>Gold</topic><topic>gold(I)⋯gold(I)</topic><topic>luminescent</topic><topic>Optical properties</topic><topic>self‐assembly</topic><topic>supramolecular</topic><topic>Trimethylamine</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tzeng, Biing‐Chiau</creatorcontrib><creatorcontrib>Chiu, Hsiu‐Hui</creatorcontrib><creatorcontrib>Chang, Jia‐Hen</creatorcontrib><creatorcontrib>Lee, Gene‐Hsiang</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of the Chinese Chemical Society (Taipei)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tzeng, Biing‐Chiau</au><au>Chiu, Hsiu‐Hui</au><au>Chang, Jia‐Hen</au><au>Lee, Gene‐Hsiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Supramolecular gold(I) compounds with trithiocyanuric acid: Self‐assembly and luminescent properties</atitle><jtitle>Journal of the Chinese Chemical Society (Taipei)</jtitle><date>2019-09</date><risdate>2019</risdate><volume>66</volume><issue>9</issue><spage>1064</spage><epage>1071</epage><pages>1064-1071</pages><issn>0009-4536</issn><eissn>2192-6549</eissn><abstract>[(N3S3)Au(AuPMe3)2]2 (1) and [(N3S3)Au(AuPEt3)2]2 (2) were prepared by treating AuCl(PMe3) or AuCl(PEt3) with H3N3S3 upon deprotonation by trimethylamine to give respective Au6 supermolecules. Using dppm(AuCl)2 instead of AuCl(PMe3) or AuCl(PEt3) to react with H3N3S3 in a similar reaction condition led to a rare heptanuclear supermolecule of [(N3S3)2Au7(dppm)4]Cl (3). It is noted that besides short intramolecular gold(I)⋯gold(I) distances, both compounds 1 and 2 also show intermolecular gold(I)⋯gold(I) distances of 3.067(1) and 3.241(1) Å, resulting in two‐dimensional and one‐dimensional polymeric gold(I) solid, respectively. In fact, compound 1 shows a similar two‐dimensional polymeric gold(I) solid to that of the reported [(N3S3)Au(AuPPhMe2)2]2 with an intermolecular gold(I)⋯gold(I) distance of 3.130(2) Å. Significantly, these intermolecular gold(I)⋯gold(I) distances are well correlated with their cone angles and emission energies. For example, intermolecular gold(I)⋯gold(I) distances increase in the order of 3.067(1) Å < 3.130(2) Å < 3.241(1) Å for PMe3 (118°), PPhMe2 (122°), and PEt3 (132°), and their emission energies also increase in the order of 542 nm < 530 nm < 504 nm, respectively. This work highlights a very good correlation between intermolecular aurophilic interactions and emission energies for a series of Au6 supermolecules, where the cone angle plays a vital role in the self‐assembly process as well. Finally, the emissions for 1–3 are tentatively assigned to the S → Au charge‐transfer transition, whereas they are most probably modified by gold(I)⋯gold(I) interactions.
[(N3S3)2Au7(dppm)4]Cl is a rare heptanuclear gold(I) supermolecule. One important feature is that the N3S3(dppmAu2) moiety forms a 10‐mmbered ring with (dppmAu2)S2 instead of a more common 8‐membered ring of (dppmAu2)NS,22 and additionally there is a long intramolecular gold(I)⋯gold(I) distance of 3.725(5) Å.</abstract><cop>Weinheim</cop><pub>Wiley‐VCH Verlag GmbH & Co. KGaA</pub><doi>10.1002/jccs.201900167</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0001-6946-0281</orcidid></addata></record> |
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| subjects | Assembly aurophilic Charge transfer Emission Gold gold(I)⋯gold(I) luminescent Optical properties self‐assembly supramolecular Trimethylamine |
| title | Supramolecular gold(I) compounds with trithiocyanuric acid: Self‐assembly and luminescent properties |
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