Low-Frequency Mechanical Effect of Concentrations of Bimolecular Reaction Intermediates on Oscillations in Structured Liquid
A mathematical model of bimolecular chemical reaction with the low-frequency mechanical action and reagents being associated is developed. The difference in reactivity of reagent molecules and their associates is taken into account. The features of the kinetics and stability of reaction modes under...
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| Veröffentlicht in: | Russian journal of physical chemistry. B 2019-07, Vol.13 (4), p.573-576 |
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| container_title | Russian journal of physical chemistry. B |
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| creator | Kulagina, T. P. Smirnov, L. P. Andrianova, Z. S. |
| description | A mathematical model of bimolecular chemical reaction with the low-frequency mechanical action and reagents being associated is developed. The difference in reactivity of reagent molecules and their associates is taken into account. The features of the kinetics and stability of reaction modes under an external low-frequency effect on the reaction rate constants of monomers, dimers, and trimers are determined. The possibility of controlling the transitions from the stable reaction mode to the unstable mode and back when the frequency and amplitude of the external influence is changed is shown. |
| doi_str_mv | 10.1134/S1990793119040109 |
| format | Article |
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P.</creatorcontrib><creatorcontrib>Andrianova, Z. S.</creatorcontrib><title>Low-Frequency Mechanical Effect of Concentrations of Bimolecular Reaction Intermediates on Oscillations in Structured Liquid</title><title>Russian journal of physical chemistry. B</title><addtitle>Russ. J. Phys. Chem. B</addtitle><description>A mathematical model of bimolecular chemical reaction with the low-frequency mechanical action and reagents being associated is developed. The difference in reactivity of reagent molecules and their associates is taken into account. The features of the kinetics and stability of reaction modes under an external low-frequency effect on the reaction rate constants of monomers, dimers, and trimers are determined. 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Catalysis</subject><subject>Organic chemistry</subject><subject>Physical Chemistry</subject><subject>Rate constants</subject><subject>Reaction intermediates</subject><subject>Reaction kinetics</subject><subject>Reagents</subject><subject>Trimers</subject><issn>1990-7931</issn><issn>1990-7923</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1UE1LAzEQDaJgrf4AbwHPq_nY3WyOWlotVApWz0s2m2jKNmmTLFLwx5ulRQ_iaWbevPeGNwBcY3SLMc3vVphzxDjFmKMcYcRPwGiAMsYJPf3pKT4HFyGsESoJ42gEvhbuM5t5teuVlXv4rOSHsEaKDk61VjJCp-HEWals9CIaZ8OAPJiN65TsO-HhixJyWMC5jcpvVGtEVIll4TJI03VHlbFwFX0vY-9VCxdm15v2Epxp0QV1daxj8Dabvk6essXycT65X2SS4jJmjFHW4oLggpOco4I3SLVFWfGcpZmIohU4hWmIIhRXOdEl0xzJimlG26Zq6BjcHHy33qWgIdZr13ubTtaEIkQIy0mVWPjAkt6F4JWut95shN_XGNXDk-s_T04actCExLXvyv86_y_6BpUifn8</recordid><startdate>20190701</startdate><enddate>20190701</enddate><creator>Kulagina, T. P.</creator><creator>Smirnov, L. 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Catalysis</topic><topic>Organic chemistry</topic><topic>Physical Chemistry</topic><topic>Rate constants</topic><topic>Reaction intermediates</topic><topic>Reaction kinetics</topic><topic>Reagents</topic><topic>Trimers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kulagina, T. P.</creatorcontrib><creatorcontrib>Smirnov, L. P.</creatorcontrib><creatorcontrib>Andrianova, Z. S.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of physical chemistry. B</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kulagina, T. P.</au><au>Smirnov, L. P.</au><au>Andrianova, Z. S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Low-Frequency Mechanical Effect of Concentrations of Bimolecular Reaction Intermediates on Oscillations in Structured Liquid</atitle><jtitle>Russian journal of physical chemistry. 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| fulltext | fulltext |
| identifier | ISSN: 1990-7931 |
| ispartof | Russian journal of physical chemistry. B, 2019-07, Vol.13 (4), p.573-576 |
| issn | 1990-7931 1990-7923 |
| language | eng |
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| source | SpringerNature Journals |
| subjects | Chemical reactions Chemistry Chemistry and Materials Science Dimers Kinetics and Mechanism of Chemical Reactions. Catalysis Organic chemistry Physical Chemistry Rate constants Reaction intermediates Reaction kinetics Reagents Trimers |
| title | Low-Frequency Mechanical Effect of Concentrations of Bimolecular Reaction Intermediates on Oscillations in Structured Liquid |
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