Theoretical and experimental investigations of mechanical properties for polymorphous YTaO4 ceramics
In this work, the dense bulk polymorphous YTaO4 ceramics with M or M' phase are synthesized by spark plasma sintering method accompanying with different tempering procedures. Combined with the nano‐indentation and theoretical calculation, their mechanical properties are systematically investiga...
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Veröffentlicht in: | Journal of the American Ceramic Society 2019-12, Vol.102 (12), p.7656-7664 |
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creator | Wu, Peng Zhou, Yunxuan Wu, Fushuo Hu, Mingyu Chong, Xiaoyu Feng, Jing |
description | In this work, the dense bulk polymorphous YTaO4 ceramics with M or M' phase are synthesized by spark plasma sintering method accompanying with different tempering procedures. Combined with the nano‐indentation and theoretical calculation, their mechanical properties are systematically investigated. The identification of crystal structure reveals that the YTaO4 crystallizes into M phase (space group: I2/a) with higher tempering temperature, otherwise it crystallizes into M' phase (space group: P2/a). The results of mechanical properties indicate M‐phase YTaO4 possesses larger Young's modulus and hardness than that of M' phase. It is stemmed from the chemical bonding strength of M phase is stronger than that of M' phase, and the stronger bonding strength of M phase also results in its elastic resilience is superior to M' phase. Besides, on account of the low symmetry of monoclinic crystal system, the Young's modulus of polymorphous YTaO4 ceramics exhibit strong anisotropy. |
doi_str_mv | 10.1111/jace.16629 |
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Combined with the nano‐indentation and theoretical calculation, their mechanical properties are systematically investigated. The identification of crystal structure reveals that the YTaO4 crystallizes into M phase (space group: I2/a) with higher tempering temperature, otherwise it crystallizes into M' phase (space group: P2/a). The results of mechanical properties indicate M‐phase YTaO4 possesses larger Young's modulus and hardness than that of M' phase. It is stemmed from the chemical bonding strength of M phase is stronger than that of M' phase, and the stronger bonding strength of M phase also results in its elastic resilience is superior to M' phase. Besides, on account of the low symmetry of monoclinic crystal system, the Young's modulus of polymorphous YTaO4 ceramics exhibit strong anisotropy.</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/jace.16629</identifier><language>eng</language><publisher>Columbus: Wiley Subscription Services, Inc</publisher><subject>Anisotropy ; Bonding strength ; Bulk density ; Ceramics ; Chemical bonds ; Crystal structure ; first‐principles calculations ; Heat treating ; Indentation ; Mechanical properties ; Modulus of elasticity ; nano‐mechanical properties ; Organic chemistry ; Plasma sintering ; rare earth tantalate ; Spark plasma sintering ; Tempering</subject><ispartof>Journal of the American Ceramic Society, 2019-12, Vol.102 (12), p.7656-7664</ispartof><rights>2019 The American Ceramic Society</rights><rights>2019 American Ceramic Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0001-7031-410X ; 0000-0003-1678-0382 ; 0000-0002-9671-6841</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1111%2Fjace.16629$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1111%2Fjace.16629$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,27915,27916,45565,45566</link.rule.ids></links><search><creatorcontrib>Wu, Peng</creatorcontrib><creatorcontrib>Zhou, Yunxuan</creatorcontrib><creatorcontrib>Wu, Fushuo</creatorcontrib><creatorcontrib>Hu, Mingyu</creatorcontrib><creatorcontrib>Chong, Xiaoyu</creatorcontrib><creatorcontrib>Feng, Jing</creatorcontrib><title>Theoretical and experimental investigations of mechanical properties for polymorphous YTaO4 ceramics</title><title>Journal of the American Ceramic Society</title><description>In this work, the dense bulk polymorphous YTaO4 ceramics with M or M' phase are synthesized by spark plasma sintering method accompanying with different tempering procedures. Combined with the nano‐indentation and theoretical calculation, their mechanical properties are systematically investigated. The identification of crystal structure reveals that the YTaO4 crystallizes into M phase (space group: I2/a) with higher tempering temperature, otherwise it crystallizes into M' phase (space group: P2/a). The results of mechanical properties indicate M‐phase YTaO4 possesses larger Young's modulus and hardness than that of M' phase. It is stemmed from the chemical bonding strength of M phase is stronger than that of M' phase, and the stronger bonding strength of M phase also results in its elastic resilience is superior to M' phase. Besides, on account of the low symmetry of monoclinic crystal system, the Young's modulus of polymorphous YTaO4 ceramics exhibit strong anisotropy.</description><subject>Anisotropy</subject><subject>Bonding strength</subject><subject>Bulk density</subject><subject>Ceramics</subject><subject>Chemical bonds</subject><subject>Crystal structure</subject><subject>first‐principles calculations</subject><subject>Heat treating</subject><subject>Indentation</subject><subject>Mechanical properties</subject><subject>Modulus of elasticity</subject><subject>nano‐mechanical properties</subject><subject>Organic chemistry</subject><subject>Plasma sintering</subject><subject>rare earth tantalate</subject><subject>Spark plasma sintering</subject><subject>Tempering</subject><issn>0002-7820</issn><issn>1551-2916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNotUE1PwzAMjRBIjMKFXxCJc0c--pXjNI0vTdplHDhFbuayTG1Tkg7Yvyfb8MV-9pOf_Qi552zKYzzuwOCUF4VQF2TC85ynQvHikkwYYyItK8GuyU0Iuwi5qrIJ2ay36DyO1kBLod9Q_B3Q2w77MTZs_41htJ8wWtcH6hraodlCf2IP3kXqaDHQxnk6uPbQOT9s3T7QjzWsMmrQQ2dNuCVXDbQB7_5zQt6fFuv5S7pcPb_OZ8t0ECJXaWMKISWHUmHBKgkRV_kmUzmDOC-4KQ1HyZrMqLpWZVWrrIj_1rEvEBqQCXk4742nfe3j5Xrn9r6PklrIaAAXeRRICD-zfmyLBz3Eb8EfNGf6aKE-WqhPFuq32XxxquQfQLxong</recordid><startdate>201912</startdate><enddate>201912</enddate><creator>Wu, Peng</creator><creator>Zhou, Yunxuan</creator><creator>Wu, Fushuo</creator><creator>Hu, Mingyu</creator><creator>Chong, Xiaoyu</creator><creator>Feng, Jing</creator><general>Wiley Subscription Services, Inc</general><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-7031-410X</orcidid><orcidid>https://orcid.org/0000-0003-1678-0382</orcidid><orcidid>https://orcid.org/0000-0002-9671-6841</orcidid></search><sort><creationdate>201912</creationdate><title>Theoretical and experimental investigations of mechanical properties for polymorphous YTaO4 ceramics</title><author>Wu, Peng ; Zhou, Yunxuan ; Wu, Fushuo ; Hu, Mingyu ; Chong, Xiaoyu ; Feng, Jing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p2259-fc62331a79e6083afc685d4950a22561c7c1e30f4c9bb978b946acebc7c2eafa3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Anisotropy</topic><topic>Bonding strength</topic><topic>Bulk density</topic><topic>Ceramics</topic><topic>Chemical bonds</topic><topic>Crystal structure</topic><topic>first‐principles calculations</topic><topic>Heat treating</topic><topic>Indentation</topic><topic>Mechanical properties</topic><topic>Modulus of elasticity</topic><topic>nano‐mechanical properties</topic><topic>Organic chemistry</topic><topic>Plasma sintering</topic><topic>rare earth tantalate</topic><topic>Spark plasma sintering</topic><topic>Tempering</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wu, Peng</creatorcontrib><creatorcontrib>Zhou, Yunxuan</creatorcontrib><creatorcontrib>Wu, Fushuo</creatorcontrib><creatorcontrib>Hu, Mingyu</creatorcontrib><creatorcontrib>Chong, Xiaoyu</creatorcontrib><creatorcontrib>Feng, Jing</creatorcontrib><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of the American Ceramic Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wu, Peng</au><au>Zhou, Yunxuan</au><au>Wu, Fushuo</au><au>Hu, Mingyu</au><au>Chong, Xiaoyu</au><au>Feng, Jing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Theoretical and experimental investigations of mechanical properties for polymorphous YTaO4 ceramics</atitle><jtitle>Journal of the American Ceramic Society</jtitle><date>2019-12</date><risdate>2019</risdate><volume>102</volume><issue>12</issue><spage>7656</spage><epage>7664</epage><pages>7656-7664</pages><issn>0002-7820</issn><eissn>1551-2916</eissn><abstract>In this work, the dense bulk polymorphous YTaO4 ceramics with M or M' phase are synthesized by spark plasma sintering method accompanying with different tempering procedures. Combined with the nano‐indentation and theoretical calculation, their mechanical properties are systematically investigated. The identification of crystal structure reveals that the YTaO4 crystallizes into M phase (space group: I2/a) with higher tempering temperature, otherwise it crystallizes into M' phase (space group: P2/a). The results of mechanical properties indicate M‐phase YTaO4 possesses larger Young's modulus and hardness than that of M' phase. It is stemmed from the chemical bonding strength of M phase is stronger than that of M' phase, and the stronger bonding strength of M phase also results in its elastic resilience is superior to M' phase. Besides, on account of the low symmetry of monoclinic crystal system, the Young's modulus of polymorphous YTaO4 ceramics exhibit strong anisotropy.</abstract><cop>Columbus</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1111/jace.16629</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-7031-410X</orcidid><orcidid>https://orcid.org/0000-0003-1678-0382</orcidid><orcidid>https://orcid.org/0000-0002-9671-6841</orcidid></addata></record> |
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subjects | Anisotropy Bonding strength Bulk density Ceramics Chemical bonds Crystal structure first‐principles calculations Heat treating Indentation Mechanical properties Modulus of elasticity nano‐mechanical properties Organic chemistry Plasma sintering rare earth tantalate Spark plasma sintering Tempering |
title | Theoretical and experimental investigations of mechanical properties for polymorphous YTaO4 ceramics |
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