Environmental Effects on Developing Wheat as Sensed by Near-Infrared Reflectance of Mature Grains

For 30 years, near-infrared (NIR) spectroscopy has routinely been applied to the cereal grains for the purpose of rapidly measuring concentrations of constituents such as protein and moisture. The research described herein examined the ability of NIR reflectance spectroscopy on harvested wheat to de...

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Veröffentlicht in:Cereal chemistry 2002-11, Vol.79 (6), p.885-891
Hauptverfasser: Delwiche, Stephen R, Graybosch, Robert A, Nelson, Lenis A, Hruschka, William R
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creator Delwiche, Stephen R
Graybosch, Robert A
Nelson, Lenis A
Hruschka, William R
description For 30 years, near-infrared (NIR) spectroscopy has routinely been applied to the cereal grains for the purpose of rapidly measuring concentrations of constituents such as protein and moisture. The research described herein examined the ability of NIR reflectance spectroscopy on harvested wheat to determine weather-related, quality-determining properties that occurred during plant development. Twenty commercial cultivars or advanced breeding lines of hard red winter and hard white wheat (Triticum aestivum L.) were grown in 10 geographical locations under prevailing natural conditions of the U.S. Great Plains. Diffuse reflectance spectra (1,100-2,498 nm) of ground wheat from these samples were modeled by partial least squares one (PLS1) and multiple linear regression algorithms for the following properties: SDS sedimentation volume, amount of time during grain fill in which the temperature or relative humidity exceeded or was less than a threshold level (i.e., >30, >32, >35, 80%,
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Partial correlation analysis was used to statistically remove the contribution of protein content from the quantitative NIR models. PLS1 models of 9-11 factors on scatter-corrected and (second order) derivatized spectra produced models whose dimensionless error (RPD, ratio of standard deviation of the property in a test set to the model standard error for that property) ranged from 2.0 to 3.3. Multiple linear regression models, involving the sum of four second-derivative terms with coefficients, produced models of slightly higher error compared with PLS models. For both modeling approaches, partial correlation analysis demonstrated that model success extends beyond an intercorrelation between property and protein content, a constituent that is well-modeled by NIR spectroscopy. 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Partial correlation analysis was used to statistically remove the contribution of protein content from the quantitative NIR models. PLS1 models of 9-11 factors on scatter-corrected and (second order) derivatized spectra produced models whose dimensionless error (RPD, ratio of standard deviation of the property in a test set to the model standard error for that property) ranged from 2.0 to 3.3. Multiple linear regression models, involving the sum of four second-derivative terms with coefficients, produced models of slightly higher error compared with PLS models. For both modeling approaches, partial correlation analysis demonstrated that model success extends beyond an intercorrelation between property and protein content, a constituent that is well-modeled by NIR spectroscopy. 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Quality</topic><topic>hard white wheat</topic><topic>least squares</topic><topic>linear models</topic><topic>near-infrared spectroscopy</topic><topic>plant development</topic><topic>protein content</topic><topic>rain</topic><topic>reflectance</topic><topic>relative humidity</topic><topic>temperature</topic><topic>Triticum aestivum</topic><topic>winter</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Delwiche, Stephen R</creatorcontrib><creatorcontrib>Graybosch, Robert A</creatorcontrib><creatorcontrib>Nelson, Lenis A</creatorcontrib><creatorcontrib>Hruschka, William R</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Docstoc</collection><collection>Agricultural Science Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>Materials Science &amp; Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural &amp; Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Engineering Collection</collection><collection>Agricultural Science Database</collection><collection>Research Library</collection><collection>Engineering Database</collection><collection>Research Library (Corporate)</collection><collection>Environmental Science Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><collection>SIRS Editorial</collection><jtitle>Cereal chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Delwiche, Stephen R</au><au>Graybosch, Robert A</au><au>Nelson, Lenis A</au><au>Hruschka, William R</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Environmental Effects on Developing Wheat as Sensed by Near-Infrared Reflectance of Mature Grains</atitle><jtitle>Cereal chemistry</jtitle><date>2002-11</date><risdate>2002</risdate><volume>79</volume><issue>6</issue><spage>885</spage><epage>891</epage><pages>885-891</pages><issn>0009-0352</issn><eissn>1943-3638</eissn><coden>CECHAF</coden><abstract>For 30 years, near-infrared (NIR) spectroscopy has routinely been applied to the cereal grains for the purpose of rapidly measuring concentrations of constituents such as protein and moisture. The research described herein examined the ability of NIR reflectance spectroscopy on harvested wheat to determine weather-related, quality-determining properties that occurred during plant development. Twenty commercial cultivars or advanced breeding lines of hard red winter and hard white wheat (Triticum aestivum L.) were grown in 10 geographical locations under prevailing natural conditions of the U.S. Great Plains. Diffuse reflectance spectra (1,100-2,498 nm) of ground wheat from these samples were modeled by partial least squares one (PLS1) and multiple linear regression algorithms for the following properties: SDS sedimentation volume, amount of time during grain fill in which the temperature or relative humidity exceeded or was less than a threshold level (i.e., &gt;30, &gt;32, &gt;35, &lt;24°C; &gt;80%, &lt;40% rh). Rainfall values associated with four pre- and post-planting stages also were examined heuristically by PLS2 analysis. Partial correlation analysis was used to statistically remove the contribution of protein content from the quantitative NIR models. PLS1 models of 9-11 factors on scatter-corrected and (second order) derivatized spectra produced models whose dimensionless error (RPD, ratio of standard deviation of the property in a test set to the model standard error for that property) ranged from 2.0 to 3.3. Multiple linear regression models, involving the sum of four second-derivative terms with coefficients, produced models of slightly higher error compared with PLS models. For both modeling approaches, partial correlation analysis demonstrated that model success extends beyond an intercorrelation between property and protein content, a constituent that is well-modeled by NIR spectroscopy. With refinement, these types of NIR models may have the potential to provide grain handlers, millers, and bakers a tool for identifying the cultural environment under which the purchased grain was produced.</abstract><cop>St. Paul, MN</cop><pub>The American Association of Cereal Chemists, Inc</pub><doi>10.1094/CCHEM.2002.79.6.885</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record>
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subjects Agronomy. Soil science and plant productions
algorithms
Biological and medical sciences
breeding
breeding lines
Chemical constitution
cultivars
cultural environment
Economic plant physiology
Fundamental and applied biological sciences. Psychology
General agronomy. Plant production
Generalities. Agricultural and farming systems. Agricultural development
Generalities. Production, biomass, yield. Quality
hard white wheat
least squares
linear models
near-infrared spectroscopy
plant development
protein content
rain
reflectance
relative humidity
temperature
Triticum aestivum
winter
title Environmental Effects on Developing Wheat as Sensed by Near-Infrared Reflectance of Mature Grains
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