Zinc ion interactions in a two-dimensional covalent organic framework based aqueous zinc ion battery
The two-dimensional structural features of covalent organic frameworks (COFs) can promote the electrochemical storage of cations like H + , Li + , and Na + through both faradaic and non-faradaic processes. However, the electrochemical storage of cations like Zn 2+ ion is still unexplored although it...
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| Veröffentlicht in: | Chemical science (Cambridge) 2019-10, Vol.1 (38), p.8889-8894 |
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| creator | Khayum M, Abdul Ghosh, Meena Vijayakumar, Vidyanand Halder, Arjun Nurhuda, Maryam Kumar, Sushil Addicoat, Matthew Kurungot, Sreekumar Banerjee, Rahul |
| description | The two-dimensional structural features of covalent organic frameworks (COFs) can promote the electrochemical storage of cations like H
+
, Li
+
, and Na
+
through both faradaic and non-faradaic processes. However, the electrochemical storage of cations like Zn
2+
ion is still unexplored although it bears a promising divalent charge. Herein, for the first time, we have utilized hydroquinone linked β-ketoenamine COF acting as a Zn
2+
anchor in an aqueous rechargeable zinc ion battery. The charge-storage mechanism comprises of an efficient reversible interlayer interaction of Zn
2+
ions with the functional moieties in the adjacent layers of COF (−182.0 kcal mol
−1
). Notably, due to the well-defined nanopores and structural organization, a constructed full cell, displays a discharge capacity as high as 276 mA h g
−1
at a current rate of 125 mA g
−1
.
We have demonstrated a hydroquinone stitched β-ketoenamine COF acting as an efficient organic cathode in an aqueous rechargeable zinc ion battery. |
| doi_str_mv | 10.1039/c9sc03052b |
| format | Article |
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+
, Li
+
, and Na
+
through both faradaic and non-faradaic processes. However, the electrochemical storage of cations like Zn
2+
ion is still unexplored although it bears a promising divalent charge. Herein, for the first time, we have utilized hydroquinone linked β-ketoenamine COF acting as a Zn
2+
anchor in an aqueous rechargeable zinc ion battery. The charge-storage mechanism comprises of an efficient reversible interlayer interaction of Zn
2+
ions with the functional moieties in the adjacent layers of COF (−182.0 kcal mol
−1
). Notably, due to the well-defined nanopores and structural organization, a constructed full cell, displays a discharge capacity as high as 276 mA h g
−1
at a current rate of 125 mA g
−1
.
We have demonstrated a hydroquinone stitched β-ketoenamine COF acting as an efficient organic cathode in an aqueous rechargeable zinc ion battery.</description><identifier>ISSN: 2041-6520</identifier><identifier>EISSN: 2041-6539</identifier><identifier>DOI: 10.1039/c9sc03052b</identifier><identifier>PMID: 31762974</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Anchors ; Cations ; Cosmetics industry ; Hydroquinone ; Interlayers ; Porosity ; Rechargeable batteries ; Zinc</subject><ispartof>Chemical science (Cambridge), 2019-10, Vol.1 (38), p.8889-8894</ispartof><rights>This journal is © The Royal Society of Chemistry 2019.</rights><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c373t-aede49b7591ef97d478cbc0aea58e91aad322cdf11bec21e8b0fc594d7ae3e2a3</citedby><cites>FETCH-LOGICAL-c373t-aede49b7591ef97d478cbc0aea58e91aad322cdf11bec21e8b0fc594d7ae3e2a3</cites><orcidid>0000-0003-0400-6592 ; 0000-0002-5406-7927 ; 0000-0002-3547-4746 ; 0000-0001-5446-7923 ; 0000-0001-6061-5902 ; 0000-0001-9068-719X ; 0000-0001-8626-1751</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,864,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31762974$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Khayum M, Abdul</creatorcontrib><creatorcontrib>Ghosh, Meena</creatorcontrib><creatorcontrib>Vijayakumar, Vidyanand</creatorcontrib><creatorcontrib>Halder, Arjun</creatorcontrib><creatorcontrib>Nurhuda, Maryam</creatorcontrib><creatorcontrib>Kumar, Sushil</creatorcontrib><creatorcontrib>Addicoat, Matthew</creatorcontrib><creatorcontrib>Kurungot, Sreekumar</creatorcontrib><creatorcontrib>Banerjee, Rahul</creatorcontrib><title>Zinc ion interactions in a two-dimensional covalent organic framework based aqueous zinc ion battery</title><title>Chemical science (Cambridge)</title><addtitle>Chem Sci</addtitle><description>The two-dimensional structural features of covalent organic frameworks (COFs) can promote the electrochemical storage of cations like H
+
, Li
+
, and Na
+
through both faradaic and non-faradaic processes. However, the electrochemical storage of cations like Zn
2+
ion is still unexplored although it bears a promising divalent charge. Herein, for the first time, we have utilized hydroquinone linked β-ketoenamine COF acting as a Zn
2+
anchor in an aqueous rechargeable zinc ion battery. The charge-storage mechanism comprises of an efficient reversible interlayer interaction of Zn
2+
ions with the functional moieties in the adjacent layers of COF (−182.0 kcal mol
−1
). Notably, due to the well-defined nanopores and structural organization, a constructed full cell, displays a discharge capacity as high as 276 mA h g
−1
at a current rate of 125 mA g
−1
.
We have demonstrated a hydroquinone stitched β-ketoenamine COF acting as an efficient organic cathode in an aqueous rechargeable zinc ion battery.</description><subject>Anchors</subject><subject>Cations</subject><subject>Cosmetics industry</subject><subject>Hydroquinone</subject><subject>Interlayers</subject><subject>Porosity</subject><subject>Rechargeable batteries</subject><subject>Zinc</subject><issn>2041-6520</issn><issn>2041-6539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpdkctLxDAQxoMo7qJevCsBLyJU82g3zVEXX7DgQb14KdNkKl3bZk26LvrXG92H4FxmkvnxMfMNIYecnXMm9YXRwTDJMlFukaFgKU9GmdTbm1qwATkIYcpiSMkzoXbJQHI1ElqlQ2Jf6s7Q2nW07nr0YPpYh_igQPuFS2zdYhfiHzTUuA9osOup86_Q1YZWHlpcOP9GSwhoKbzP0c0D_VprltBH0c99slNBE_BglffI88310_gumTzc3o8vJ4mRSvYJoMVUlyrTHCutbKpyUxoGCFmOmgNYKYSxFeclGsExL1llMp1aBShRgNwjp0vdmXdxlNAXbR0MNg10P3MVIu6tRyMt8oie_EOnbu7jlpESWishcp5F6mxJGe9C8FgVM1-34D8Lzoof-4uxfhz_2n8V4eOV5Lxs0W7QtdkROFoCPphN9-9-8hv0jItO</recordid><startdate>20191014</startdate><enddate>20191014</enddate><creator>Khayum M, Abdul</creator><creator>Ghosh, Meena</creator><creator>Vijayakumar, Vidyanand</creator><creator>Halder, Arjun</creator><creator>Nurhuda, Maryam</creator><creator>Kumar, Sushil</creator><creator>Addicoat, Matthew</creator><creator>Kurungot, Sreekumar</creator><creator>Banerjee, Rahul</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-0400-6592</orcidid><orcidid>https://orcid.org/0000-0002-5406-7927</orcidid><orcidid>https://orcid.org/0000-0002-3547-4746</orcidid><orcidid>https://orcid.org/0000-0001-5446-7923</orcidid><orcidid>https://orcid.org/0000-0001-6061-5902</orcidid><orcidid>https://orcid.org/0000-0001-9068-719X</orcidid><orcidid>https://orcid.org/0000-0001-8626-1751</orcidid></search><sort><creationdate>20191014</creationdate><title>Zinc ion interactions in a two-dimensional covalent organic framework based aqueous zinc ion battery</title><author>Khayum M, Abdul ; Ghosh, Meena ; Vijayakumar, Vidyanand ; Halder, Arjun ; Nurhuda, Maryam ; Kumar, Sushil ; Addicoat, Matthew ; Kurungot, Sreekumar ; Banerjee, Rahul</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c373t-aede49b7591ef97d478cbc0aea58e91aad322cdf11bec21e8b0fc594d7ae3e2a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Anchors</topic><topic>Cations</topic><topic>Cosmetics industry</topic><topic>Hydroquinone</topic><topic>Interlayers</topic><topic>Porosity</topic><topic>Rechargeable batteries</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Khayum M, Abdul</creatorcontrib><creatorcontrib>Ghosh, Meena</creatorcontrib><creatorcontrib>Vijayakumar, Vidyanand</creatorcontrib><creatorcontrib>Halder, Arjun</creatorcontrib><creatorcontrib>Nurhuda, Maryam</creatorcontrib><creatorcontrib>Kumar, Sushil</creatorcontrib><creatorcontrib>Addicoat, Matthew</creatorcontrib><creatorcontrib>Kurungot, Sreekumar</creatorcontrib><creatorcontrib>Banerjee, Rahul</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical science (Cambridge)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Khayum M, Abdul</au><au>Ghosh, Meena</au><au>Vijayakumar, Vidyanand</au><au>Halder, Arjun</au><au>Nurhuda, Maryam</au><au>Kumar, Sushil</au><au>Addicoat, Matthew</au><au>Kurungot, Sreekumar</au><au>Banerjee, Rahul</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Zinc ion interactions in a two-dimensional covalent organic framework based aqueous zinc ion battery</atitle><jtitle>Chemical science (Cambridge)</jtitle><addtitle>Chem Sci</addtitle><date>2019-10-14</date><risdate>2019</risdate><volume>1</volume><issue>38</issue><spage>8889</spage><epage>8894</epage><pages>8889-8894</pages><issn>2041-6520</issn><eissn>2041-6539</eissn><abstract>The two-dimensional structural features of covalent organic frameworks (COFs) can promote the electrochemical storage of cations like H
+
, Li
+
, and Na
+
through both faradaic and non-faradaic processes. However, the electrochemical storage of cations like Zn
2+
ion is still unexplored although it bears a promising divalent charge. Herein, for the first time, we have utilized hydroquinone linked β-ketoenamine COF acting as a Zn
2+
anchor in an aqueous rechargeable zinc ion battery. The charge-storage mechanism comprises of an efficient reversible interlayer interaction of Zn
2+
ions with the functional moieties in the adjacent layers of COF (−182.0 kcal mol
−1
). Notably, due to the well-defined nanopores and structural organization, a constructed full cell, displays a discharge capacity as high as 276 mA h g
−1
at a current rate of 125 mA g
−1
.
We have demonstrated a hydroquinone stitched β-ketoenamine COF acting as an efficient organic cathode in an aqueous rechargeable zinc ion battery.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>31762974</pmid><doi>10.1039/c9sc03052b</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-0400-6592</orcidid><orcidid>https://orcid.org/0000-0002-5406-7927</orcidid><orcidid>https://orcid.org/0000-0002-3547-4746</orcidid><orcidid>https://orcid.org/0000-0001-5446-7923</orcidid><orcidid>https://orcid.org/0000-0001-6061-5902</orcidid><orcidid>https://orcid.org/0000-0001-9068-719X</orcidid><orcidid>https://orcid.org/0000-0001-8626-1751</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
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| language | eng |
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| source | DOAJ Directory of Open Access Journals; PubMed Central Open Access; EZB-FREE-00999 freely available EZB journals; PubMed Central |
| subjects | Anchors Cations Cosmetics industry Hydroquinone Interlayers Porosity Rechargeable batteries Zinc |
| title | Zinc ion interactions in a two-dimensional covalent organic framework based aqueous zinc ion battery |
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