Oxidative Olefination of Benzylamine with an Active Methylene Compound Mediated by Hypervalent Iodine (III)
Hypervalent iodine‐mediated oxidative olefination of amines with an active methylene compound provides a rapid gateway towards the formation of electrophilic alkenes under mild reaction conditions in good to excellent yields. This is an efficient protocol for the preparation of substituted electroph...
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| Veröffentlicht in: | European journal of organic chemistry 2019-09, Vol.2019 (36), p.6232-6239 |
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| container_end_page | 6239 |
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| container_issue | 36 |
| container_start_page | 6232 |
| container_title | European journal of organic chemistry |
| container_volume | 2019 |
| creator | Rupanawar, Bapurao D. Veetil, Sruthi M. Suryavanshi, Gurunath |
| description | Hypervalent iodine‐mediated oxidative olefination of amines with an active methylene compound provides a rapid gateway towards the formation of electrophilic alkenes under mild reaction conditions in good to excellent yields. This is an efficient protocol for the preparation of substituted electrophilic alkenes.
Hypervalent iodine mediates the oxidative olefination of amines with active methylene compounds for the formation of electrophilic alkenes under mild reaction conditions in good to excellent yields. |
| doi_str_mv | 10.1002/ejoc.201900970 |
| format | Article |
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Hypervalent iodine mediates the oxidative olefination of amines with active methylene compounds for the formation of electrophilic alkenes under mild reaction conditions in good to excellent yields.</description><subject>Alkenes</subject><subject>Amines</subject><subject>Hypervalent iodine</subject><subject>Iodine</subject><subject>Methylene</subject><subject>Oxidative olefination</subject><subject>Synthetic methods</subject><issn>1434-193X</issn><issn>1099-0690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkDFPwzAQhS0EEqWwMltigSHlnDhxPZaq0KCiLCCxRY59UVPSOCRpS_j1uBTByHJ3uvveO-kRcslgxAD8W1xZPfKBSQAp4IgMGEjpQSTh2M084B6TwespOWvbFTgmitiAvCUfhVFdsUWalJgXlZttRW1O77D67Eu1Liqku6JbUlXRif4mn7Bb9iW6w9Sua7upjFuZQnVoaNbTeV9js1UO6Ghszd7gOo7jm3NykquyxYufPiQv97Pn6dxbJA_xdLLwdMAEeKEYM8Z9o1WojZBhJJTAHIQEbjiLjMxyHUjOITO-CTRjEkMeZRjKsc59HAdDcnXwrRv7vsG2S1d201TuZer7UoJwhTtqdKB0Y9u2wTytm2Ktmj5lkO4DTfeBpr-BOoE8CHZFif0_dDp7TKZ_2i-I8Hob</recordid><startdate>20190930</startdate><enddate>20190930</enddate><creator>Rupanawar, Bapurao D.</creator><creator>Veetil, Sruthi M.</creator><creator>Suryavanshi, Gurunath</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-6299-0914</orcidid></search><sort><creationdate>20190930</creationdate><title>Oxidative Olefination of Benzylamine with an Active Methylene Compound Mediated by Hypervalent Iodine (III)</title><author>Rupanawar, Bapurao D. ; Veetil, Sruthi M. ; Suryavanshi, Gurunath</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3170-5781142dca5cd79567a7ef07904d416d9bfc39440bd2d3c119e546be598cf2e83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Alkenes</topic><topic>Amines</topic><topic>Hypervalent iodine</topic><topic>Iodine</topic><topic>Methylene</topic><topic>Oxidative olefination</topic><topic>Synthetic methods</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rupanawar, Bapurao D.</creatorcontrib><creatorcontrib>Veetil, Sruthi M.</creatorcontrib><creatorcontrib>Suryavanshi, Gurunath</creatorcontrib><collection>CrossRef</collection><jtitle>European journal of organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rupanawar, Bapurao D.</au><au>Veetil, Sruthi M.</au><au>Suryavanshi, Gurunath</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Oxidative Olefination of Benzylamine with an Active Methylene Compound Mediated by Hypervalent Iodine (III)</atitle><jtitle>European journal of organic chemistry</jtitle><date>2019-09-30</date><risdate>2019</risdate><volume>2019</volume><issue>36</issue><spage>6232</spage><epage>6239</epage><pages>6232-6239</pages><issn>1434-193X</issn><eissn>1099-0690</eissn><abstract>Hypervalent iodine‐mediated oxidative olefination of amines with an active methylene compound provides a rapid gateway towards the formation of electrophilic alkenes under mild reaction conditions in good to excellent yields. This is an efficient protocol for the preparation of substituted electrophilic alkenes.
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| issn | 1434-193X 1099-0690 |
| language | eng |
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| source | Wiley Online Library All Journals |
| subjects | Alkenes Amines Hypervalent iodine Iodine Methylene Oxidative olefination Synthetic methods |
| title | Oxidative Olefination of Benzylamine with an Active Methylene Compound Mediated by Hypervalent Iodine (III) |
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