Tight Xenon Confinement in a Crystalline Sandwich‐like Hydrogen‐Bonded Dimeric Capsule of a Cyclic Peptide
A cyclic hexapeptide with three pyridyl moieties connected to its backbone forms a hydrogen‐bonded dimer, which tightly encapsulates a single xenon atom, like a pearl in its shell. The dimer imprints its shape and symmetry to the captured xenon atom, as demonstrated by 129Xe NMR spectroscopy, single...
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| Veröffentlicht in: | Angewandte Chemie 2019-10, Vol.131 (41), p.14614-14618 |
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| creator | Pizzi, Andrea Ozores, Haxel Lionel Calvelo, Martín García‐Fandiño, Rebeca Amorín, Manuel Demitri, Nicola Terraneo, Giancarlo Bracco, Silvia Comotti, Angiolina Sozzani, Piero Bezuidenhout, Charl X. Metrangolo, Pierangelo Granja, Juan R. |
| description | A cyclic hexapeptide with three pyridyl moieties connected to its backbone forms a hydrogen‐bonded dimer, which tightly encapsulates a single xenon atom, like a pearl in its shell. The dimer imprints its shape and symmetry to the captured xenon atom, as demonstrated by 129Xe NMR spectroscopy, single‐crystal X‐ray diffraction, and computational studies. The dimers self‐assemble hierarchically into tubular structures to form a porous supramolecular architecture, whose cavities are filled by small molecules and gases.
Eng eingeschlossen: Ein cyclisches Hexapeptid mit drei Pyridylgruppen an der Hauptkette bildet ein wasserstoffbrückengebundenes Dimer, das ein einzelnes Xenon‐Atom eng einkapselt. Die Dimere ordnen sich hierarchisch zu röhrenartigen Strukturen in einer porösen supramolekularen Architektur an, deren Hohlräume durch kleine Moleküle und Gase ausgefüllt werden können. |
| doi_str_mv | 10.1002/ange.201906599 |
| format | Article |
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Eng eingeschlossen: Ein cyclisches Hexapeptid mit drei Pyridylgruppen an der Hauptkette bildet ein wasserstoffbrückengebundenes Dimer, das ein einzelnes Xenon‐Atom eng einkapselt. Die Dimere ordnen sich hierarchisch zu röhrenartigen Strukturen in einer porösen supramolekularen Architektur an, deren Hohlräume durch kleine Moleküle und Gase ausgefüllt werden können.</description><identifier>ISSN: 0044-8249</identifier><identifier>EISSN: 1521-3757</identifier><identifier>DOI: 10.1002/ange.201906599</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Bonding strength ; Chemistry ; Computer applications ; Cyclische Peptide ; Dimers ; Gaseinschluss ; Gases ; Magnetic resonance spectroscopy ; NMR ; NMR spectroscopy ; Nuclear magnetic resonance ; Selbstassemblierung ; Wirt-Gast-Systeme ; Xenon ; Xenon 129</subject><ispartof>Angewandte Chemie, 2019-10, Vol.131 (41), p.14614-14618</ispartof><rights>2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2029-d100c6989c27991a89320dfaf14f1f699c26399f227cfcec1be015f81066b2723</citedby><cites>FETCH-LOGICAL-c2029-d100c6989c27991a89320dfaf14f1f699c26399f227cfcec1be015f81066b2723</cites><orcidid>0000-0002-2992-5555 ; 0000-0002-8396-8951 ; 0000-0002-4180-9151 ; 0000-0001-7114-1781 ; 0000-0002-1225-2577 ; 0000-0002-2575-6424 ; 0000-0001-6776-5073 ; 0000-0003-0288-3233 ; 0000-0002-5842-7504 ; 0000-0002-5274-3928 ; 0000-0002-9956-6279 ; 0000-0002-7945-099X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fange.201906599$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fange.201906599$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids></links><search><creatorcontrib>Pizzi, Andrea</creatorcontrib><creatorcontrib>Ozores, Haxel Lionel</creatorcontrib><creatorcontrib>Calvelo, Martín</creatorcontrib><creatorcontrib>García‐Fandiño, Rebeca</creatorcontrib><creatorcontrib>Amorín, Manuel</creatorcontrib><creatorcontrib>Demitri, Nicola</creatorcontrib><creatorcontrib>Terraneo, Giancarlo</creatorcontrib><creatorcontrib>Bracco, Silvia</creatorcontrib><creatorcontrib>Comotti, Angiolina</creatorcontrib><creatorcontrib>Sozzani, Piero</creatorcontrib><creatorcontrib>Bezuidenhout, Charl X.</creatorcontrib><creatorcontrib>Metrangolo, Pierangelo</creatorcontrib><creatorcontrib>Granja, Juan R.</creatorcontrib><title>Tight Xenon Confinement in a Crystalline Sandwich‐like Hydrogen‐Bonded Dimeric Capsule of a Cyclic Peptide</title><title>Angewandte Chemie</title><description>A cyclic hexapeptide with three pyridyl moieties connected to its backbone forms a hydrogen‐bonded dimer, which tightly encapsulates a single xenon atom, like a pearl in its shell. The dimer imprints its shape and symmetry to the captured xenon atom, as demonstrated by 129Xe NMR spectroscopy, single‐crystal X‐ray diffraction, and computational studies. The dimers self‐assemble hierarchically into tubular structures to form a porous supramolecular architecture, whose cavities are filled by small molecules and gases.
Eng eingeschlossen: Ein cyclisches Hexapeptid mit drei Pyridylgruppen an der Hauptkette bildet ein wasserstoffbrückengebundenes Dimer, das ein einzelnes Xenon‐Atom eng einkapselt. Die Dimere ordnen sich hierarchisch zu röhrenartigen Strukturen in einer porösen supramolekularen Architektur an, deren Hohlräume durch kleine Moleküle und Gase ausgefüllt werden können.</description><subject>Bonding strength</subject><subject>Chemistry</subject><subject>Computer applications</subject><subject>Cyclische Peptide</subject><subject>Dimers</subject><subject>Gaseinschluss</subject><subject>Gases</subject><subject>Magnetic resonance spectroscopy</subject><subject>NMR</subject><subject>NMR spectroscopy</subject><subject>Nuclear magnetic resonance</subject><subject>Selbstassemblierung</subject><subject>Wirt-Gast-Systeme</subject><subject>Xenon</subject><subject>Xenon 129</subject><issn>0044-8249</issn><issn>1521-3757</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFUE1LAzEUDKJgrV49BzxvTbKfOda1tkJRwQreQpp9aVO3Sc1uKXvzJ_gb_SWmVPTo6fGGmXnzBqFLSgaUEHYt7QIGjFBOspTzI9SjKaNRnKf5MeoRkiRRwRJ-is6aZkUIyVjOe8jOzGLZ4lewzuLSWW0srMG22Fgscem7ppV1HUD8LG21M2r59fFZmzfAk67ybgE27DfOVlDhW7MGbxQu5abZ1oCd3lt0qg7YE2xaU8E5OtGybuDiZ_bRy91oVk6i6eP4vhxOI8UI41EVHlIZL7gKITmVBY8ZqbTUNNFUZzzgWcy5ZixXWoGicyA01QUlWTZnOYv76Orgu_HufQtNK1Zu6204KRjjeZEUBckDa3BgKe-axoMWG2_W0neCErHvVOw7Fb-dBgE_CHamhu4fthg-jEd_2m8BAHzA</recordid><startdate>20191007</startdate><enddate>20191007</enddate><creator>Pizzi, Andrea</creator><creator>Ozores, Haxel Lionel</creator><creator>Calvelo, Martín</creator><creator>García‐Fandiño, Rebeca</creator><creator>Amorín, Manuel</creator><creator>Demitri, Nicola</creator><creator>Terraneo, Giancarlo</creator><creator>Bracco, Silvia</creator><creator>Comotti, Angiolina</creator><creator>Sozzani, Piero</creator><creator>Bezuidenhout, Charl X.</creator><creator>Metrangolo, Pierangelo</creator><creator>Granja, Juan R.</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-2992-5555</orcidid><orcidid>https://orcid.org/0000-0002-8396-8951</orcidid><orcidid>https://orcid.org/0000-0002-4180-9151</orcidid><orcidid>https://orcid.org/0000-0001-7114-1781</orcidid><orcidid>https://orcid.org/0000-0002-1225-2577</orcidid><orcidid>https://orcid.org/0000-0002-2575-6424</orcidid><orcidid>https://orcid.org/0000-0001-6776-5073</orcidid><orcidid>https://orcid.org/0000-0003-0288-3233</orcidid><orcidid>https://orcid.org/0000-0002-5842-7504</orcidid><orcidid>https://orcid.org/0000-0002-5274-3928</orcidid><orcidid>https://orcid.org/0000-0002-9956-6279</orcidid><orcidid>https://orcid.org/0000-0002-7945-099X</orcidid></search><sort><creationdate>20191007</creationdate><title>Tight Xenon Confinement in a Crystalline Sandwich‐like Hydrogen‐Bonded Dimeric Capsule of a Cyclic Peptide</title><author>Pizzi, Andrea ; Ozores, Haxel Lionel ; Calvelo, Martín ; García‐Fandiño, Rebeca ; Amorín, Manuel ; Demitri, Nicola ; Terraneo, Giancarlo ; Bracco, Silvia ; Comotti, Angiolina ; Sozzani, Piero ; Bezuidenhout, Charl X. ; Metrangolo, Pierangelo ; Granja, Juan R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2029-d100c6989c27991a89320dfaf14f1f699c26399f227cfcec1be015f81066b2723</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Bonding strength</topic><topic>Chemistry</topic><topic>Computer applications</topic><topic>Cyclische Peptide</topic><topic>Dimers</topic><topic>Gaseinschluss</topic><topic>Gases</topic><topic>Magnetic resonance spectroscopy</topic><topic>NMR</topic><topic>NMR spectroscopy</topic><topic>Nuclear magnetic resonance</topic><topic>Selbstassemblierung</topic><topic>Wirt-Gast-Systeme</topic><topic>Xenon</topic><topic>Xenon 129</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pizzi, Andrea</creatorcontrib><creatorcontrib>Ozores, Haxel Lionel</creatorcontrib><creatorcontrib>Calvelo, Martín</creatorcontrib><creatorcontrib>García‐Fandiño, Rebeca</creatorcontrib><creatorcontrib>Amorín, Manuel</creatorcontrib><creatorcontrib>Demitri, Nicola</creatorcontrib><creatorcontrib>Terraneo, Giancarlo</creatorcontrib><creatorcontrib>Bracco, Silvia</creatorcontrib><creatorcontrib>Comotti, Angiolina</creatorcontrib><creatorcontrib>Sozzani, Piero</creatorcontrib><creatorcontrib>Bezuidenhout, Charl X.</creatorcontrib><creatorcontrib>Metrangolo, Pierangelo</creatorcontrib><creatorcontrib>Granja, Juan R.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Angewandte Chemie</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pizzi, Andrea</au><au>Ozores, Haxel Lionel</au><au>Calvelo, Martín</au><au>García‐Fandiño, Rebeca</au><au>Amorín, Manuel</au><au>Demitri, Nicola</au><au>Terraneo, Giancarlo</au><au>Bracco, Silvia</au><au>Comotti, Angiolina</au><au>Sozzani, Piero</au><au>Bezuidenhout, Charl X.</au><au>Metrangolo, Pierangelo</au><au>Granja, Juan R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tight Xenon Confinement in a Crystalline Sandwich‐like Hydrogen‐Bonded Dimeric Capsule of a Cyclic Peptide</atitle><jtitle>Angewandte Chemie</jtitle><date>2019-10-07</date><risdate>2019</risdate><volume>131</volume><issue>41</issue><spage>14614</spage><epage>14618</epage><pages>14614-14618</pages><issn>0044-8249</issn><eissn>1521-3757</eissn><abstract>A cyclic hexapeptide with three pyridyl moieties connected to its backbone forms a hydrogen‐bonded dimer, which tightly encapsulates a single xenon atom, like a pearl in its shell. 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Eng eingeschlossen: Ein cyclisches Hexapeptid mit drei Pyridylgruppen an der Hauptkette bildet ein wasserstoffbrückengebundenes Dimer, das ein einzelnes Xenon‐Atom eng einkapselt. Die Dimere ordnen sich hierarchisch zu röhrenartigen Strukturen in einer porösen supramolekularen Architektur an, deren Hohlräume durch kleine Moleküle und Gase ausgefüllt werden können.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/ange.201906599</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-2992-5555</orcidid><orcidid>https://orcid.org/0000-0002-8396-8951</orcidid><orcidid>https://orcid.org/0000-0002-4180-9151</orcidid><orcidid>https://orcid.org/0000-0001-7114-1781</orcidid><orcidid>https://orcid.org/0000-0002-1225-2577</orcidid><orcidid>https://orcid.org/0000-0002-2575-6424</orcidid><orcidid>https://orcid.org/0000-0001-6776-5073</orcidid><orcidid>https://orcid.org/0000-0003-0288-3233</orcidid><orcidid>https://orcid.org/0000-0002-5842-7504</orcidid><orcidid>https://orcid.org/0000-0002-5274-3928</orcidid><orcidid>https://orcid.org/0000-0002-9956-6279</orcidid><orcidid>https://orcid.org/0000-0002-7945-099X</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Bonding strength Chemistry Computer applications Cyclische Peptide Dimers Gaseinschluss Gases Magnetic resonance spectroscopy NMR NMR spectroscopy Nuclear magnetic resonance Selbstassemblierung Wirt-Gast-Systeme Xenon Xenon 129 |
| title | Tight Xenon Confinement in a Crystalline Sandwich‐like Hydrogen‐Bonded Dimeric Capsule of a Cyclic Peptide |
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