Choline chloride-lactic acid deep eutectic solvent for delignification and nanocellulose production of moso bamboo
A facile, green and economical method for the high-efficiency utilization and functionalization of bamboo fiber could significantly improve the development of biomass industries. Here, we demonstrated a deep eutectic solvent, which formed from choline chloride (ChCl) and lactic acid (LC), as pretrea...
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| Veröffentlicht in: | Cellulose (London) 2019-12, Vol.26 (18), p.9447-9462 |
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| creator | Liu, Qian Yuan, Tao Fu, Qin-jin Bai, Yuan-yuan Peng, Feng Yao, Chun-li |
| description | A facile, green and economical method for the high-efficiency utilization and functionalization of bamboo fiber could significantly improve the development of biomass industries. Here, we demonstrated a deep eutectic solvent, which formed from choline chloride (ChCl) and lactic acid (LC), as pretreating agent to delignify moso bamboo (
Phyllostachys pubescens
) and produce nanocellulose. The results showed that most of the lignin was efficiently removed (94.39%) and 91% of the cellulose was recovered after the moso bamboo was pretreated with ChCl–LC at 120 °C for 3 h with a solid-to-liquid ratio of 1:25. Furthermore, nanofibers with widths of 20–80 nm were successfully prepared from pretreated fibers after a simple mechanical process. SEM and AFM images showed that they have excellent aspect ratio. In addition, the obtained nanofibers could be used to fabricate strong films which feature a high tensile strength ranged from 163 to 213 MPa. |
| doi_str_mv | 10.1007/s10570-019-02726-0 |
| format | Article |
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Phyllostachys pubescens
) and produce nanocellulose. The results showed that most of the lignin was efficiently removed (94.39%) and 91% of the cellulose was recovered after the moso bamboo was pretreated with ChCl–LC at 120 °C for 3 h with a solid-to-liquid ratio of 1:25. Furthermore, nanofibers with widths of 20–80 nm were successfully prepared from pretreated fibers after a simple mechanical process. SEM and AFM images showed that they have excellent aspect ratio. In addition, the obtained nanofibers could be used to fabricate strong films which feature a high tensile strength ranged from 163 to 213 MPa.</description><identifier>ISSN: 0969-0239</identifier><identifier>EISSN: 1572-882X</identifier><identifier>DOI: 10.1007/s10570-019-02726-0</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Aspect ratio ; Bamboo ; Bioorganic Chemistry ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Chlorides ; Choline ; Composites ; Economic conditions ; Glass ; Lactic acid ; Nanofibers ; Natural Materials ; Organic Chemistry ; Original Research ; Physical Chemistry ; Polymer Sciences ; Solvents ; Sustainable Development</subject><ispartof>Cellulose (London), 2019-12, Vol.26 (18), p.9447-9462</ispartof><rights>Springer Nature B.V. 2019</rights><rights>Cellulose is a copyright of Springer, (2019). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c422t-a0ff445b0423ea93911e1dc8084e3a917f5f94c7f91d4d0d1bd41b486e9d0e893</citedby><cites>FETCH-LOGICAL-c422t-a0ff445b0423ea93911e1dc8084e3a917f5f94c7f91d4d0d1bd41b486e9d0e893</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10570-019-02726-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10570-019-02726-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Liu, Qian</creatorcontrib><creatorcontrib>Yuan, Tao</creatorcontrib><creatorcontrib>Fu, Qin-jin</creatorcontrib><creatorcontrib>Bai, Yuan-yuan</creatorcontrib><creatorcontrib>Peng, Feng</creatorcontrib><creatorcontrib>Yao, Chun-li</creatorcontrib><title>Choline chloride-lactic acid deep eutectic solvent for delignification and nanocellulose production of moso bamboo</title><title>Cellulose (London)</title><addtitle>Cellulose</addtitle><description>A facile, green and economical method for the high-efficiency utilization and functionalization of bamboo fiber could significantly improve the development of biomass industries. Here, we demonstrated a deep eutectic solvent, which formed from choline chloride (ChCl) and lactic acid (LC), as pretreating agent to delignify moso bamboo (
Phyllostachys pubescens
) and produce nanocellulose. The results showed that most of the lignin was efficiently removed (94.39%) and 91% of the cellulose was recovered after the moso bamboo was pretreated with ChCl–LC at 120 °C for 3 h with a solid-to-liquid ratio of 1:25. Furthermore, nanofibers with widths of 20–80 nm were successfully prepared from pretreated fibers after a simple mechanical process. SEM and AFM images showed that they have excellent aspect ratio. In addition, the obtained nanofibers could be used to fabricate strong films which feature a high tensile strength ranged from 163 to 213 MPa.</description><subject>Aspect ratio</subject><subject>Bamboo</subject><subject>Bioorganic Chemistry</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chlorides</subject><subject>Choline</subject><subject>Composites</subject><subject>Economic conditions</subject><subject>Glass</subject><subject>Lactic acid</subject><subject>Nanofibers</subject><subject>Natural Materials</subject><subject>Organic Chemistry</subject><subject>Original Research</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Solvents</subject><subject>Sustainable Development</subject><issn>0969-0239</issn><issn>1572-882X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kE1LAzEQhoMoWKt_wFPA8-okm3Y3Ryl-QcGLgreQTSZtSprUZFfw37ttBW-eBub9mOEh5JrBLQNo7gqDWQMVMFkBb_i8ghMyYbOGV23LP07JBOR8L9XynFyUsgEA2XA2IXmxTsFHpGYdUvYWq6BN7w3VxltqEXcUhx4Pq5LCF8aeupRHJfhV9M4b3fsUqY6WRh2TwRCGkArSXU52MAcxObpNJdFOb7uULsmZ06Hg1e-ckvfHh7fFc7V8fXpZ3C8rIzjvKw3OCTHrQPAatawlY8isaaEVWGvJGjdzUpjGSWaFBcs6K1gn2jlKC9jKekpujr3jJ58Dll5t0pDjeFJxPuKQXMzb0cWPLpNTKRmd2mW_1flbMVB7turIVo1s1YGtgjFUH0NlNMcV5r_qf1I_7AB-fg</recordid><startdate>20191201</startdate><enddate>20191201</enddate><creator>Liu, Qian</creator><creator>Yuan, Tao</creator><creator>Fu, Qin-jin</creator><creator>Bai, Yuan-yuan</creator><creator>Peng, Feng</creator><creator>Yao, Chun-li</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20191201</creationdate><title>Choline chloride-lactic acid deep eutectic solvent for delignification and nanocellulose production of moso bamboo</title><author>Liu, Qian ; Yuan, Tao ; Fu, Qin-jin ; Bai, Yuan-yuan ; Peng, Feng ; Yao, Chun-li</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c422t-a0ff445b0423ea93911e1dc8084e3a917f5f94c7f91d4d0d1bd41b486e9d0e893</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Aspect ratio</topic><topic>Bamboo</topic><topic>Bioorganic Chemistry</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chlorides</topic><topic>Choline</topic><topic>Composites</topic><topic>Economic conditions</topic><topic>Glass</topic><topic>Lactic acid</topic><topic>Nanofibers</topic><topic>Natural Materials</topic><topic>Organic Chemistry</topic><topic>Original Research</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Solvents</topic><topic>Sustainable Development</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Qian</creatorcontrib><creatorcontrib>Yuan, Tao</creatorcontrib><creatorcontrib>Fu, Qin-jin</creatorcontrib><creatorcontrib>Bai, Yuan-yuan</creatorcontrib><creatorcontrib>Peng, Feng</creatorcontrib><creatorcontrib>Yao, Chun-li</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Cellulose (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Qian</au><au>Yuan, Tao</au><au>Fu, Qin-jin</au><au>Bai, Yuan-yuan</au><au>Peng, Feng</au><au>Yao, Chun-li</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Choline chloride-lactic acid deep eutectic solvent for delignification and nanocellulose production of moso bamboo</atitle><jtitle>Cellulose (London)</jtitle><stitle>Cellulose</stitle><date>2019-12-01</date><risdate>2019</risdate><volume>26</volume><issue>18</issue><spage>9447</spage><epage>9462</epage><pages>9447-9462</pages><issn>0969-0239</issn><eissn>1572-882X</eissn><abstract>A facile, green and economical method for the high-efficiency utilization and functionalization of bamboo fiber could significantly improve the development of biomass industries. Here, we demonstrated a deep eutectic solvent, which formed from choline chloride (ChCl) and lactic acid (LC), as pretreating agent to delignify moso bamboo (
Phyllostachys pubescens
) and produce nanocellulose. The results showed that most of the lignin was efficiently removed (94.39%) and 91% of the cellulose was recovered after the moso bamboo was pretreated with ChCl–LC at 120 °C for 3 h with a solid-to-liquid ratio of 1:25. Furthermore, nanofibers with widths of 20–80 nm were successfully prepared from pretreated fibers after a simple mechanical process. SEM and AFM images showed that they have excellent aspect ratio. In addition, the obtained nanofibers could be used to fabricate strong films which feature a high tensile strength ranged from 163 to 213 MPa.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10570-019-02726-0</doi><tpages>16</tpages></addata></record> |
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| subjects | Aspect ratio Bamboo Bioorganic Chemistry Ceramics Chemistry Chemistry and Materials Science Chlorides Choline Composites Economic conditions Glass Lactic acid Nanofibers Natural Materials Organic Chemistry Original Research Physical Chemistry Polymer Sciences Solvents Sustainable Development |
| title | Choline chloride-lactic acid deep eutectic solvent for delignification and nanocellulose production of moso bamboo |
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