Anode dissolution of ternary Pb–Sb–Bi alloys and reduction of lead in the KCl–PbC2 melt
The influence of bismuth, antimony and lead concentrations on the Pb–Sb–Bi alloys anode dissolution in the KCl–PbCl 2 equimolar melt was studied. The lead dissolution process, which starts at the potentials close to the equilibrium ones, was found to be the basic process up to the certain potentials...
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| Veröffentlicht in: | Journal of the Iranian Chemical Society 2019-11, Vol.16 (11), p.2501-2507 |
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| container_title | Journal of the Iranian Chemical Society |
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| creator | Arkhipov, P. A. Kholkina, A. S. Zaykov, Yu. P. Arkhipov, S. P. |
| description | The influence of bismuth, antimony and lead concentrations on the Pb–Sb–Bi alloys anode dissolution in the KCl–PbCl
2
equimolar melt was studied. The lead dissolution process, which starts at the potentials close to the equilibrium ones, was found to be the basic process up to the certain potentials. A number of electrons, which take part in the cathode reactions, was determined. The diffusion layer thickness in the liquid metal anode was estimated according to the values of metal-limiting diffusion current. The electrolytic reduction of lead from the Pb–Sb–Bi ternary alloys was performed. |
| doi_str_mv | 10.1007/s13738-019-01720-4 |
| format | Article |
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2
equimolar melt was studied. The lead dissolution process, which starts at the potentials close to the equilibrium ones, was found to be the basic process up to the certain potentials. A number of electrons, which take part in the cathode reactions, was determined. The diffusion layer thickness in the liquid metal anode was estimated according to the values of metal-limiting diffusion current. The electrolytic reduction of lead from the Pb–Sb–Bi ternary alloys was performed.</description><identifier>ISSN: 1735-207X</identifier><identifier>EISSN: 1735-2428</identifier><identifier>DOI: 10.1007/s13738-019-01720-4</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Analytical Chemistry ; Anodes ; Anodic dissolution ; Antimony ; Biochemistry ; Bismuth base alloys ; Chemistry ; Chemistry and Materials Science ; Diffusion layers ; Dissolution ; Inorganic Chemistry ; Lead ; Lead base alloys ; Lead chlorides ; Liquid metals ; Organic Chemistry ; Original Paper ; Physical Chemistry ; Potassium chloride ; Reduction ; Reduction (electrolytic) ; Ternary alloys ; Thickness</subject><ispartof>Journal of the Iranian Chemical Society, 2019-11, Vol.16 (11), p.2501-2507</ispartof><rights>Iranian Chemical Society 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-7126b8bd3c50ff714c3f80516aa33e25adebbd14cfb3d493125fec6b7ff19e413</citedby><cites>FETCH-LOGICAL-c319t-7126b8bd3c50ff714c3f80516aa33e25adebbd14cfb3d493125fec6b7ff19e413</cites><orcidid>0000-0001-6843-9667</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s13738-019-01720-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s13738-019-01720-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27929,27930,41493,42562,51324</link.rule.ids></links><search><creatorcontrib>Arkhipov, P. A.</creatorcontrib><creatorcontrib>Kholkina, A. S.</creatorcontrib><creatorcontrib>Zaykov, Yu. P.</creatorcontrib><creatorcontrib>Arkhipov, S. P.</creatorcontrib><title>Anode dissolution of ternary Pb–Sb–Bi alloys and reduction of lead in the KCl–PbC2 melt</title><title>Journal of the Iranian Chemical Society</title><addtitle>J IRAN CHEM SOC</addtitle><description>The influence of bismuth, antimony and lead concentrations on the Pb–Sb–Bi alloys anode dissolution in the KCl–PbCl
2
equimolar melt was studied. The lead dissolution process, which starts at the potentials close to the equilibrium ones, was found to be the basic process up to the certain potentials. A number of electrons, which take part in the cathode reactions, was determined. The diffusion layer thickness in the liquid metal anode was estimated according to the values of metal-limiting diffusion current. The electrolytic reduction of lead from the Pb–Sb–Bi ternary alloys was performed.</description><subject>Analytical Chemistry</subject><subject>Anodes</subject><subject>Anodic dissolution</subject><subject>Antimony</subject><subject>Biochemistry</subject><subject>Bismuth base alloys</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Diffusion layers</subject><subject>Dissolution</subject><subject>Inorganic Chemistry</subject><subject>Lead</subject><subject>Lead base alloys</subject><subject>Lead chlorides</subject><subject>Liquid metals</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Potassium chloride</subject><subject>Reduction</subject><subject>Reduction (electrolytic)</subject><subject>Ternary alloys</subject><subject>Thickness</subject><issn>1735-207X</issn><issn>1735-2428</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kMtKAzEUhoMoWKsv4CrgejTXZmZZizcsKKjgRkIySXRKOqnJzKI738E39ElMHYs7Fzk5HL7_wPkAOMboFCMkzhKmgpYFwlV-gqCC7YARFpQXhJFyd9sj8bwPDlJaIMQF4mwEXqZtMBaaJqXg-64JLQwOdja2Kq7hvf76-HzYlPMGKu_DOkHVGhit6est7K0ysGlh92bh7cxn-F7PCFxa3x2CPad8ske__xg8XV48zq6L-d3VzWw6L2qKq64QmEx0qQ2tOXJOYFZTVyKOJ0pRaglXxmpt8thpalhFMeHO1hMtnMOVZZiOwcmwdxXDe29TJxehzyf4JAmpGMdZj8gUGag6hpSidXIVm2W-U2IkNxrloFFmjfJHo2Q5RIdQynD7auPf6n9S3zPfd8s</recordid><startdate>20191101</startdate><enddate>20191101</enddate><creator>Arkhipov, P. A.</creator><creator>Kholkina, A. S.</creator><creator>Zaykov, Yu. P.</creator><creator>Arkhipov, S. P.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-6843-9667</orcidid></search><sort><creationdate>20191101</creationdate><title>Anode dissolution of ternary Pb–Sb–Bi alloys and reduction of lead in the KCl–PbC2 melt</title><author>Arkhipov, P. A. ; Kholkina, A. S. ; Zaykov, Yu. P. ; Arkhipov, S. P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-7126b8bd3c50ff714c3f80516aa33e25adebbd14cfb3d493125fec6b7ff19e413</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Analytical Chemistry</topic><topic>Anodes</topic><topic>Anodic dissolution</topic><topic>Antimony</topic><topic>Biochemistry</topic><topic>Bismuth base alloys</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Diffusion layers</topic><topic>Dissolution</topic><topic>Inorganic Chemistry</topic><topic>Lead</topic><topic>Lead base alloys</topic><topic>Lead chlorides</topic><topic>Liquid metals</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Potassium chloride</topic><topic>Reduction</topic><topic>Reduction (electrolytic)</topic><topic>Ternary alloys</topic><topic>Thickness</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Arkhipov, P. A.</creatorcontrib><creatorcontrib>Kholkina, A. S.</creatorcontrib><creatorcontrib>Zaykov, Yu. P.</creatorcontrib><creatorcontrib>Arkhipov, S. P.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of the Iranian Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Arkhipov, P. A.</au><au>Kholkina, A. S.</au><au>Zaykov, Yu. P.</au><au>Arkhipov, S. P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Anode dissolution of ternary Pb–Sb–Bi alloys and reduction of lead in the KCl–PbC2 melt</atitle><jtitle>Journal of the Iranian Chemical Society</jtitle><stitle>J IRAN CHEM SOC</stitle><date>2019-11-01</date><risdate>2019</risdate><volume>16</volume><issue>11</issue><spage>2501</spage><epage>2507</epage><pages>2501-2507</pages><issn>1735-207X</issn><eissn>1735-2428</eissn><abstract>The influence of bismuth, antimony and lead concentrations on the Pb–Sb–Bi alloys anode dissolution in the KCl–PbCl
2
equimolar melt was studied. The lead dissolution process, which starts at the potentials close to the equilibrium ones, was found to be the basic process up to the certain potentials. A number of electrons, which take part in the cathode reactions, was determined. The diffusion layer thickness in the liquid metal anode was estimated according to the values of metal-limiting diffusion current. The electrolytic reduction of lead from the Pb–Sb–Bi ternary alloys was performed.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s13738-019-01720-4</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0001-6843-9667</orcidid></addata></record> |
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| ispartof | Journal of the Iranian Chemical Society, 2019-11, Vol.16 (11), p.2501-2507 |
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| subjects | Analytical Chemistry Anodes Anodic dissolution Antimony Biochemistry Bismuth base alloys Chemistry Chemistry and Materials Science Diffusion layers Dissolution Inorganic Chemistry Lead Lead base alloys Lead chlorides Liquid metals Organic Chemistry Original Paper Physical Chemistry Potassium chloride Reduction Reduction (electrolytic) Ternary alloys Thickness |
| title | Anode dissolution of ternary Pb–Sb–Bi alloys and reduction of lead in the KCl–PbC2 melt |
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