Synthesis of ultrahigh molecular weight bottlebrush block copolymers of ω-end-norbornyl polystyrene and polymethacrylate macromonomers

Well-controlled polystyrene-polymethacrylate bottlebrush block copolymers (BBCPs) of ultrahigh molecular weight using ω-end-norbornyl polystyrene as the macromonomer for the first block were synthesized by combining living anionic polymerization (LAP) and ring-opening metathesis polymerization (ROMP...

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Veröffentlicht in:	Polymer (Guilford) 2019-08, Vol.177, p.241-249
Hauptverfasser:	Seo, Ho-Bin, Yu, Yong-Guen, Chae, Chang-Geun, Kim, Myung-Jin, Lee, Jae-Suk
Format:	Artikel
Sprache:	eng
Schlagworte:	Anionic polymerization Block copolymers Bottlebrush block copolymers Chemical synthesis Copolymers Degree of polymerization Dispersion Metathesis Molecular weight Morphology Photonic crystals Physical characteristics Polymerization Polymethyl methacrylate Polymethylmethacrylate Polystyrene Polystyrene resins Ring-opening metathesis polymerization Self-assembly
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