New vesicular carbon-based rhenium phosphides with all-pH range electrocatalytic hydrogen evolution activity

[Display omitted] •The novel Re3P4@NPVC and Re2P@NPVC catalysts were designed by a novel strategy.•Coupling metal Re and P is able to promote the HER pathway.•The electronic coupling of NPVC layer and nanoparticles efficiently promotes the electron-transfer process for HER.•The Re3P4@NPVC exhibit re...

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