Structure and Properties of the Non‐Centrosymmetric Manganese(II) Borate Mn5(BO3)3OH
The rose‐colored compound Mn5(BO3)3OH was synthesized under high‐pressure/high‐temperature conditions of 2.5 GPa and 973 K in a Walker‐type multianvil press. Single‐crystal X‐ray structure determination yielded the non‐centrosymmetric monoclinic space group Pm (no. 6) with the lattice parameters a =...
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| Veröffentlicht in: | European journal of inorganic chemistry 2019-09, Vol.2019 (34), p.3854-3862 |
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| creator | Falkowski, Viktoria Zeugner, Alexander Bayarjargal, Lkhamsuren Saxer, Andreas Ruck, Michael Huppertz, Hubert |
| description | The rose‐colored compound Mn5(BO3)3OH was synthesized under high‐pressure/high‐temperature conditions of 2.5 GPa and 973 K in a Walker‐type multianvil press. Single‐crystal X‐ray structure determination yielded the non‐centrosymmetric monoclinic space group Pm (no. 6) with the lattice parameters a = 329.71(1), b = 1384.92(5), c = 902.37(3) pm, and β = 107.92(1)°. The presence of the hydroxide group is ascertained by vibrational spectroscopy. Magnetization experiments in the range from 300 to 14 K revealed paramagnetic behavior with antiferromagnetic ordering below 14 K and an effective magnetic moment of 12.2 µB per formula unit. The acentric nature of the material was verified by second harmonic generation measurements, yielding a considerably strong intensity (Isample/Iquartz = 11.14). Additionally, thermal investigations showed a several‐step transformation to Mn2OBO3 upon heating under air.
High‐pressure synthesis of acentric Mn5(BO3)3OH: By means of high‐pressure/high temperature synthesis, the non‐centrosymmetric manganese(II) compound Mn5(BO3)3OH was obtained and characterized by single‐crystal and powder X‐ray diffraction. Additionally, vibrational spectroscopy, UV/Vis, thermoanalytical, magnetic, and SHG measurements were performed. |
| doi_str_mv | 10.1002/ejic.201900769 |
| format | Article |
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High‐pressure synthesis of acentric Mn5(BO3)3OH: By means of high‐pressure/high temperature synthesis, the non‐centrosymmetric manganese(II) compound Mn5(BO3)3OH was obtained and characterized by single‐crystal and powder X‐ray diffraction. Additionally, vibrational spectroscopy, UV/Vis, thermoanalytical, magnetic, and SHG measurements were performed.</description><identifier>ISSN: 1434-1948</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/ejic.201900769</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Antiferromagnetism ; Borates ; Crystal structure ; High‐pressure chemistry ; Inorganic chemistry ; Lattice parameters ; Magnetic moments ; Magnetic properties ; Manganese ; Second harmonic generation ; Structure elucidation</subject><ispartof>European journal of inorganic chemistry, 2019-09, Vol.2019 (34), p.3854-3862</ispartof><rights>2019 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2019. This article is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-8570-7659 ; 0000-0002-2098-6087 ; 0000-0002-2391-6025</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fejic.201900769$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fejic.201900769$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Falkowski, Viktoria</creatorcontrib><creatorcontrib>Zeugner, Alexander</creatorcontrib><creatorcontrib>Bayarjargal, Lkhamsuren</creatorcontrib><creatorcontrib>Saxer, Andreas</creatorcontrib><creatorcontrib>Ruck, Michael</creatorcontrib><creatorcontrib>Huppertz, Hubert</creatorcontrib><title>Structure and Properties of the Non‐Centrosymmetric Manganese(II) Borate Mn5(BO3)3OH</title><title>European journal of inorganic chemistry</title><description>The rose‐colored compound Mn5(BO3)3OH was synthesized under high‐pressure/high‐temperature conditions of 2.5 GPa and 973 K in a Walker‐type multianvil press. Single‐crystal X‐ray structure determination yielded the non‐centrosymmetric monoclinic space group Pm (no. 6) with the lattice parameters a = 329.71(1), b = 1384.92(5), c = 902.37(3) pm, and β = 107.92(1)°. The presence of the hydroxide group is ascertained by vibrational spectroscopy. Magnetization experiments in the range from 300 to 14 K revealed paramagnetic behavior with antiferromagnetic ordering below 14 K and an effective magnetic moment of 12.2 µB per formula unit. The acentric nature of the material was verified by second harmonic generation measurements, yielding a considerably strong intensity (Isample/Iquartz = 11.14). Additionally, thermal investigations showed a several‐step transformation to Mn2OBO3 upon heating under air.
High‐pressure synthesis of acentric Mn5(BO3)3OH: By means of high‐pressure/high temperature synthesis, the non‐centrosymmetric manganese(II) compound Mn5(BO3)3OH was obtained and characterized by single‐crystal and powder X‐ray diffraction. Additionally, vibrational spectroscopy, UV/Vis, thermoanalytical, magnetic, and SHG measurements were performed.</description><subject>Antiferromagnetism</subject><subject>Borates</subject><subject>Crystal structure</subject><subject>High‐pressure chemistry</subject><subject>Inorganic chemistry</subject><subject>Lattice parameters</subject><subject>Magnetic moments</subject><subject>Magnetic properties</subject><subject>Manganese</subject><subject>Second harmonic generation</subject><subject>Structure elucidation</subject><issn>1434-1948</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNo9kM1KAzEUhYMoWKtb1wE3dTH15qeZZGlLtSOtFfzZhjRNdEo7M2YySHc-gs_okzil0tU9Fz7OgQ-hSwJ9AkBv3Cq3fQpEAaRCHaEOAaUSEJIet5kznhDF5Sk6q-sVADBgooPenmNobGyCw6ZY4qdQVi7E3NW49Dh-OPxYFr_fPyNXxFDW283GxZBbPDPFuylc7XpZdo2HZTDR4Vkx6A3n7JrNJ-foxJt17S7-bxe93o1fRpNkOr_PRrfTpCJcqkTYVIIAwRdeMgWeMqq4VcQOvE2955LQlDIBhnsvhVTcWKH8YiGcVVYsGeuiq31vFcrPxtVRr8omFO2kprTliVJ00FJqT33la7fVVcg3Jmw1Ab0Tp3fi9EGcHj9ko8PH_gAO0mNF</recordid><startdate>20190915</startdate><enddate>20190915</enddate><creator>Falkowski, Viktoria</creator><creator>Zeugner, Alexander</creator><creator>Bayarjargal, Lkhamsuren</creator><creator>Saxer, Andreas</creator><creator>Ruck, Michael</creator><creator>Huppertz, Hubert</creator><general>Wiley Subscription Services, Inc</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-8570-7659</orcidid><orcidid>https://orcid.org/0000-0002-2098-6087</orcidid><orcidid>https://orcid.org/0000-0002-2391-6025</orcidid></search><sort><creationdate>20190915</creationdate><title>Structure and Properties of the Non‐Centrosymmetric Manganese(II) Borate Mn5(BO3)3OH</title><author>Falkowski, Viktoria ; Zeugner, Alexander ; Bayarjargal, Lkhamsuren ; Saxer, Andreas ; Ruck, Michael ; Huppertz, Hubert</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p1489-6c7806064bf8390f23294c91c5fc7ff481272360a4ff86894ac69fbb6ec9c6d33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Antiferromagnetism</topic><topic>Borates</topic><topic>Crystal structure</topic><topic>High‐pressure chemistry</topic><topic>Inorganic chemistry</topic><topic>Lattice parameters</topic><topic>Magnetic moments</topic><topic>Magnetic properties</topic><topic>Manganese</topic><topic>Second harmonic generation</topic><topic>Structure elucidation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Falkowski, Viktoria</creatorcontrib><creatorcontrib>Zeugner, Alexander</creatorcontrib><creatorcontrib>Bayarjargal, Lkhamsuren</creatorcontrib><creatorcontrib>Saxer, Andreas</creatorcontrib><creatorcontrib>Ruck, Michael</creatorcontrib><creatorcontrib>Huppertz, Hubert</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>European journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Falkowski, Viktoria</au><au>Zeugner, Alexander</au><au>Bayarjargal, Lkhamsuren</au><au>Saxer, Andreas</au><au>Ruck, Michael</au><au>Huppertz, Hubert</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structure and Properties of the Non‐Centrosymmetric Manganese(II) Borate Mn5(BO3)3OH</atitle><jtitle>European journal of inorganic chemistry</jtitle><date>2019-09-15</date><risdate>2019</risdate><volume>2019</volume><issue>34</issue><spage>3854</spage><epage>3862</epage><pages>3854-3862</pages><issn>1434-1948</issn><eissn>1099-0682</eissn><abstract>The rose‐colored compound Mn5(BO3)3OH was synthesized under high‐pressure/high‐temperature conditions of 2.5 GPa and 973 K in a Walker‐type multianvil press. Single‐crystal X‐ray structure determination yielded the non‐centrosymmetric monoclinic space group Pm (no. 6) with the lattice parameters a = 329.71(1), b = 1384.92(5), c = 902.37(3) pm, and β = 107.92(1)°. The presence of the hydroxide group is ascertained by vibrational spectroscopy. Magnetization experiments in the range from 300 to 14 K revealed paramagnetic behavior with antiferromagnetic ordering below 14 K and an effective magnetic moment of 12.2 µB per formula unit. The acentric nature of the material was verified by second harmonic generation measurements, yielding a considerably strong intensity (Isample/Iquartz = 11.14). Additionally, thermal investigations showed a several‐step transformation to Mn2OBO3 upon heating under air.
High‐pressure synthesis of acentric Mn5(BO3)3OH: By means of high‐pressure/high temperature synthesis, the non‐centrosymmetric manganese(II) compound Mn5(BO3)3OH was obtained and characterized by single‐crystal and powder X‐ray diffraction. Additionally, vibrational spectroscopy, UV/Vis, thermoanalytical, magnetic, and SHG measurements were performed.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/ejic.201900769</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-8570-7659</orcidid><orcidid>https://orcid.org/0000-0002-2098-6087</orcidid><orcidid>https://orcid.org/0000-0002-2391-6025</orcidid></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Antiferromagnetism Borates Crystal structure High‐pressure chemistry Inorganic chemistry Lattice parameters Magnetic moments Magnetic properties Manganese Second harmonic generation Structure elucidation |
| title | Structure and Properties of the Non‐Centrosymmetric Manganese(II) Borate Mn5(BO3)3OH |
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