Catalyst‐ and Additive‐Free Chemoselective Transfer Hydrogenation of α‐Keto Amides to α‐Hydroxy Amides by Sodium Formate

A catalyst‐ and additive‐free chemoselective transfer hydrogenation of α‐keto amides to α‐hydroxy amides is easily achieved by using sodium formate as a hydrogen source. The utility of this method is demonstrated by gram‐scale synthesis and transformation of the resultant α‐hydroxy amides into polys...

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Veröffentlicht in:	European journal of organic chemistry 2019-09, Vol.2019 (34), p.5985-5991
Hauptverfasser:	Hao, Feiyue, Gu, Zhenyu, Liu, Guyue, Yao, Wubing, Jiang, Huajiang, Wu, Jiashou
Format:	Artikel
Sprache:	eng
Schlagworte:	Amides Catalysis Catalysts Chemical industry Hydrogen bonding Hydrogen bonds Hydrogen storage Hydrogenation Sodium formate Transfer hydrogenation α‐Hydroxy amides α‐Keto amides
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