Synthesis, Structure, Magnetic and Photoluminescent Properties of Lanthanide(III) Complexes with a Ligand Based on 1,10-Phenanthroline and (+)−3-Carene
Ionic complexes of the composition [LnL 2 (NO 3 ) 2 ] 2 [Ln(NO 3 ) 5 ]3Me 2 CO (Ln = Sm ( 1 ), Eu ( 2 ), Tb ( 3 ), Dy ( 4 )) with an optically active ligand L containing 1,10-phenanthroline and (+)−3-carene moieties are synthesized. According to the X-ray crystallographic data, the crystal structure...
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| Veröffentlicht in: | Journal of structural chemistry 2019-08, Vol.60 (8), p.1314-1326 |
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| creator | Bryleva, Yu. A. Glinskaya, L. A. Agafontsev, A. M. Rakhmanova, M. I. Bogomyakov, A. S. Sukhikh, T. S. Gorbunova, E. A. Tkachev, A. V. Larionov, S. V. |
| description | Ionic complexes of the composition [LnL
2
(NO
3
)
2
]
2
[Ln(NO
3
)
5
]3Me
2
CO (Ln = Sm (
1
), Eu (
2
), Tb (
3
), Dy (
4
)) with an optically active ligand
L
containing 1,10-phenanthroline and (+)−3-carene moieties are synthesized. According to the X-ray crystallographic data, the crystal structure of compound
2
is composed of complex [EuL
2
(NO
3
)
2
]
+
cations (N
6
O
4
polyhedron) and complex [Eu(NO
3
)
5
]
2−
anions (O
10
polyhedron), and also Me
2
CO molecules. The
L
and NO
3
ligands perform both tridentate and bidentate chelating functions respectively. Complexes
1–4
are isostructural and crystallize in the non-centrosymmetric space group
P
1; their magnetic properties are studied in the temperature range 2–300 K. The μ
eff
values for
1–4
at 300 K are 3.14 μ
B
, 6.08 μ
B
, 16.76 μ
B
, and 18.30 μ
B
respectively and are typical of Ln
3+
ions. For complex
3
significant anisotropy results in a nonlinear field dependence of the magnetization at 2 K. Complexes
1–4
exhibit metal-centered orange (Sm
3+
), red (Eu
3+
), green (Tb
3+
), and yellow (Dy
3+
) luminescence in the solid state at room temperature. Luminescence quantum yield decreases for solid samples in the order
2 > 1 > 3 ≈ 4. |
| doi_str_mv | 10.1134/S0022476619080110 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2284678518</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2284678518</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-5b298f926f7a8f62b88fae12df69fcc44abfd9fdbc57a403f3f6af4458f66fa63</originalsourceid><addsrcrecordid>eNp1kb1OwzAUhS0EEqXwAGyWWIpowHYSxxkh4idSEZUKc-Qm122q1i62I-gbMLPxejwJCUViQEx3OOf7znAROqbknNIwupgQwliUcE5TIgilZAf1aJyEgUiSdBf1ujjo8n104NyCEJKKlPfQx2Sj_Rxc7YZ44m1T-sbCEN_LmQZfl1jqCo_nxptls6o1uBK0x2Nr1mB9DQ4bhUeyNUhdVzDI8_wUZ2a1XsJrG77Ufo4lHtWzTnMlHVTYaEyHlATjOegOtGbZer93Bmenn2_vYZBJCxoO0Z6SSwdHP7ePnm6uH7O7YPRwm2eXo6AMKfdBPGWpUCnjKpFCcTYVQkmgrFI8VWUZRXKqqlRV0zJOZERCFSouVRTFbZkrycM-Otl619Y8N-B8sTCN1e1kwZiIeCJiKtoW3bZKa5yzoIq1rVfSbgpKiu4DxZ8PtAzbMq7t6hnYX_P_0Be-9Ymi</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2284678518</pqid></control><display><type>article</type><title>Synthesis, Structure, Magnetic and Photoluminescent Properties of Lanthanide(III) Complexes with a Ligand Based on 1,10-Phenanthroline and (+)−3-Carene</title><source>SpringerLink Journals - AutoHoldings</source><creator>Bryleva, Yu. A. ; Glinskaya, L. A. ; Agafontsev, A. M. ; Rakhmanova, M. I. ; Bogomyakov, A. S. ; Sukhikh, T. S. ; Gorbunova, E. A. ; Tkachev, A. V. ; Larionov, S. V.</creator><creatorcontrib>Bryleva, Yu. A. ; Glinskaya, L. A. ; Agafontsev, A. M. ; Rakhmanova, M. I. ; Bogomyakov, A. S. ; Sukhikh, T. S. ; Gorbunova, E. A. ; Tkachev, A. V. ; Larionov, S. V.</creatorcontrib><description>Ionic complexes of the composition [LnL
2
(NO
3
)
2
]
2
[Ln(NO
3
)
5
]3Me
2
CO (Ln = Sm (
1
), Eu (
2
), Tb (
3
), Dy (
4
)) with an optically active ligand
L
containing 1,10-phenanthroline and (+)−3-carene moieties are synthesized. According to the X-ray crystallographic data, the crystal structure of compound
2
is composed of complex [EuL
2
(NO
3
)
2
]
+
cations (N
6
O
4
polyhedron) and complex [Eu(NO
3
)
5
]
2−
anions (O
10
polyhedron), and also Me
2
CO molecules. The
L
and NO
3
ligands perform both tridentate and bidentate chelating functions respectively. Complexes
1–4
are isostructural and crystallize in the non-centrosymmetric space group
P
1; their magnetic properties are studied in the temperature range 2–300 K. The μ
eff
values for
1–4
at 300 K are 3.14 μ
B
, 6.08 μ
B
, 16.76 μ
B
, and 18.30 μ
B
respectively and are typical of Ln
3+
ions. For complex
3
significant anisotropy results in a nonlinear field dependence of the magnetization at 2 K. Complexes
1–4
exhibit metal-centered orange (Sm
3+
), red (Eu
3+
), green (Tb
3+
), and yellow (Dy
3+
) luminescence in the solid state at room temperature. Luminescence quantum yield decreases for solid samples in the order
2 > 1 > 3 ≈ 4.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476619080110</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Anisotropy ; Atomic ; Atomic/Molecular Structure and Spectra ; Chelation ; Chemistry ; Chemistry and Materials Science ; Coordination compounds ; Crystal structure ; Crystallography ; Dependence ; Dysprosium ; Inorganic Chemistry ; Ligands ; Luminescence ; Magnetic properties ; Molecular ; Optical activity ; Optical and Plasma Physics ; Photoluminescence ; Physical Chemistry ; Polyhedra ; Samarium ; Solid State Physics</subject><ispartof>Journal of structural chemistry, 2019-08, Vol.60 (8), p.1314-1326</ispartof><rights>Pleiades Publishing, Ltd. 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-5b298f926f7a8f62b88fae12df69fcc44abfd9fdbc57a403f3f6af4458f66fa63</citedby><cites>FETCH-LOGICAL-c316t-5b298f926f7a8f62b88fae12df69fcc44abfd9fdbc57a403f3f6af4458f66fa63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0022476619080110$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0022476619080110$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Bryleva, Yu. A.</creatorcontrib><creatorcontrib>Glinskaya, L. A.</creatorcontrib><creatorcontrib>Agafontsev, A. M.</creatorcontrib><creatorcontrib>Rakhmanova, M. I.</creatorcontrib><creatorcontrib>Bogomyakov, A. S.</creatorcontrib><creatorcontrib>Sukhikh, T. S.</creatorcontrib><creatorcontrib>Gorbunova, E. A.</creatorcontrib><creatorcontrib>Tkachev, A. V.</creatorcontrib><creatorcontrib>Larionov, S. V.</creatorcontrib><title>Synthesis, Structure, Magnetic and Photoluminescent Properties of Lanthanide(III) Complexes with a Ligand Based on 1,10-Phenanthroline and (+)−3-Carene</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>Ionic complexes of the composition [LnL
2
(NO
3
)
2
]
2
[Ln(NO
3
)
5
]3Me
2
CO (Ln = Sm (
1
), Eu (
2
), Tb (
3
), Dy (
4
)) with an optically active ligand
L
containing 1,10-phenanthroline and (+)−3-carene moieties are synthesized. According to the X-ray crystallographic data, the crystal structure of compound
2
is composed of complex [EuL
2
(NO
3
)
2
]
+
cations (N
6
O
4
polyhedron) and complex [Eu(NO
3
)
5
]
2−
anions (O
10
polyhedron), and also Me
2
CO molecules. The
L
and NO
3
ligands perform both tridentate and bidentate chelating functions respectively. Complexes
1–4
are isostructural and crystallize in the non-centrosymmetric space group
P
1; their magnetic properties are studied in the temperature range 2–300 K. The μ
eff
values for
1–4
at 300 K are 3.14 μ
B
, 6.08 μ
B
, 16.76 μ
B
, and 18.30 μ
B
respectively and are typical of Ln
3+
ions. For complex
3
significant anisotropy results in a nonlinear field dependence of the magnetization at 2 K. Complexes
1–4
exhibit metal-centered orange (Sm
3+
), red (Eu
3+
), green (Tb
3+
), and yellow (Dy
3+
) luminescence in the solid state at room temperature. Luminescence quantum yield decreases for solid samples in the order
2 > 1 > 3 ≈ 4.</description><subject>Anisotropy</subject><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Chelation</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination compounds</subject><subject>Crystal structure</subject><subject>Crystallography</subject><subject>Dependence</subject><subject>Dysprosium</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>Luminescence</subject><subject>Magnetic properties</subject><subject>Molecular</subject><subject>Optical activity</subject><subject>Optical and Plasma Physics</subject><subject>Photoluminescence</subject><subject>Physical Chemistry</subject><subject>Polyhedra</subject><subject>Samarium</subject><subject>Solid State Physics</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kb1OwzAUhS0EEqXwAGyWWIpowHYSxxkh4idSEZUKc-Qm122q1i62I-gbMLPxejwJCUViQEx3OOf7znAROqbknNIwupgQwliUcE5TIgilZAf1aJyEgUiSdBf1ujjo8n104NyCEJKKlPfQx2Sj_Rxc7YZ44m1T-sbCEN_LmQZfl1jqCo_nxptls6o1uBK0x2Nr1mB9DQ4bhUeyNUhdVzDI8_wUZ2a1XsJrG77Ufo4lHtWzTnMlHVTYaEyHlATjOegOtGbZer93Bmenn2_vYZBJCxoO0Z6SSwdHP7ePnm6uH7O7YPRwm2eXo6AMKfdBPGWpUCnjKpFCcTYVQkmgrFI8VWUZRXKqqlRV0zJOZERCFSouVRTFbZkrycM-Otl619Y8N-B8sTCN1e1kwZiIeCJiKtoW3bZKa5yzoIq1rVfSbgpKiu4DxZ8PtAzbMq7t6hnYX_P_0Be-9Ymi</recordid><startdate>20190801</startdate><enddate>20190801</enddate><creator>Bryleva, Yu. A.</creator><creator>Glinskaya, L. A.</creator><creator>Agafontsev, A. M.</creator><creator>Rakhmanova, M. I.</creator><creator>Bogomyakov, A. S.</creator><creator>Sukhikh, T. S.</creator><creator>Gorbunova, E. A.</creator><creator>Tkachev, A. V.</creator><creator>Larionov, S. V.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20190801</creationdate><title>Synthesis, Structure, Magnetic and Photoluminescent Properties of Lanthanide(III) Complexes with a Ligand Based on 1,10-Phenanthroline and (+)−3-Carene</title><author>Bryleva, Yu. A. ; Glinskaya, L. A. ; Agafontsev, A. M. ; Rakhmanova, M. I. ; Bogomyakov, A. S. ; Sukhikh, T. S. ; Gorbunova, E. A. ; Tkachev, A. V. ; Larionov, S. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-5b298f926f7a8f62b88fae12df69fcc44abfd9fdbc57a403f3f6af4458f66fa63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Anisotropy</topic><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Chelation</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination compounds</topic><topic>Crystal structure</topic><topic>Crystallography</topic><topic>Dependence</topic><topic>Dysprosium</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>Luminescence</topic><topic>Magnetic properties</topic><topic>Molecular</topic><topic>Optical activity</topic><topic>Optical and Plasma Physics</topic><topic>Photoluminescence</topic><topic>Physical Chemistry</topic><topic>Polyhedra</topic><topic>Samarium</topic><topic>Solid State Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bryleva, Yu. A.</creatorcontrib><creatorcontrib>Glinskaya, L. A.</creatorcontrib><creatorcontrib>Agafontsev, A. M.</creatorcontrib><creatorcontrib>Rakhmanova, M. I.</creatorcontrib><creatorcontrib>Bogomyakov, A. S.</creatorcontrib><creatorcontrib>Sukhikh, T. S.</creatorcontrib><creatorcontrib>Gorbunova, E. A.</creatorcontrib><creatorcontrib>Tkachev, A. V.</creatorcontrib><creatorcontrib>Larionov, S. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bryleva, Yu. A.</au><au>Glinskaya, L. A.</au><au>Agafontsev, A. M.</au><au>Rakhmanova, M. I.</au><au>Bogomyakov, A. S.</au><au>Sukhikh, T. S.</au><au>Gorbunova, E. A.</au><au>Tkachev, A. V.</au><au>Larionov, S. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, Structure, Magnetic and Photoluminescent Properties of Lanthanide(III) Complexes with a Ligand Based on 1,10-Phenanthroline and (+)−3-Carene</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2019-08-01</date><risdate>2019</risdate><volume>60</volume><issue>8</issue><spage>1314</spage><epage>1326</epage><pages>1314-1326</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>Ionic complexes of the composition [LnL
2
(NO
3
)
2
]
2
[Ln(NO
3
)
5
]3Me
2
CO (Ln = Sm (
1
), Eu (
2
), Tb (
3
), Dy (
4
)) with an optically active ligand
L
containing 1,10-phenanthroline and (+)−3-carene moieties are synthesized. According to the X-ray crystallographic data, the crystal structure of compound
2
is composed of complex [EuL
2
(NO
3
)
2
]
+
cations (N
6
O
4
polyhedron) and complex [Eu(NO
3
)
5
]
2−
anions (O
10
polyhedron), and also Me
2
CO molecules. The
L
and NO
3
ligands perform both tridentate and bidentate chelating functions respectively. Complexes
1–4
are isostructural and crystallize in the non-centrosymmetric space group
P
1; their magnetic properties are studied in the temperature range 2–300 K. The μ
eff
values for
1–4
at 300 K are 3.14 μ
B
, 6.08 μ
B
, 16.76 μ
B
, and 18.30 μ
B
respectively and are typical of Ln
3+
ions. For complex
3
significant anisotropy results in a nonlinear field dependence of the magnetization at 2 K. Complexes
1–4
exhibit metal-centered orange (Sm
3+
), red (Eu
3+
), green (Tb
3+
), and yellow (Dy
3+
) luminescence in the solid state at room temperature. Luminescence quantum yield decreases for solid samples in the order
2 > 1 > 3 ≈ 4.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476619080110</doi><tpages>13</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Journal of structural chemistry, 2019-08, Vol.60 (8), p.1314-1326 |
| issn | 0022-4766 1573-8779 |
| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Anisotropy Atomic Atomic/Molecular Structure and Spectra Chelation Chemistry Chemistry and Materials Science Coordination compounds Crystal structure Crystallography Dependence Dysprosium Inorganic Chemistry Ligands Luminescence Magnetic properties Molecular Optical activity Optical and Plasma Physics Photoluminescence Physical Chemistry Polyhedra Samarium Solid State Physics |
| title | Synthesis, Structure, Magnetic and Photoluminescent Properties of Lanthanide(III) Complexes with a Ligand Based on 1,10-Phenanthroline and (+)−3-Carene |
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