A Palladium‐Catalyzed Decarboxylative Heck‐Type Reaction of Disubstituted Vinylphosphonates in the Stereoselective Synthesis of Trisubstituted Vinylphosphonates

We describe a highly stereoselective and atomically economical approach for the preparation of trisubstituted vinylphosphonates through palladium‐catalyzed decarboxylative Heck‐type reactions of vinylphosphonates. Excellent E/Z selectivity was achieved mostly with E‐isomers; this was difficult to ac...

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Veröffentlicht in:	European journal of organic chemistry 2019-09, Vol.2019 (33), p.5656-5661
Hauptverfasser:	Ren, Linjing, Ran, Maogang, He, Jiaxin, Xiang, Dan, Chen, Feng, Liu, Peijun, He, Chunyang, Yao, Qiuli
Format:	Artikel
Sprache:	eng
Schlagworte:	Carboxylic acids Chemical reactions Chemical synthesis C–C coupling Decarboxylative Heck‐type reaction Isomers Palladium Phosphorus Selectivity Stereoselectivity Vinylphosphonate
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