Ruthenium‐Catalyzed Alternating Ring‐Opening Metathesis Copolymerization of Norborn‐2‐ene with Cyclic Olefins
A Grubbs‐type olefin metathesis catalyst bearing a backbone‐substituted unsymmetrical N‐heterocyclic carbene (NHC) ligand has been prepared from readily available reagents using a four‐step synthetic protocol. This catalyst was found able to promote the alternating ring‐opening metathesis copolymeri...
Gespeichert in:
| Veröffentlicht in: | Advanced synthesis & catalysis 2019-09, Vol.361 (17), p.4133-4139 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 4139 |
|---|---|
| container_issue | 17 |
| container_start_page | 4133 |
| container_title | Advanced synthesis & catalysis |
| container_volume | 361 |
| creator | Paradiso, Veronica Grisi, Fabia |
| description | A Grubbs‐type olefin metathesis catalyst bearing a backbone‐substituted unsymmetrical N‐heterocyclic carbene (NHC) ligand has been prepared from readily available reagents using a four‐step synthetic protocol. This catalyst was found able to promote the alternating ring‐opening metathesis copolymerization of norborn‐2‐ene (NBE) with cis‐cyclooctene (COE) or cyclopentene (CPE) with a high degree of chemoselectivity (98% and 95% of alternating diads, respectively) at low comonomers ratios. |
| doi_str_mv | 10.1002/adsc.201900565 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2284134153</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2284134153</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3545-b4ca449fe2eed306acf63f8fadd3499edbbd65016e37b85b7e16a6ef5bc5d01c3</originalsourceid><addsrcrecordid>eNqFkL9OwzAQhyMEEqWwMkdiTrHj2EnGKvyVCpUKzJbjnKmrNA52oiqdeASekSfBVVEZGc53J3-fJf-C4BKjCUYovhaVk5MY4RwhyuhRMMIM0yjBLD8-zBSdBmfOrRDCaZamo6Bf9N0SGt2vvz-_CtGJethCFU7rDmwjOt28hwt_-Mt56zG_PkEnvOK0CwvTmnpYg9Vbj5omNCp8NrY0tvFC7AsaCDe6W4bFIGstw3kNSjfuPDhRonZw8dvHwdvd7WvxEM3m94_FdBZJQhMalYkUSZIriAEqgpiQihGVKVFVJMlzqMqyYhRhBiQtM1qmgJlgoGgpaYWwJOPgav9ua81HD67jK9P7f9WOx3GWYOITIZ6a7ClpjXMWFG-tXgs7cIz4Llq-i5YfovVCvhc2uobhH5pPb16KP_cHkIqEcA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2284134153</pqid></control><display><type>article</type><title>Ruthenium‐Catalyzed Alternating Ring‐Opening Metathesis Copolymerization of Norborn‐2‐ene with Cyclic Olefins</title><source>Access via Wiley Online Library</source><creator>Paradiso, Veronica ; Grisi, Fabia</creator><creatorcontrib>Paradiso, Veronica ; Grisi, Fabia</creatorcontrib><description>A Grubbs‐type olefin metathesis catalyst bearing a backbone‐substituted unsymmetrical N‐heterocyclic carbene (NHC) ligand has been prepared from readily available reagents using a four‐step synthetic protocol. This catalyst was found able to promote the alternating ring‐opening metathesis copolymerization of norborn‐2‐ene (NBE) with cis‐cyclooctene (COE) or cyclopentene (CPE) with a high degree of chemoselectivity (98% and 95% of alternating diads, respectively) at low comonomers ratios.</description><identifier>ISSN: 1615-4150</identifier><identifier>EISSN: 1615-4169</identifier><identifier>DOI: 10.1002/adsc.201900565</identifier><language>eng</language><publisher>Heidelberg: Wiley Subscription Services, Inc</publisher><subject>Alkenes ; alternating copolymerization ; Catalysis ; Catalysts ; Copolymerization ; Cyclopentene ; Metathesis ; NHC ligand ; olefin metathesis ; Reagents ; ROMP ; Ruthenium ; ruthenium catalysts</subject><ispartof>Advanced synthesis & catalysis, 2019-09, Vol.361 (17), p.4133-4139</ispartof><rights>2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3545-b4ca449fe2eed306acf63f8fadd3499edbbd65016e37b85b7e16a6ef5bc5d01c3</citedby><cites>FETCH-LOGICAL-c3545-b4ca449fe2eed306acf63f8fadd3499edbbd65016e37b85b7e16a6ef5bc5d01c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fadsc.201900565$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadsc.201900565$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27928,27929,45578,45579</link.rule.ids></links><search><creatorcontrib>Paradiso, Veronica</creatorcontrib><creatorcontrib>Grisi, Fabia</creatorcontrib><title>Ruthenium‐Catalyzed Alternating Ring‐Opening Metathesis Copolymerization of Norborn‐2‐ene with Cyclic Olefins</title><title>Advanced synthesis & catalysis</title><description>A Grubbs‐type olefin metathesis catalyst bearing a backbone‐substituted unsymmetrical N‐heterocyclic carbene (NHC) ligand has been prepared from readily available reagents using a four‐step synthetic protocol. This catalyst was found able to promote the alternating ring‐opening metathesis copolymerization of norborn‐2‐ene (NBE) with cis‐cyclooctene (COE) or cyclopentene (CPE) with a high degree of chemoselectivity (98% and 95% of alternating diads, respectively) at low comonomers ratios.</description><subject>Alkenes</subject><subject>alternating copolymerization</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Copolymerization</subject><subject>Cyclopentene</subject><subject>Metathesis</subject><subject>NHC ligand</subject><subject>olefin metathesis</subject><subject>Reagents</subject><subject>ROMP</subject><subject>Ruthenium</subject><subject>ruthenium catalysts</subject><issn>1615-4150</issn><issn>1615-4169</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkL9OwzAQhyMEEqWwMkdiTrHj2EnGKvyVCpUKzJbjnKmrNA52oiqdeASekSfBVVEZGc53J3-fJf-C4BKjCUYovhaVk5MY4RwhyuhRMMIM0yjBLD8-zBSdBmfOrRDCaZamo6Bf9N0SGt2vvz-_CtGJethCFU7rDmwjOt28hwt_-Mt56zG_PkEnvOK0CwvTmnpYg9Vbj5omNCp8NrY0tvFC7AsaCDe6W4bFIGstw3kNSjfuPDhRonZw8dvHwdvd7WvxEM3m94_FdBZJQhMalYkUSZIriAEqgpiQihGVKVFVJMlzqMqyYhRhBiQtM1qmgJlgoGgpaYWwJOPgav9ua81HD67jK9P7f9WOx3GWYOITIZ6a7ClpjXMWFG-tXgs7cIz4Llq-i5YfovVCvhc2uobhH5pPb16KP_cHkIqEcA</recordid><startdate>20190903</startdate><enddate>20190903</enddate><creator>Paradiso, Veronica</creator><creator>Grisi, Fabia</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20190903</creationdate><title>Ruthenium‐Catalyzed Alternating Ring‐Opening Metathesis Copolymerization of Norborn‐2‐ene with Cyclic Olefins</title><author>Paradiso, Veronica ; Grisi, Fabia</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3545-b4ca449fe2eed306acf63f8fadd3499edbbd65016e37b85b7e16a6ef5bc5d01c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Alkenes</topic><topic>alternating copolymerization</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Copolymerization</topic><topic>Cyclopentene</topic><topic>Metathesis</topic><topic>NHC ligand</topic><topic>olefin metathesis</topic><topic>Reagents</topic><topic>ROMP</topic><topic>Ruthenium</topic><topic>ruthenium catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Paradiso, Veronica</creatorcontrib><creatorcontrib>Grisi, Fabia</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced synthesis & catalysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Paradiso, Veronica</au><au>Grisi, Fabia</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ruthenium‐Catalyzed Alternating Ring‐Opening Metathesis Copolymerization of Norborn‐2‐ene with Cyclic Olefins</atitle><jtitle>Advanced synthesis & catalysis</jtitle><date>2019-09-03</date><risdate>2019</risdate><volume>361</volume><issue>17</issue><spage>4133</spage><epage>4139</epage><pages>4133-4139</pages><issn>1615-4150</issn><eissn>1615-4169</eissn><abstract>A Grubbs‐type olefin metathesis catalyst bearing a backbone‐substituted unsymmetrical N‐heterocyclic carbene (NHC) ligand has been prepared from readily available reagents using a four‐step synthetic protocol. This catalyst was found able to promote the alternating ring‐opening metathesis copolymerization of norborn‐2‐ene (NBE) with cis‐cyclooctene (COE) or cyclopentene (CPE) with a high degree of chemoselectivity (98% and 95% of alternating diads, respectively) at low comonomers ratios.</abstract><cop>Heidelberg</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/adsc.201900565</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1615-4150 |
| ispartof | Advanced synthesis & catalysis, 2019-09, Vol.361 (17), p.4133-4139 |
| issn | 1615-4150 1615-4169 |
| language | eng |
| recordid | cdi_proquest_journals_2284134153 |
| source | Access via Wiley Online Library |
| subjects | Alkenes alternating copolymerization Catalysis Catalysts Copolymerization Cyclopentene Metathesis NHC ligand olefin metathesis Reagents ROMP Ruthenium ruthenium catalysts |
| title | Ruthenium‐Catalyzed Alternating Ring‐Opening Metathesis Copolymerization of Norborn‐2‐ene with Cyclic Olefins |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-16T18%3A47%3A15IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Ruthenium%E2%80%90Catalyzed%20Alternating%20Ring%E2%80%90Opening%20Metathesis%20Copolymerization%20of%20Norborn%E2%80%902%E2%80%90ene%20with%20Cyclic%20Olefins&rft.jtitle=Advanced%20synthesis%20&%20catalysis&rft.au=Paradiso,%20Veronica&rft.date=2019-09-03&rft.volume=361&rft.issue=17&rft.spage=4133&rft.epage=4139&rft.pages=4133-4139&rft.issn=1615-4150&rft.eissn=1615-4169&rft_id=info:doi/10.1002/adsc.201900565&rft_dat=%3Cproquest_cross%3E2284134153%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2284134153&rft_id=info:pmid/&rfr_iscdi=true |