Cobalt‐Catalyzed Transfer Hydrogenation of α‐Ketoesters and N‐Cyclicsulfonylimides Using H2O as Hydrogen Source
A Co‐catalyzed effective transfer hydrogenation of various α‐ketoesters and N‐cyclicsulfonylimides by safe and environmentally benign H2O as hydrogen source is described. The reaction used easily available and easy to handle zinc metal as a reductant. Interestingly, the catalytic system does not req...
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| Veröffentlicht in: | Advanced synthesis & catalysis 2019-09, Vol.361 (17), p.3991-3997 |
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| container_issue | 17 |
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| container_title | Advanced synthesis & catalysis |
| container_volume | 361 |
| creator | Gao, Yang Zhang, Xuexin Laishram, Ronibala Devi Chen, Jingchao Li, Kangkui Zhang, Keyang Zeng, Guangzhi Fan, Baomin |
| description | A Co‐catalyzed effective transfer hydrogenation of various α‐ketoesters and N‐cyclicsulfonylimides by safe and environmentally benign H2O as hydrogen source is described. The reaction used easily available and easy to handle zinc metal as a reductant. Interestingly, the catalytic system does not require ligand for reduction of N‐cyclicsulfonylimides. |
| doi_str_mv | 10.1002/adsc.201900636 |
| format | Article |
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| subjects | Catalysis Hydrogen storage Hydrogenation N-Cyclicsulfonylimides Transfer deuteriation Transfer hydrogenation Water α-Hydroxyester α-Ketoesters |
| title | Cobalt‐Catalyzed Transfer Hydrogenation of α‐Ketoesters and N‐Cyclicsulfonylimides Using H2O as Hydrogen Source |
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