Metal organic framework doped Spiro-OMeTAD with increased conductivity for improving perovskite solar cell performance
[Display omitted] •[In0.5K(3-qlc)Cl1.5(H2O)0.5]2n (In10) is firstly used to oxidize Spiro-OMeTAD.•The film presented improved conductivity, enhanced charge transport.•The modified PSCs exhibit improved efficiency (14.1–17.0%). In this work, a metal–organic framework, namely, [In0.5K(3-qlc)Cl1.5(H2O)...
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Veröffentlicht in: | Solar energy 2019-08, Vol.188, p.380-385 |
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creator | Li, Mengru Wang, Jiaqi Jiang, Aifeng Xia, Debin Du, Xi Dong, Yayu Wang, Ping Fan, Ruiqing Yang, Yulin |
description | [Display omitted]
•[In0.5K(3-qlc)Cl1.5(H2O)0.5]2n (In10) is firstly used to oxidize Spiro-OMeTAD.•The film presented improved conductivity, enhanced charge transport.•The modified PSCs exhibit improved efficiency (14.1–17.0%).
In this work, a metal–organic framework, namely, [In0.5K(3-qlc)Cl1.5(H2O)0.5]2n, (In10) is first incorporated into 2,2′,7,7′-tetrakis(N,N′-di-p-methoxyphenylamine)-9,9′-spirobifluorene (Spiro-OMeTAD). Through the simple and effective strategy, Spiro-OMeTAD oxidation is achieved and the conductivity of corresponding hole transport layer is increased, which favors the charge transport and suppresses charge recombination of perovskite solar cells (PSCs). Besides, due to the intense visible photoluminescence feature of In10, its addition can enhance the light response of perovskite solar cell. Furthermore, the modified PSCs exhibit an obviously improved device performance with short-current density (Jsc), open circuit voltage (Voc), and fill factor (FF) increasing from 22.7 to 24.3 mA cm−2, 0.95 to 1.0 V, and 0.65 to 0.70, respectively. As a result, the power conversion efficiency (PCE) exhibits 20% enhancement from 14.1 to 17.0%. |
doi_str_mv | 10.1016/j.solener.2019.05.078 |
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•[In0.5K(3-qlc)Cl1.5(H2O)0.5]2n (In10) is firstly used to oxidize Spiro-OMeTAD.•The film presented improved conductivity, enhanced charge transport.•The modified PSCs exhibit improved efficiency (14.1–17.0%).
In this work, a metal–organic framework, namely, [In0.5K(3-qlc)Cl1.5(H2O)0.5]2n, (In10) is first incorporated into 2,2′,7,7′-tetrakis(N,N′-di-p-methoxyphenylamine)-9,9′-spirobifluorene (Spiro-OMeTAD). Through the simple and effective strategy, Spiro-OMeTAD oxidation is achieved and the conductivity of corresponding hole transport layer is increased, which favors the charge transport and suppresses charge recombination of perovskite solar cells (PSCs). Besides, due to the intense visible photoluminescence feature of In10, its addition can enhance the light response of perovskite solar cell. Furthermore, the modified PSCs exhibit an obviously improved device performance with short-current density (Jsc), open circuit voltage (Voc), and fill factor (FF) increasing from 22.7 to 24.3 mA cm−2, 0.95 to 1.0 V, and 0.65 to 0.70, respectively. As a result, the power conversion efficiency (PCE) exhibits 20% enhancement from 14.1 to 17.0%.</description><identifier>ISSN: 0038-092X</identifier><identifier>EISSN: 1471-1257</identifier><identifier>DOI: 10.1016/j.solener.2019.05.078</identifier><language>eng</language><publisher>New York: Elsevier Ltd</publisher><subject>[In0.5K(3-qlc)Cl1.5(H2O)0.5]2n ; Charge transport ; Circuits ; Conductivity ; Energy conversion efficiency ; Light effects ; Metal organic frameworks ; Metals ; Open circuit voltage ; Oxidation ; Perovskite solar cell ; Perovskites ; Photoluminescence ; Photons ; Photovoltaic cells ; Recombination ; Solar cells ; Solar energy ; Spiro-OMeTAD</subject><ispartof>Solar energy, 2019-08, Vol.188, p.380-385</ispartof><rights>2019 International Solar Energy Society</rights><rights>Copyright Pergamon Press Inc. Aug 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c376t-400abd0fe48c51501f690f341809ac6c22f960764b6236f4eb922539c457b7973</citedby><cites>FETCH-LOGICAL-c376t-400abd0fe48c51501f690f341809ac6c22f960764b6236f4eb922539c457b7973</cites><orcidid>0000-0002-5461-9672 ; 0000-0002-2108-662X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.solener.2019.05.078$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Li, Mengru</creatorcontrib><creatorcontrib>Wang, Jiaqi</creatorcontrib><creatorcontrib>Jiang, Aifeng</creatorcontrib><creatorcontrib>Xia, Debin</creatorcontrib><creatorcontrib>Du, Xi</creatorcontrib><creatorcontrib>Dong, Yayu</creatorcontrib><creatorcontrib>Wang, Ping</creatorcontrib><creatorcontrib>Fan, Ruiqing</creatorcontrib><creatorcontrib>Yang, Yulin</creatorcontrib><title>Metal organic framework doped Spiro-OMeTAD with increased conductivity for improving perovskite solar cell performance</title><title>Solar energy</title><description>[Display omitted]
•[In0.5K(3-qlc)Cl1.5(H2O)0.5]2n (In10) is firstly used to oxidize Spiro-OMeTAD.•The film presented improved conductivity, enhanced charge transport.•The modified PSCs exhibit improved efficiency (14.1–17.0%).
In this work, a metal–organic framework, namely, [In0.5K(3-qlc)Cl1.5(H2O)0.5]2n, (In10) is first incorporated into 2,2′,7,7′-tetrakis(N,N′-di-p-methoxyphenylamine)-9,9′-spirobifluorene (Spiro-OMeTAD). Through the simple and effective strategy, Spiro-OMeTAD oxidation is achieved and the conductivity of corresponding hole transport layer is increased, which favors the charge transport and suppresses charge recombination of perovskite solar cells (PSCs). Besides, due to the intense visible photoluminescence feature of In10, its addition can enhance the light response of perovskite solar cell. Furthermore, the modified PSCs exhibit an obviously improved device performance with short-current density (Jsc), open circuit voltage (Voc), and fill factor (FF) increasing from 22.7 to 24.3 mA cm−2, 0.95 to 1.0 V, and 0.65 to 0.70, respectively. As a result, the power conversion efficiency (PCE) exhibits 20% enhancement from 14.1 to 17.0%.</description><subject>[In0.5K(3-qlc)Cl1.5(H2O)0.5]2n</subject><subject>Charge transport</subject><subject>Circuits</subject><subject>Conductivity</subject><subject>Energy conversion efficiency</subject><subject>Light effects</subject><subject>Metal organic frameworks</subject><subject>Metals</subject><subject>Open circuit voltage</subject><subject>Oxidation</subject><subject>Perovskite solar cell</subject><subject>Perovskites</subject><subject>Photoluminescence</subject><subject>Photons</subject><subject>Photovoltaic cells</subject><subject>Recombination</subject><subject>Solar cells</subject><subject>Solar energy</subject><subject>Spiro-OMeTAD</subject><issn>0038-092X</issn><issn>1471-1257</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFUMtOwzAQtBBIlMcnIFninLB2Ejs5IVSeUisOgMTNcp01uKRxsNMi_h5X7Z3TrnZnZneGkAsGOQMmrpZ59B32GHIOrMmhykHWB2TCSskyxit5SCYARZ1Bw9-PyUmMSwAmWS0nZDPHUXfUhw_dO0Nt0Cv88eGLtn7Alr4MLvjseY6vN7f0x42f1PUmoI5pZ3zfrs3oNm78pdYH6lZD8BvXf9ABUxO_3Ig0vaYDNdh122mCrXRv8IwcWd1FPN_XU_J2f_c6fcxmzw9P05tZZgopxqwE0IsWLJa1qVgFzIoGbFGyGhpthOHcNgKkKBeCF8KWuGg4r4rGlJVcyEYWp-Ryp5s--15jHNXSr0OfTirO6yLlJEAkVLVDmeBjDGjVENxKh1_FQG0jVku1j1htI1ZQqURNvOsdD5OFjUvbaBwme60LaEbVevePwh9oKYkf</recordid><startdate>20190801</startdate><enddate>20190801</enddate><creator>Li, Mengru</creator><creator>Wang, Jiaqi</creator><creator>Jiang, Aifeng</creator><creator>Xia, Debin</creator><creator>Du, Xi</creator><creator>Dong, Yayu</creator><creator>Wang, Ping</creator><creator>Fan, Ruiqing</creator><creator>Yang, Yulin</creator><general>Elsevier Ltd</general><general>Pergamon Press Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7ST</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>KR7</scope><scope>L7M</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0002-5461-9672</orcidid><orcidid>https://orcid.org/0000-0002-2108-662X</orcidid></search><sort><creationdate>20190801</creationdate><title>Metal organic framework doped Spiro-OMeTAD with increased conductivity for improving perovskite solar cell performance</title><author>Li, Mengru ; Wang, Jiaqi ; Jiang, Aifeng ; Xia, Debin ; Du, Xi ; Dong, Yayu ; Wang, Ping ; Fan, Ruiqing ; Yang, Yulin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c376t-400abd0fe48c51501f690f341809ac6c22f960764b6236f4eb922539c457b7973</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>[In0.5K(3-qlc)Cl1.5(H2O)0.5]2n</topic><topic>Charge transport</topic><topic>Circuits</topic><topic>Conductivity</topic><topic>Energy conversion efficiency</topic><topic>Light effects</topic><topic>Metal organic frameworks</topic><topic>Metals</topic><topic>Open circuit voltage</topic><topic>Oxidation</topic><topic>Perovskite solar cell</topic><topic>Perovskites</topic><topic>Photoluminescence</topic><topic>Photons</topic><topic>Photovoltaic cells</topic><topic>Recombination</topic><topic>Solar cells</topic><topic>Solar energy</topic><topic>Spiro-OMeTAD</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Mengru</creatorcontrib><creatorcontrib>Wang, Jiaqi</creatorcontrib><creatorcontrib>Jiang, Aifeng</creatorcontrib><creatorcontrib>Xia, Debin</creatorcontrib><creatorcontrib>Du, Xi</creatorcontrib><creatorcontrib>Dong, Yayu</creatorcontrib><creatorcontrib>Wang, Ping</creatorcontrib><creatorcontrib>Fan, Ruiqing</creatorcontrib><creatorcontrib>Yang, Yulin</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Environment Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><jtitle>Solar energy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Mengru</au><au>Wang, Jiaqi</au><au>Jiang, Aifeng</au><au>Xia, Debin</au><au>Du, Xi</au><au>Dong, Yayu</au><au>Wang, Ping</au><au>Fan, Ruiqing</au><au>Yang, Yulin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Metal organic framework doped Spiro-OMeTAD with increased conductivity for improving perovskite solar cell performance</atitle><jtitle>Solar energy</jtitle><date>2019-08-01</date><risdate>2019</risdate><volume>188</volume><spage>380</spage><epage>385</epage><pages>380-385</pages><issn>0038-092X</issn><eissn>1471-1257</eissn><abstract>[Display omitted]
•[In0.5K(3-qlc)Cl1.5(H2O)0.5]2n (In10) is firstly used to oxidize Spiro-OMeTAD.•The film presented improved conductivity, enhanced charge transport.•The modified PSCs exhibit improved efficiency (14.1–17.0%).
In this work, a metal–organic framework, namely, [In0.5K(3-qlc)Cl1.5(H2O)0.5]2n, (In10) is first incorporated into 2,2′,7,7′-tetrakis(N,N′-di-p-methoxyphenylamine)-9,9′-spirobifluorene (Spiro-OMeTAD). Through the simple and effective strategy, Spiro-OMeTAD oxidation is achieved and the conductivity of corresponding hole transport layer is increased, which favors the charge transport and suppresses charge recombination of perovskite solar cells (PSCs). Besides, due to the intense visible photoluminescence feature of In10, its addition can enhance the light response of perovskite solar cell. Furthermore, the modified PSCs exhibit an obviously improved device performance with short-current density (Jsc), open circuit voltage (Voc), and fill factor (FF) increasing from 22.7 to 24.3 mA cm−2, 0.95 to 1.0 V, and 0.65 to 0.70, respectively. As a result, the power conversion efficiency (PCE) exhibits 20% enhancement from 14.1 to 17.0%.</abstract><cop>New York</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.solener.2019.05.078</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-5461-9672</orcidid><orcidid>https://orcid.org/0000-0002-2108-662X</orcidid></addata></record> |
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subjects | [In0.5K(3-qlc)Cl1.5(H2O)0.5]2n Charge transport Circuits Conductivity Energy conversion efficiency Light effects Metal organic frameworks Metals Open circuit voltage Oxidation Perovskite solar cell Perovskites Photoluminescence Photons Photovoltaic cells Recombination Solar cells Solar energy Spiro-OMeTAD |
title | Metal organic framework doped Spiro-OMeTAD with increased conductivity for improving perovskite solar cell performance |
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