Metal organic framework doped Spiro-OMeTAD with increased conductivity for improving perovskite solar cell performance

[Display omitted] •[In0.5K(3-qlc)Cl1.5(H2O)0.5]2n (In10) is firstly used to oxidize Spiro-OMeTAD.•The film presented improved conductivity, enhanced charge transport.•The modified PSCs exhibit improved efficiency (14.1–17.0%). In this work, a metal–organic framework, namely, [In0.5K(3-qlc)Cl1.5(H2O)...

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Veröffentlicht in:Solar energy 2019-08, Vol.188, p.380-385
Hauptverfasser: Li, Mengru, Wang, Jiaqi, Jiang, Aifeng, Xia, Debin, Du, Xi, Dong, Yayu, Wang, Ping, Fan, Ruiqing, Yang, Yulin
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container_end_page 385
container_issue
container_start_page 380
container_title Solar energy
container_volume 188
creator Li, Mengru
Wang, Jiaqi
Jiang, Aifeng
Xia, Debin
Du, Xi
Dong, Yayu
Wang, Ping
Fan, Ruiqing
Yang, Yulin
description [Display omitted] •[In0.5K(3-qlc)Cl1.5(H2O)0.5]2n (In10) is firstly used to oxidize Spiro-OMeTAD.•The film presented improved conductivity, enhanced charge transport.•The modified PSCs exhibit improved efficiency (14.1–17.0%). In this work, a metal–organic framework, namely, [In0.5K(3-qlc)Cl1.5(H2O)0.5]2n, (In10) is first incorporated into 2,2′,7,7′-tetrakis(N,N′-di-p-methoxyphenylamine)-9,9′-spirobifluorene (Spiro-OMeTAD). Through the simple and effective strategy, Spiro-OMeTAD oxidation is achieved and the conductivity of corresponding hole transport layer is increased, which favors the charge transport and suppresses charge recombination of perovskite solar cells (PSCs). Besides, due to the intense visible photoluminescence feature of In10, its addition can enhance the light response of perovskite solar cell. Furthermore, the modified PSCs exhibit an obviously improved device performance with short-current density (Jsc), open circuit voltage (Voc), and fill factor (FF) increasing from 22.7 to 24.3 mA cm−2, 0.95 to 1.0 V, and 0.65 to 0.70, respectively. As a result, the power conversion efficiency (PCE) exhibits 20% enhancement from 14.1 to 17.0%.
doi_str_mv 10.1016/j.solener.2019.05.078
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In this work, a metal–organic framework, namely, [In0.5K(3-qlc)Cl1.5(H2O)0.5]2n, (In10) is first incorporated into 2,2′,7,7′-tetrakis(N,N′-di-p-methoxyphenylamine)-9,9′-spirobifluorene (Spiro-OMeTAD). Through the simple and effective strategy, Spiro-OMeTAD oxidation is achieved and the conductivity of corresponding hole transport layer is increased, which favors the charge transport and suppresses charge recombination of perovskite solar cells (PSCs). Besides, due to the intense visible photoluminescence feature of In10, its addition can enhance the light response of perovskite solar cell. Furthermore, the modified PSCs exhibit an obviously improved device performance with short-current density (Jsc), open circuit voltage (Voc), and fill factor (FF) increasing from 22.7 to 24.3 mA cm−2, 0.95 to 1.0 V, and 0.65 to 0.70, respectively. As a result, the power conversion efficiency (PCE) exhibits 20% enhancement from 14.1 to 17.0%.</description><identifier>ISSN: 0038-092X</identifier><identifier>EISSN: 1471-1257</identifier><identifier>DOI: 10.1016/j.solener.2019.05.078</identifier><language>eng</language><publisher>New York: Elsevier Ltd</publisher><subject>[In0.5K(3-qlc)Cl1.5(H2O)0.5]2n ; Charge transport ; Circuits ; Conductivity ; Energy conversion efficiency ; Light effects ; Metal organic frameworks ; Metals ; Open circuit voltage ; Oxidation ; Perovskite solar cell ; Perovskites ; Photoluminescence ; Photons ; Photovoltaic cells ; Recombination ; Solar cells ; Solar energy ; Spiro-OMeTAD</subject><ispartof>Solar energy, 2019-08, Vol.188, p.380-385</ispartof><rights>2019 International Solar Energy Society</rights><rights>Copyright Pergamon Press Inc. 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In this work, a metal–organic framework, namely, [In0.5K(3-qlc)Cl1.5(H2O)0.5]2n, (In10) is first incorporated into 2,2′,7,7′-tetrakis(N,N′-di-p-methoxyphenylamine)-9,9′-spirobifluorene (Spiro-OMeTAD). Through the simple and effective strategy, Spiro-OMeTAD oxidation is achieved and the conductivity of corresponding hole transport layer is increased, which favors the charge transport and suppresses charge recombination of perovskite solar cells (PSCs). Besides, due to the intense visible photoluminescence feature of In10, its addition can enhance the light response of perovskite solar cell. Furthermore, the modified PSCs exhibit an obviously improved device performance with short-current density (Jsc), open circuit voltage (Voc), and fill factor (FF) increasing from 22.7 to 24.3 mA cm−2, 0.95 to 1.0 V, and 0.65 to 0.70, respectively. 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In this work, a metal–organic framework, namely, [In0.5K(3-qlc)Cl1.5(H2O)0.5]2n, (In10) is first incorporated into 2,2′,7,7′-tetrakis(N,N′-di-p-methoxyphenylamine)-9,9′-spirobifluorene (Spiro-OMeTAD). Through the simple and effective strategy, Spiro-OMeTAD oxidation is achieved and the conductivity of corresponding hole transport layer is increased, which favors the charge transport and suppresses charge recombination of perovskite solar cells (PSCs). Besides, due to the intense visible photoluminescence feature of In10, its addition can enhance the light response of perovskite solar cell. Furthermore, the modified PSCs exhibit an obviously improved device performance with short-current density (Jsc), open circuit voltage (Voc), and fill factor (FF) increasing from 22.7 to 24.3 mA cm−2, 0.95 to 1.0 V, and 0.65 to 0.70, respectively. 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subjects [In0.5K(3-qlc)Cl1.5(H2O)0.5]2n
Charge transport
Circuits
Conductivity
Energy conversion efficiency
Light effects
Metal organic frameworks
Metals
Open circuit voltage
Oxidation
Perovskite solar cell
Perovskites
Photoluminescence
Photons
Photovoltaic cells
Recombination
Solar cells
Solar energy
Spiro-OMeTAD
title Metal organic framework doped Spiro-OMeTAD with increased conductivity for improving perovskite solar cell performance
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