Selective oxidation of methane with H2O2 over Fe-silicalite-1: An investigation of the influence of crystal sizes, calcination temperatures and acidities

[Display omitted] •A crystal size around 400 nm was preferable as diffusion limitations occur in the secondary particle (200 μm) when crystal size is below 400 nm.•Increasing calcination temperatures led to a growing fraction of extra-framework Fe species.•Extra-framework Fe species are responsible...

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Veröffentlicht in:	Applied catalysis. A, General General, 2019-08, Vol.583, p.117121, Article 117121
Hauptverfasser:	Zuo, Hualiang, Klemm, Elias
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalysts Crystals Decomposition Fe-silicalite-1 Hydrogen peroxide Methane Micro reactor Oxidation Roasting Selective oxidation Silicalite
Online-Zugang:	Volltext
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