A Highly Active, Recyclable and Cost-Effective Magnetic Nanoparticles Supported Copper Catalyst for N-arylation Reaction
The immobilization of a copper complex by covalent anchoring of 2-hydroxybenzophenone on the surface of amine-functionalized magnetic nanoparticles was reported. The structure and morphology of the catalyst was characterized by different techniques such as Fourier-transform infrared spectroscopy (FT...
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| Veröffentlicht in: | Catalysis letters 2020, Vol.150 (1), p.65-73 |
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| creator | Zahedi, Razieh Asadi, Zahra Firuzabadi, Fahimeh Dehghani |
| description | The immobilization of a copper complex by covalent anchoring of 2-hydroxybenzophenone on the surface of amine-functionalized magnetic nanoparticles was reported. The structure and morphology of the catalyst was characterized by different techniques such as Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), transmission electron micrograph (TEM), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), vibrating sample magnetometer (VSM) and inductively coupled plasma (ICP) spectroscopy. This efficient and cost effective catalyst was applied in the N-arylation reaction and the products were obtained in good to excellent yields in short reaction times. The cost-effective catalyst demonstrated high stability, which could be facilely separated from the reaction mixture by applying an external magnet and recycled at least four times with only a slight decrease in its activity.
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| doi_str_mv | 10.1007/s10562-019-02929-x |
| format | Article |
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Graphic Abstract</description><subject>Anchoring</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination compounds</subject><subject>Copper</subject><subject>Copper compounds</subject><subject>Diffraction</subject><subject>Economic aspects</subject><subject>Electron micrographs</subject><subject>Energy transmission</subject><subject>Fourier transforms</subject><subject>Inductively coupled plasma</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Infrared spectroscopy</subject><subject>Morphology</subject><subject>Nanoparticles</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><subject>Spectrum analysis</subject><subject>X-ray spectroscopy</subject><subject>X-rays</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kV9rHCEUxYfSQtNtvkCehD4VaqKOo-vjsqRNIH8gyUPe5I57nU6YjFN1w-63r5splLwEHzzo75wrnqo64eyUM6bPEmeNEpRxQ5kwwtDdh-qIN1rQpTaPH4tmnNNai8fP1ZeUnhhjRnNzVO1W5KLvfg97snK5f8Ef5A7d3g3QDkhg3JB1SJmee4-v1-QauhFz78gNjGGCWOSAidxvpynEjAd-mjCSNWQY9ikTHyK5oRD3A-Q-jCUe3EF8rT55GBIe_9sX1cPP84f1Bb26_XW5Xl1RJ4XJtFWyWbatbhojVe2k4QKlcABeclXLVqEEvwRRNw3X0rSgtRdeGY2q0WZTL6pvc-wUw58tpmyfwjaOZaIVQitlal1yF9XpTHUwoO1HH3IEV9YGn3sXRvR9OV8pzpZaSn0wfH9jKEzGXe5gm5K9vL97y4qZdTGkFNHbKfbP5UcsZ_bQnp3bs6U9-9qe3RVTPZtSgccO4_93v-P6CwPmnQw</recordid><startdate>2020</startdate><enddate>2020</enddate><creator>Zahedi, Razieh</creator><creator>Asadi, Zahra</creator><creator>Firuzabadi, Fahimeh Dehghani</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>2020</creationdate><title>A Highly Active, Recyclable and Cost-Effective Magnetic Nanoparticles Supported Copper Catalyst for N-arylation Reaction</title><author>Zahedi, Razieh ; Asadi, Zahra ; Firuzabadi, Fahimeh Dehghani</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c429t-b6458bb7559463c4912e42caaf41634b6e4af8a23551749ba77f2f697e6579d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Anchoring</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination compounds</topic><topic>Copper</topic><topic>Copper compounds</topic><topic>Diffraction</topic><topic>Economic aspects</topic><topic>Electron micrographs</topic><topic>Energy transmission</topic><topic>Fourier transforms</topic><topic>Inductively coupled plasma</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Infrared spectroscopy</topic><topic>Morphology</topic><topic>Nanoparticles</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><topic>Spectrum analysis</topic><topic>X-ray spectroscopy</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zahedi, Razieh</creatorcontrib><creatorcontrib>Asadi, Zahra</creatorcontrib><creatorcontrib>Firuzabadi, Fahimeh Dehghani</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zahedi, Razieh</au><au>Asadi, Zahra</au><au>Firuzabadi, Fahimeh Dehghani</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Highly Active, Recyclable and Cost-Effective Magnetic Nanoparticles Supported Copper Catalyst for N-arylation Reaction</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2020</date><risdate>2020</risdate><volume>150</volume><issue>1</issue><spage>65</spage><epage>73</epage><pages>65-73</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>The immobilization of a copper complex by covalent anchoring of 2-hydroxybenzophenone on the surface of amine-functionalized magnetic nanoparticles was reported. The structure and morphology of the catalyst was characterized by different techniques such as Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), transmission electron micrograph (TEM), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), vibrating sample magnetometer (VSM) and inductively coupled plasma (ICP) spectroscopy. This efficient and cost effective catalyst was applied in the N-arylation reaction and the products were obtained in good to excellent yields in short reaction times. The cost-effective catalyst demonstrated high stability, which could be facilely separated from the reaction mixture by applying an external magnet and recycled at least four times with only a slight decrease in its activity.
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| subjects | Anchoring Catalysis Catalysts Chemistry Chemistry and Materials Science Coordination compounds Copper Copper compounds Diffraction Economic aspects Electron micrographs Energy transmission Fourier transforms Inductively coupled plasma Industrial Chemistry/Chemical Engineering Infrared spectroscopy Morphology Nanoparticles Organometallic Chemistry Physical Chemistry Spectrum analysis X-ray spectroscopy X-rays |
| title | A Highly Active, Recyclable and Cost-Effective Magnetic Nanoparticles Supported Copper Catalyst for N-arylation Reaction |
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