Formation of Five-Membered Carbocycles from d-Glucose: A Concise Synthesis of 4-Hydroxy-2-(hydroxymethyl)cyclopentenone

A concise synthesis of 4-hydroxy-2-(hydroxymethyl)cyclopentenone (1) has been accomplished from d-glucose by a three-step sequence that features a catalyst-free hydrothermal reaction of d-glucal, which is readily obtained from d-glucose. Optimization of the reaction conditions for synthesizing 1 was...

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Veröffentlicht in:	Bulletin of the Chemical Society of Japan 2019, Vol.92 (8), p.1324-1328
Hauptverfasser:	Koseki, Yoshitaka, Watanabe, Toshihiro, Kamishima, Takaaki, Kwon, Eunsang, Kasai, Hitoshi
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical synthesis Fine chemicals Glucose Hydrothermal reactions Optimization Organic chemistry Reaction time
Online-Zugang:	Volltext
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