Preparation of Nb2O5 with an air filter-like structure and its excellent electrochemical performance in supercapacitors
A Nb2O5 compound with a structure similar to an air filter (AF-Nb2O5) was synthesized using a hydrothermal method, and further calcined to form a product that was designated CAF-Nb2O5. The morphology and microstructure of the AF-Nb2O5 and CAF-Nb2O5 were examined using X-ray diffraction, scanning ele...
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Veröffentlicht in: | Journal of alloys and compounds 2019-09, Vol.802, p.668-674 |
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creator | Liu, Jingqiang Xiang, Kaixiong Zhou, Wei Zhu, Yirong Xiao, Li Chen, Wenhao Chen, Han |
description | A Nb2O5 compound with a structure similar to an air filter (AF-Nb2O5) was synthesized using a hydrothermal method, and further calcined to form a product that was designated CAF-Nb2O5. The morphology and microstructure of the AF-Nb2O5 and CAF-Nb2O5 were examined using X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The AF-Nb2O5 and CAF-Nb2O5 exhibited similar filter-like structures, which consisted of regular pores and ordered networks. The CAF-Nb2O5 exhibited a high specific capacitance of 258 F g−1 at a current density of 0.5 A g−1, an excellent rate capacity of 172 F g−1 at the high current density of 5 A g−1 and an impressive capacitance retention of 90.5% after 5000 cycles at the current density of 2 A g−1. The CAF-Nb2O5 exhibited excellent electrochemical properties by virtue of its abundance of ion channels and its filter-like structure.
•A novel structured Nb2O5 was achieved by hydrothermal method.•The novel structure is similar to air filter.•The air filter-like Nb2O5 is an ideal electrode material for supercapacitors.•The air filter-like Nb2O5 exhibits the excellent electrochemical performance. |
doi_str_mv | 10.1016/j.jallcom.2019.06.191 |
format | Article |
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•A novel structured Nb2O5 was achieved by hydrothermal method.•The novel structure is similar to air filter.•The air filter-like Nb2O5 is an ideal electrode material for supercapacitors.•The air filter-like Nb2O5 exhibits the excellent electrochemical performance.</description><identifier>ISSN: 0925-8388</identifier><identifier>EISSN: 1873-4669</identifier><identifier>DOI: 10.1016/j.jallcom.2019.06.191</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Air filters ; Capacitance ; Current density ; Electrochemical analysis ; Electrochemical performance ; Electron microscopes ; Electron microscopy ; Hydrothermal method ; Ion channels ; Microscopy ; Morphology ; Niobium oxides ; Niobium pentoxide ; Supercapacitor</subject><ispartof>Journal of alloys and compounds, 2019-09, Vol.802, p.668-674</ispartof><rights>2019 Elsevier B.V.</rights><rights>Copyright Elsevier BV Sep 25, 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c376t-c325111aba79bf411524e4b822c1d10b13490d92ed9dd918254e34d4520acb913</citedby><cites>FETCH-LOGICAL-c376t-c325111aba79bf411524e4b822c1d10b13490d92ed9dd918254e34d4520acb913</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S092583881932273X$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Liu, Jingqiang</creatorcontrib><creatorcontrib>Xiang, Kaixiong</creatorcontrib><creatorcontrib>Zhou, Wei</creatorcontrib><creatorcontrib>Zhu, Yirong</creatorcontrib><creatorcontrib>Xiao, Li</creatorcontrib><creatorcontrib>Chen, Wenhao</creatorcontrib><creatorcontrib>Chen, Han</creatorcontrib><title>Preparation of Nb2O5 with an air filter-like structure and its excellent electrochemical performance in supercapacitors</title><title>Journal of alloys and compounds</title><description>A Nb2O5 compound with a structure similar to an air filter (AF-Nb2O5) was synthesized using a hydrothermal method, and further calcined to form a product that was designated CAF-Nb2O5. The morphology and microstructure of the AF-Nb2O5 and CAF-Nb2O5 were examined using X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The AF-Nb2O5 and CAF-Nb2O5 exhibited similar filter-like structures, which consisted of regular pores and ordered networks. The CAF-Nb2O5 exhibited a high specific capacitance of 258 F g−1 at a current density of 0.5 A g−1, an excellent rate capacity of 172 F g−1 at the high current density of 5 A g−1 and an impressive capacitance retention of 90.5% after 5000 cycles at the current density of 2 A g−1. The CAF-Nb2O5 exhibited excellent electrochemical properties by virtue of its abundance of ion channels and its filter-like structure.
•A novel structured Nb2O5 was achieved by hydrothermal method.•The novel structure is similar to air filter.•The air filter-like Nb2O5 is an ideal electrode material for supercapacitors.•The air filter-like Nb2O5 exhibits the excellent electrochemical performance.</description><subject>Air filters</subject><subject>Capacitance</subject><subject>Current density</subject><subject>Electrochemical analysis</subject><subject>Electrochemical performance</subject><subject>Electron microscopes</subject><subject>Electron microscopy</subject><subject>Hydrothermal method</subject><subject>Ion channels</subject><subject>Microscopy</subject><subject>Morphology</subject><subject>Niobium oxides</subject><subject>Niobium pentoxide</subject><subject>Supercapacitor</subject><issn>0925-8388</issn><issn>1873-4669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkM1u1TAQhS0EEpfSR0CyxDrBYzs_XiFUQUGqWhZ0bTn2RHXwjYPt0PbtcbnddzMjzZw5o_MR8gFYCwz6T0u7mBBsPLacgWpZ34KCV-QA4yAa2ffqNTkwxbtmFOP4lrzLeWGsKgUcyP3PhJtJpvi40jjT64nfdPTelztqVmp8orMPBVMT_G-kuaTdlj1hXTrqS6b4YDEEXAvFgLakaO_w6K0JdMM0x3Q0q0XqV5r3OrBmM9aXmPJ78mY2IeP5cz8jt9--_rr43lzdXP64-HLVWDH0pVbeAYCZzKCmWQJ0XKKcRs4tOGATCKmYUxydck7ByDuJQjrZcWbspECckY8n3y3FPzvmope4p7W-1JwPYpAgxr6qupPKpphzwllvyR9NetTA9BNjvehnxvqJsWa9hv_un093WCP89Zh0th5rYudTpaFd9C84_AN0Nok4</recordid><startdate>20190925</startdate><enddate>20190925</enddate><creator>Liu, Jingqiang</creator><creator>Xiang, Kaixiong</creator><creator>Zhou, Wei</creator><creator>Zhu, Yirong</creator><creator>Xiao, Li</creator><creator>Chen, Wenhao</creator><creator>Chen, Han</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20190925</creationdate><title>Preparation of Nb2O5 with an air filter-like structure and its excellent electrochemical performance in supercapacitors</title><author>Liu, Jingqiang ; Xiang, Kaixiong ; Zhou, Wei ; Zhu, Yirong ; Xiao, Li ; Chen, Wenhao ; Chen, Han</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c376t-c325111aba79bf411524e4b822c1d10b13490d92ed9dd918254e34d4520acb913</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Air filters</topic><topic>Capacitance</topic><topic>Current density</topic><topic>Electrochemical analysis</topic><topic>Electrochemical performance</topic><topic>Electron microscopes</topic><topic>Electron microscopy</topic><topic>Hydrothermal method</topic><topic>Ion channels</topic><topic>Microscopy</topic><topic>Morphology</topic><topic>Niobium oxides</topic><topic>Niobium pentoxide</topic><topic>Supercapacitor</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Jingqiang</creatorcontrib><creatorcontrib>Xiang, Kaixiong</creatorcontrib><creatorcontrib>Zhou, Wei</creatorcontrib><creatorcontrib>Zhu, Yirong</creatorcontrib><creatorcontrib>Xiao, Li</creatorcontrib><creatorcontrib>Chen, Wenhao</creatorcontrib><creatorcontrib>Chen, Han</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of alloys and compounds</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Jingqiang</au><au>Xiang, Kaixiong</au><au>Zhou, Wei</au><au>Zhu, Yirong</au><au>Xiao, Li</au><au>Chen, Wenhao</au><au>Chen, Han</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of Nb2O5 with an air filter-like structure and its excellent electrochemical performance in supercapacitors</atitle><jtitle>Journal of alloys and compounds</jtitle><date>2019-09-25</date><risdate>2019</risdate><volume>802</volume><spage>668</spage><epage>674</epage><pages>668-674</pages><issn>0925-8388</issn><eissn>1873-4669</eissn><abstract>A Nb2O5 compound with a structure similar to an air filter (AF-Nb2O5) was synthesized using a hydrothermal method, and further calcined to form a product that was designated CAF-Nb2O5. The morphology and microstructure of the AF-Nb2O5 and CAF-Nb2O5 were examined using X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The AF-Nb2O5 and CAF-Nb2O5 exhibited similar filter-like structures, which consisted of regular pores and ordered networks. The CAF-Nb2O5 exhibited a high specific capacitance of 258 F g−1 at a current density of 0.5 A g−1, an excellent rate capacity of 172 F g−1 at the high current density of 5 A g−1 and an impressive capacitance retention of 90.5% after 5000 cycles at the current density of 2 A g−1. The CAF-Nb2O5 exhibited excellent electrochemical properties by virtue of its abundance of ion channels and its filter-like structure.
•A novel structured Nb2O5 was achieved by hydrothermal method.•The novel structure is similar to air filter.•The air filter-like Nb2O5 is an ideal electrode material for supercapacitors.•The air filter-like Nb2O5 exhibits the excellent electrochemical performance.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jallcom.2019.06.191</doi><tpages>7</tpages></addata></record> |
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subjects | Air filters Capacitance Current density Electrochemical analysis Electrochemical performance Electron microscopes Electron microscopy Hydrothermal method Ion channels Microscopy Morphology Niobium oxides Niobium pentoxide Supercapacitor |
title | Preparation of Nb2O5 with an air filter-like structure and its excellent electrochemical performance in supercapacitors |
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