Preparation of Nb2O5 with an air filter-like structure and its excellent electrochemical performance in supercapacitors

A Nb2O5 compound with a structure similar to an air filter (AF-Nb2O5) was synthesized using a hydrothermal method, and further calcined to form a product that was designated CAF-Nb2O5. The morphology and microstructure of the AF-Nb2O5 and CAF-Nb2O5 were examined using X-ray diffraction, scanning ele...

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Veröffentlicht in:Journal of alloys and compounds 2019-09, Vol.802, p.668-674
Hauptverfasser: Liu, Jingqiang, Xiang, Kaixiong, Zhou, Wei, Zhu, Yirong, Xiao, Li, Chen, Wenhao, Chen, Han
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container_end_page 674
container_issue
container_start_page 668
container_title Journal of alloys and compounds
container_volume 802
creator Liu, Jingqiang
Xiang, Kaixiong
Zhou, Wei
Zhu, Yirong
Xiao, Li
Chen, Wenhao
Chen, Han
description A Nb2O5 compound with a structure similar to an air filter (AF-Nb2O5) was synthesized using a hydrothermal method, and further calcined to form a product that was designated CAF-Nb2O5. The morphology and microstructure of the AF-Nb2O5 and CAF-Nb2O5 were examined using X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The AF-Nb2O5 and CAF-Nb2O5 exhibited similar filter-like structures, which consisted of regular pores and ordered networks. The CAF-Nb2O5 exhibited a high specific capacitance of 258 F g−1 at a current density of 0.5 A g−1, an excellent rate capacity of 172 F g−1 at the high current density of 5 A g−1 and an impressive capacitance retention of 90.5% after 5000 cycles at the current density of 2 A g−1. The CAF-Nb2O5 exhibited excellent electrochemical properties by virtue of its abundance of ion channels and its filter-like structure. •A novel structured Nb2O5 was achieved by hydrothermal method.•The novel structure is similar to air filter.•The air filter-like Nb2O5 is an ideal electrode material for supercapacitors.•The air filter-like Nb2O5 exhibits the excellent electrochemical performance.
doi_str_mv 10.1016/j.jallcom.2019.06.191
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The morphology and microstructure of the AF-Nb2O5 and CAF-Nb2O5 were examined using X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The AF-Nb2O5 and CAF-Nb2O5 exhibited similar filter-like structures, which consisted of regular pores and ordered networks. The CAF-Nb2O5 exhibited a high specific capacitance of 258 F g−1 at a current density of 0.5 A g−1, an excellent rate capacity of 172 F g−1 at the high current density of 5 A g−1 and an impressive capacitance retention of 90.5% after 5000 cycles at the current density of 2 A g−1. The CAF-Nb2O5 exhibited excellent electrochemical properties by virtue of its abundance of ion channels and its filter-like structure. •A novel structured Nb2O5 was achieved by hydrothermal method.•The novel structure is similar to air filter.•The air filter-like Nb2O5 is an ideal electrode material for supercapacitors.•The air filter-like Nb2O5 exhibits the excellent electrochemical performance.</description><identifier>ISSN: 0925-8388</identifier><identifier>EISSN: 1873-4669</identifier><identifier>DOI: 10.1016/j.jallcom.2019.06.191</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Air filters ; Capacitance ; Current density ; Electrochemical analysis ; Electrochemical performance ; Electron microscopes ; Electron microscopy ; Hydrothermal method ; Ion channels ; Microscopy ; Morphology ; Niobium oxides ; Niobium pentoxide ; Supercapacitor</subject><ispartof>Journal of alloys and compounds, 2019-09, Vol.802, p.668-674</ispartof><rights>2019 Elsevier B.V.</rights><rights>Copyright Elsevier BV Sep 25, 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c376t-c325111aba79bf411524e4b822c1d10b13490d92ed9dd918254e34d4520acb913</citedby><cites>FETCH-LOGICAL-c376t-c325111aba79bf411524e4b822c1d10b13490d92ed9dd918254e34d4520acb913</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S092583881932273X$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Liu, Jingqiang</creatorcontrib><creatorcontrib>Xiang, Kaixiong</creatorcontrib><creatorcontrib>Zhou, Wei</creatorcontrib><creatorcontrib>Zhu, Yirong</creatorcontrib><creatorcontrib>Xiao, Li</creatorcontrib><creatorcontrib>Chen, Wenhao</creatorcontrib><creatorcontrib>Chen, Han</creatorcontrib><title>Preparation of Nb2O5 with an air filter-like structure and its excellent electrochemical performance in supercapacitors</title><title>Journal of alloys and compounds</title><description>A Nb2O5 compound with a structure similar to an air filter (AF-Nb2O5) was synthesized using a hydrothermal method, and further calcined to form a product that was designated CAF-Nb2O5. 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The CAF-Nb2O5 exhibited excellent electrochemical properties by virtue of its abundance of ion channels and its filter-like structure. •A novel structured Nb2O5 was achieved by hydrothermal method.•The novel structure is similar to air filter.•The air filter-like Nb2O5 is an ideal electrode material for supercapacitors.•The air filter-like Nb2O5 exhibits the excellent electrochemical performance.</description><subject>Air filters</subject><subject>Capacitance</subject><subject>Current density</subject><subject>Electrochemical analysis</subject><subject>Electrochemical performance</subject><subject>Electron microscopes</subject><subject>Electron microscopy</subject><subject>Hydrothermal method</subject><subject>Ion channels</subject><subject>Microscopy</subject><subject>Morphology</subject><subject>Niobium oxides</subject><subject>Niobium pentoxide</subject><subject>Supercapacitor</subject><issn>0925-8388</issn><issn>1873-4669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkM1u1TAQhS0EEpfSR0CyxDrBYzs_XiFUQUGqWhZ0bTn2RHXwjYPt0PbtcbnddzMjzZw5o_MR8gFYCwz6T0u7mBBsPLacgWpZ34KCV-QA4yAa2ffqNTkwxbtmFOP4lrzLeWGsKgUcyP3PhJtJpvi40jjT64nfdPTelztqVmp8orMPBVMT_G-kuaTdlj1hXTrqS6b4YDEEXAvFgLakaO_w6K0JdMM0x3Q0q0XqV5r3OrBmM9aXmPJ78mY2IeP5cz8jt9--_rr43lzdXP64-HLVWDH0pVbeAYCZzKCmWQJ0XKKcRs4tOGATCKmYUxydck7ByDuJQjrZcWbspECckY8n3y3FPzvmope4p7W-1JwPYpAgxr6qupPKpphzwllvyR9NetTA9BNjvehnxvqJsWa9hv_un093WCP89Zh0th5rYudTpaFd9C84_AN0Nok4</recordid><startdate>20190925</startdate><enddate>20190925</enddate><creator>Liu, Jingqiang</creator><creator>Xiang, Kaixiong</creator><creator>Zhou, Wei</creator><creator>Zhu, Yirong</creator><creator>Xiao, Li</creator><creator>Chen, Wenhao</creator><creator>Chen, Han</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20190925</creationdate><title>Preparation of Nb2O5 with an air filter-like structure and its excellent electrochemical performance in supercapacitors</title><author>Liu, Jingqiang ; Xiang, Kaixiong ; Zhou, Wei ; Zhu, Yirong ; Xiao, Li ; Chen, Wenhao ; Chen, Han</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c376t-c325111aba79bf411524e4b822c1d10b13490d92ed9dd918254e34d4520acb913</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Air filters</topic><topic>Capacitance</topic><topic>Current density</topic><topic>Electrochemical analysis</topic><topic>Electrochemical performance</topic><topic>Electron microscopes</topic><topic>Electron microscopy</topic><topic>Hydrothermal method</topic><topic>Ion channels</topic><topic>Microscopy</topic><topic>Morphology</topic><topic>Niobium oxides</topic><topic>Niobium pentoxide</topic><topic>Supercapacitor</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Jingqiang</creatorcontrib><creatorcontrib>Xiang, Kaixiong</creatorcontrib><creatorcontrib>Zhou, Wei</creatorcontrib><creatorcontrib>Zhu, Yirong</creatorcontrib><creatorcontrib>Xiao, Li</creatorcontrib><creatorcontrib>Chen, Wenhao</creatorcontrib><creatorcontrib>Chen, Han</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of alloys and compounds</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Jingqiang</au><au>Xiang, Kaixiong</au><au>Zhou, Wei</au><au>Zhu, Yirong</au><au>Xiao, Li</au><au>Chen, Wenhao</au><au>Chen, Han</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of Nb2O5 with an air filter-like structure and its excellent electrochemical performance in supercapacitors</atitle><jtitle>Journal of alloys and compounds</jtitle><date>2019-09-25</date><risdate>2019</risdate><volume>802</volume><spage>668</spage><epage>674</epage><pages>668-674</pages><issn>0925-8388</issn><eissn>1873-4669</eissn><abstract>A Nb2O5 compound with a structure similar to an air filter (AF-Nb2O5) was synthesized using a hydrothermal method, and further calcined to form a product that was designated CAF-Nb2O5. The morphology and microstructure of the AF-Nb2O5 and CAF-Nb2O5 were examined using X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The AF-Nb2O5 and CAF-Nb2O5 exhibited similar filter-like structures, which consisted of regular pores and ordered networks. The CAF-Nb2O5 exhibited a high specific capacitance of 258 F g−1 at a current density of 0.5 A g−1, an excellent rate capacity of 172 F g−1 at the high current density of 5 A g−1 and an impressive capacitance retention of 90.5% after 5000 cycles at the current density of 2 A g−1. The CAF-Nb2O5 exhibited excellent electrochemical properties by virtue of its abundance of ion channels and its filter-like structure. •A novel structured Nb2O5 was achieved by hydrothermal method.•The novel structure is similar to air filter.•The air filter-like Nb2O5 is an ideal electrode material for supercapacitors.•The air filter-like Nb2O5 exhibits the excellent electrochemical performance.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jallcom.2019.06.191</doi><tpages>7</tpages></addata></record>
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subjects Air filters
Capacitance
Current density
Electrochemical analysis
Electrochemical performance
Electron microscopes
Electron microscopy
Hydrothermal method
Ion channels
Microscopy
Morphology
Niobium oxides
Niobium pentoxide
Supercapacitor
title Preparation of Nb2O5 with an air filter-like structure and its excellent electrochemical performance in supercapacitors
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